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1,12-Dicarbadodecaborane(12)


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Deltasub14.7 ± 0.24kcal/molN/APilcher and Skinner, 1983See also Miroshnichenko, Pavlovich, et al., 1976.

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
10.3 ± 0.2PIOrlov, Pustobaev, et al., 1988LL
10.6PEFehlner, Wu, et al., 1980Vertical value; LLK

Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
PackedSF-96160.1070.Stuchlik and Pacakova, 1979 
PackedSF-96200.1083.Stuchlik and Pacakova, 1979 
PackedApiezon L160.1098.Stuchlik and Pacakova, 1979 
PackedApiezon L200.1112.Stuchlik and Pacakova, 1979 

Kovats' RI, polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
PackedCarbowax 20M160.1418.Stuchlik and Pacakova, 1979N2, Chromosorb W DMCS; Column length: 2.4 m
PackedCarbowax 20M200.1438.Stuchlik and Pacakova, 1979N2, Chromosorb W DMCS; Column length: 2.4 m

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Miroshnichenko, Pavlovich, et al., 1976
Miroshnichenko, E.A.; Pavlovich, V.K.; Lebedev, Yu.A.; Stanko, V.I.; Gal'chenko, G.L., Microcalorimetric determination of enthalpies of sublimation of carboranes, Termodin. Org. Soedin, 1976, 5, 3. [all data]

Orlov, Pustobaev, et al., 1988
Orlov, V.M.; Pustobaev, V.N.; Ol'shevskaya, V.A.; Zakharkin, L.I.; Gal'chenko, G.L., Study of the distribution of electron density in vinyl and aryl derivatives of closo-12-carboranes by photoionization mass specctrometry, Dokl. Phys. Chem., 1988, 300, 518. [all data]

Fehlner, Wu, et al., 1980
Fehlner, T.P.; Wu, M.; Meneghelli, B.J.; Rudolph, R.W., Ultraviolet photoelectron spectroscopy of thiaboranes, Inorg. Chem., 1980, 19, 49. [all data]

Stuchlik and Pacakova, 1979
Stuchlik, J.; Pacakova, V., Gas chromatographic behaviour of some carboranes, J. Chromatogr., 1979, 174, 1, 224-227, https://doi.org/10.1016/S0021-9673(00)87057-0 . [all data]


Notes

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