Acetaldimine

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas6. ± 2.kcal/molIonPeerboom, Ingemann, et al., 1990Appearance potentials

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

View reactions leading to C2H5N+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
Proton affinity (review)211.5kcal/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity203.8kcal/molN/AHunter and Lias, 1998HL

Ionization energy determinations

IE (eV) Method Reference Comment
9.5PEBock and Dammel, 1987LBLHLM
9.6PELafon, Gonbeau, et al., 1986LBLHLM
10.2PEBock and Dammel, 1987Vertical value; LBLHLM
10.25PELafon, Gonbeau, et al., 1986Vertical value; LBLHLM
10.18 ± 0.02PEFrost, MacDonald, et al., 1978Vertical value; LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Peerboom, Ingemann, et al., 1990
Peerboom, R.A.L.; Ingemann, S.; Nibbering, N.M.M.; Liebman, J.F., Proton affinities and heats of formation of the imines CH2=NH, CH2=NMe and PhCH=NH, J. Chem. Soc. Perkin Trans. 2, 1990, 1825-1828. [all data]

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Bock and Dammel, 1987
Bock, H.; Dammel, R., Methanimine RR"C=NR": Darstellung und photoelektronen-spektren, J. Am. Chem. Soc., 1987, 120, 1961. [all data]

Lafon, Gonbeau, et al., 1986
Lafon, C.; Gonbeau, D.; Pfister-Guillouzo, G.; Lasne, M.; Ripoll; Denis, J.; Nouv, J., Etheneamine: Spectre Photoelectronique, J. Chem., 1986, 10, 70. [all data]

Frost, MacDonald, et al., 1978
Frost, D.C.; MacDonald, B.; McDowell, C.A.; Westwood, N.P.C., Pyrolysis of trimethyl hexahydro-s-triazines. The photoelectron spectra of N-methylmethylenimine, CH2=NCH3, and C-methyl- methylenimine, CH3CH=NH, J. Electron Spectrosc. Relat. Phenom., 1978, 14, 379. [all data]


Notes

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