Benzeneacetic acid, α-[(trimethylsilyl)oxy]-, trimethylsilyl ester


Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-1SE-52CP Sil 5 CBSE-52Ultra-2
Column length (m) 10.25. 25.25.
Carrier gas HeHeN2HeHe
Substrate      
Column diameter (mm) 0.220.32 0.200.31
Phase thickness (μm) 0.170.52 0.400.52
Tstart (C) 70.70.60.50.50.
Tend (C) 270.270.280.270.300.
Heat rate (K/min) 5.5.6.5.5.
Initial hold (min)   0.5  
Final hold (min)   5.  
I 1473.1491.1472.1491.1491.
ReferenceLefevere, Verhaeghe, et al., 1989Lefevere, Verhaeghe, et al., 1989Wurth, Kumps, et al., 1989Lefevere, Verhaeghe, et al., 1988Tuchman, Bowers, et al., 1984
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type PackedPacked
Active phase OV-1OV-1
Column length (m) 2.2.
Carrier gas N2He
Substrate SupelcoportChromosorb W HP (80-100 mesh)
Column diameter (mm)   
Phase thickness (μm)   
Tstart (C) 80.100.
Tend (C) 240.325.
Heat rate (K/min) 4.10.
Initial hold (min)   
Final hold (min)   
I 1470.1477.
ReferenceMattsson and Petersson, 1977Butts, 1972
Comment MSDC-RI MSDC-RI

References

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lefevere, Verhaeghe, et al., 1989
Lefevere, M.F.; Verhaeghe, B.J.; Declerck, D.H.; Van Bocxlaer, J.F.; De Leenheer, A.P.; De Sagher, R.M., Metabolic Profiling of Urinary Organic Acids by Single and Multicolumn Capillary Gas Chromatography, J. Chromatogr. Sci., 1989, 27, 1, 23-29, https://doi.org/10.1093/chromsci/27.1.23 . [all data]

Wurth, Kumps, et al., 1989
Wurth, C.; Kumps, A.; Mardens, Y., Urinary organic acids: Retention indices on two capillary gas chromatography columns, J. Chromatogr., 1989, 491, 186-192, https://doi.org/10.1016/S0378-4347(00)82831-5 . [all data]

Lefevere, Verhaeghe, et al., 1988
Lefevere, M.F.; Verhaeghe, B.J.; Declerck, D.M.; de Leenheer, A.P., Automated profiling of urinary organic acids by dual-column gas chromatography and gas chromatography/mass spectrometry, Biomed. Environ. Mass Spectrom., 1988, 15, 6, 311-322, https://doi.org/10.1002/bms.1200150603 . [all data]

Tuchman, Bowers, et al., 1984
Tuchman, M.; Bowers, L.D.; Fregien, K.D.; Crippin, P.J.; Krivit, W., Capillary Gas Chromatographic Separation of Urinary Organic Acids. Retention Indices of 101 Urinary Acids on a 5% Phenylmethyl Silicone Capillary Column, J. Chromatogr. Sci., 1984, 22, 5, 198-202, https://doi.org/10.1093/chromsci/22.5.198 . [all data]

Mattsson and Petersson, 1977
Mattsson, M.; Petersson, G., Reference GLC Data for the Analysis of Phenolic Compounds as Trimethylsilyl Derivatives, J. Chromatogr. Sci., 1977, 15, 12, 546-554, https://doi.org/10.1093/chromsci/15.12.546 . [all data]

Butts, 1972
Butts, W.C., Two-Column Gas Chromatography of Trimethylsilyl Derivatives of Biochemically Significant Compounds, Anal. Biochemistry, 1972, 46, 1, 187-199, https://doi.org/10.1016/0003-2697(72)90411-3 . [all data]


Notes

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