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Fluoranthene

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Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow

Quantity Value Units Method Reference Comment
Deltafgas291.4 ± 4.0kJ/molReviewRoux, Temprado, et al., 2008There are sufficient literature values to make a qualified recommendation where the suggested value is in good agreement with values predicted using thermochemical cycles or from reliable estimates. In general, the evaluated uncertainty limits are on the order of (2 to 4) kJ/mol.; DRB
Deltafgas289.8kJ/molN/AWestrum and Wong, 1967Value computed using «DELTA»fHsolid° value of 189.8±0.4 kj/mol from Westrum and Wong, 1967 and «DELTA»subH° value of 100.0 kj/mol from Boyd, Christensen, et al., 1965.; DRB
Deltafgas292.0 ± 2.2kJ/molCcbBoyd, Christensen, et al., 1965Reanalyzed by Cox and Pilcher, 1970, Original value = 295. ± 7.5 kJ/mol; ALS

Constant pressure heat capacity of gas

Cp,gas (J/mol*K) Temperature (K) Reference Comment
42.0050.Dorofeeva O.V., 1989These values are based on the experimental assignment of vibrational spectra. The S(300 K) and Cp(300 K) values calculated by MM3 method [ Pope C.J., 1995] are 10 and 4 J/mol*K, respectively, larger than selected ones. Recommended values are also reproduced in the reference book [ Frenkel M., 1994].; GT
65.72100.
95.81150.
130.42200.
184.90273.15
203.6 ± 2.0298.15
204.95300.
274.78400.
332.96500.
379.38600.
416.36700.
446.20800.
470.63900.
490.881000.
507.821100.
522.121200.
534.261300.
544.631400.
553.541500.

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafsolid190.2 ± 2.8kJ/molReviewRoux, Temprado, et al., 2008There are sufficient literature values to make a qualified recommendation where the suggested value is in good agreement with values predicted using thermochemical cycles or from reliable estimates. In general, the evaluated uncertainty limits are on the order of (2 to 4) kJ/mol.; DRB
Deltafsolid189.8 ± 0.4kJ/molCcrWestrum and Wong, 1967ALS
Deltafsolid192. ± 5.4kJ/molCcbBoyd, Christensen, et al., 1965ALS
Quantity Value Units Method Reference Comment
Deltacsolid-7915.2 ± 0.4kJ/molCcrWestrum and Wong, 1967Corresponding «DELTA»fsolid = 189.9 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacsolid-7917.8 ± 5.4kJ/molCcbBoyd, Christensen, et al., 1965Corresponding «DELTA»fsolid = 192. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
solid,1 bar230.58J/mol*KN/AWong and Westrum, 1971DH

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
230.25298.15Wong and Westrum, 1971T = 5 to 427 K.; DH

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tfus381.0KN/ACasellato, Vecchi, et al., 1973Uncertainty assigned by TRC = 0.2 K; TRC
Tfus386.1KN/ASangster and Irvine, 1956Uncertainty assigned by TRC = 3. K; TRC
Tfus385.2KN/ASangster and Irvine, 1956Uncertainty assigned by TRC = 3. K; TRC
Tfus385.4KN/ASangster and Irvine, 1956Uncertainty assigned by TRC = 3. K; TRC
Tfus383.45KN/ASchuyer, Blom, et al., 1953Uncertainty assigned by TRC = 1. K; TRC
Quantity Value Units Method Reference Comment
Ttriple383.340KN/AWong and Westrum, 1971, 2Uncertainty assigned by TRC = 0.005 K; TRC
Ttriple383.330KN/AWong and Westrum, 1971, 2Uncertainty assigned by TRC = 0.005 K; TRC
Quantity Value Units Method Reference Comment
Deltavap86.8 ± 1.3kJ/molGCRibeiro da Silva, Gomes, et al., 2005Based on data from 423. - 493. K.; AC
Quantity Value Units Method Reference Comment
Deltasub101.2 ± 2.8kJ/molReviewRoux, Temprado, et al., 2008There are sufficient literature values to make a qualified recommendation where the suggested value is in good agreement with values predicted using thermochemical cycles or from reliable estimates. In general, the evaluated uncertainty limits are on the order of (2 to 4) kJ/mol.; DRB
Deltasub99.2 ± 0.8kJ/molVMorawetz, 1972ALS
Deltasub99.2 ± 0.8kJ/molCMorawetz, 1972, 2See also Pedley and Rylance, 1977.; AC
Deltasub102. ± 2.kJ/molVBoyd, Christensen, et al., 1965ALS
Deltasub100.0kJ/molN/ABoyd, Christensen, et al., 1965DRB

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
79.3398.GCLei, Chankalal, et al., 2002Based on data from 323. - 473. K.; AC
77.4398.GCHinckley, Bidleman, et al., 1990Based on data from 343. - 453. K.; AC
62.2518.AStephenson and Malanowski, 1987Based on data from 503. - 658. K. See also Tsypikina and Ya, 1955.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
470. - 657.42.512131017.476-253.875Tsypkina, 1955Coefficents calculated by NIST from author's data.

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Method Reference Comment
98.3383.GSNass, Lenoir, et al., 1995Based on data from 313. - 453. K.; AC
84.6 ± 0.9303.GSSonnefeld, Zoller, et al., 1983Based on data from 283. - 323. K.; AC
102. ± 2.340.MEBoyd, Christensen, et al., 1965Based on data from 328. - 353. K. See also Cox and Pilcher, 1970, 2.; AC
102.6328.N/AHoyer and Peperle, 1958Based on data from 298. - 358. K.; AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
18.728383.36Wong and Westrum, 1971DH
18.74383.4Domalski and Hearing, 1996AC

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
48.85383.36Wong and Westrum, 1971DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Henry's Law data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Rolf Sander

Henry's Law constant (water solution)

kH(T) = H exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K)))
H = Henry's law constant for solubility in water at 298.15 K (mol/kg*bar)
d(ln(kH))/d(1/T) = Temperature dependence constant (K)

H (mol/kg*bar) d(ln(kH))/d(1/T) (K) Method Reference
110.6900.XN/A
0.46 LN/A

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Henry's Law data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
MM - Michael M. Meot-Ner (Mautner)
LL - Sharon G. Lias and Joel F. Liebman
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to C16H10+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)7.9 ± 0.1eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)828.6kJ/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity800.9kJ/molN/AHunter and Lias, 1998HL

Electron affinity determinations

EA (eV) Method Reference Comment
0.629995ECDMichl, 1969B

Proton affinity at 298K

Proton affinity (kJ/mol) Reference Comment
826.8Aue, Guidoni, et al., 2000Experimental literature data re-evaluated by the authors using ab initio protonation entropies; MM

Gas basicity at 298K

Gas basicity (review) (kJ/mol) Reference Comment
799.6Aue, Guidoni, et al., 2000Experimental literature data re-evaluated by the authors using ab initio protonation entropies; MM

Ionization energy determinations

IE (eV) Method Reference Comment
7.9 ± 0.1TRPILing and Lifshitz, 1995LL
7.95 ± 0.04PEBoschi, Clar, et al., 1974LLK
7.80 ± 0.01PIDewar, Haselbach, et al., 1970RDSH
7.72CTSSlifkin and Allison, 1967RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C16H8+11.50 ± 0.122HDERLing and Lifshitz, 1995LL
C16H8+11.24 ± 0.25H2DERLing and Lifshitz, 1995LL
C16H9+12.38 ± 0.14HDERLing and Lifshitz, 1995LL

IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Gas Phase Spectrum

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IR spectrum
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Additional Data

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Owner NIST Standard Reference Data Program
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NIST Mass Spectrometry Data Center
State gas
Instrument HP-GC/MS/IRD

This IR spectrum is from the NIST/EPA Gas-Phase Infrared Database .


Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, UV/Visible spectrum, Gas Chromatography, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-NW- 126
NIST MS number 228362

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


UV/Visible spectrum

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Victor Talrose, Eugeny B. Stern, Antonina A. Goncharova, Natalia A. Messineva, Natalia V. Trusova, Margarita V. Efimkina

Spectrum

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UVVis spectrum
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Additional Data

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Source Streitwieser and Suzuki, 1961
Owner INEP CP RAS, NIST OSRD
Collection (C) 2007 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin INSTITUTE OF ENERGY PROBLEMS OF CHEMICAL PHYSICS, RAS
Source reference RAS UV No. 382
Instrument n.i.g.
Melting point 107.8
Boiling point 384

Gas Chromatography

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillarySPB-5180.2057.Corbella, Rodríguez, et al., 199515. m/0.32 mm/0.25 «mu»m, He
PackedOV-101250.2091.Rudenko, Bulychova, et al., 1984N2; Column length: 3. m
PackedOV-101230.2091.Grimmer and Böhnke, 1975Gas Chrom Q; Column length: 10. m
PackedSE-30200.2051.Shlyakhov, Anvaer, et al., 1975 
CapillaryOV-101230.2091.Grimmer and Böhnke, 1972N2; Column length: 50. m; Column diameter: 0.50 mm

Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryHP-5MS2053.5Zhao C.X., Li, et al., 200630. m/0.25 mm/0.25 «mu»m, He, 4. K/min; Tstart: 80. C; Tend: 300. C
CapillaryDB-52060.1Song, Lai, et al., 200330. m/0.25 mm/0.25 «mu»m, He, 4. K/min; Tstart: 40. C; Tend: 310. C
CapillaryDB-52060.1Song, Lai, et al., 200330. m/0.25 mm/0.25 «mu»m, He, 40. C @ 5. min, 4. K/min; Tend: 310. C
CapillaryDB-52032.6Song, Lai, et al., 200330. m/0.25 mm/0.25 «mu»m, He, 2. K/min; Tstart: 40. C; Tend: 310. C
CapillaryDB-52060.1Song, Lai, et al., 200330. m/0.25 mm/0.25 «mu»m, He, 4. K/min; Tstart: 40. C; Tend: 310. C
CapillaryDB-52076.5Song, Lai, et al., 200330. m/0.25 mm/0.25 «mu»m, He, 6. K/min; Tstart: 40. C; Tend: 310. C
CapillaryOV-12038.9Zhang, Shen, et al., 200025. m/0.2 mm/0.33 «mu»m, 5. K/min; Tstart: 100. C; Tend: 180. C
CapillaryOV-12062.3Zhang, Shen, et al., 200025. m/0.2 mm/0.33 «mu»m, 5. K/min; Tstart: 100. C; Tend: 180. C
CapillaryHP-5MS2085.Nahir, 199930. m/0.25 mm/0.25 «mu»m, 10. K/min; Tstart: 50. C; Tend: 300. C
CapillaryDB-52032.6Lai and Song, 199530. m/0.25 mm/0.25 «mu»m, He, 2. K/min; Tstart: 40. C; Tend: 310. C
CapillaryDB-52060.1Lai and Song, 199530. m/0.25 mm/0.25 «mu»m, He, 4. K/min; Tstart: 40. C; Tend: 310. C
CapillaryDB-52076.5Lai and Song, 199530. m/0.25 mm/0.25 «mu»m, He, 6. K/min; Tstart: 40. C; Tend: 310. C
CapillaryDB-52060.1Lai and Song, 199530. m/0.25 mm/0.25 «mu»m, He, 4. K/min; Tstart: 40. C; Tend: 310. C
CapillaryDB-52060.1Lai and Song, 199530. m/0.25 mm/0.25 «mu»m, He, 40. C @ 5. min, 4. K/min; Tend: 310. C
CapillaryDB-52084.Rostad and Pereira, 198630. m/0.26 mm/0.25 «mu»m, He, 50. C @ 4. min, 6. K/min, 300. C @ 20. min
CapillarySE-522011.Beernaert, 1979He, 50. C @ 5. min, 6. K/min; Column length: 33.3 m; Column diameter: 0.50 mm; Tend: 320. C
CapillarySE-522009.Beernaert, 1979He, 50. C @ 5. min, 6. K/min; Column length: 16.6 m; Column diameter: 0.50 mm; Tend: 320. C
CapillarySE-522009.Beernaert, 1979He, 50. C @ 5. min, 6. K/min; Column length: 16.6 m; Column diameter: 0.50 mm; Tend: 320. C
CapillarySE-522009.Beernaert, 1979He, 50. C @ 5. min, 6. K/min; Column length: 16.6 m; Column diameter: 0.50 mm; Tend: 320. C
CapillarySE-522009.Beernaert, 1979He, 50. C @ 5. min, 6. K/min; Column length: 16.6 m; Column diameter: 0.50 mm; Tend: 320. C
CapillarySE-522009.Beernaert, 1979He, 50. C @ 5. min, 6. K/min; Column length: 16.6 m; Column diameter: 0.50 mm; Tend: 320. C
CapillarySE-522023.Beernaert, 1979He, 50. C @ 5. min, 6. K/min; Column length: 16.6 m; Column diameter: 0.50 mm; Tend: 320. C
CapillarySE-522023.Beernaert, 1979He, 50. C @ 5. min, 6. K/min; Column length: 16.6 m; Column diameter: 0.50 mm; Tend: 320. C
CapillarySE-522023.Beernaert, 1979He, 50. C @ 5. min, 6. K/min; Column length: 16.6 m; Column diameter: 0.50 mm; Tend: 320. C
CapillarySE-522023.Beernaert, 1979He, 50. C @ 5. min, 6. K/min; Column length: 16.6 m; Column diameter: 0.50 mm; Tend: 320. C
CapillarySE-522030.Beernaert, 1979He, 50. C @ 5. min, 6. K/min; Column length: 16.6 m; Column diameter: 0.50 mm; Tend: 320. C
CapillarySE-522030.Beernaert, 1979He, 50. C @ 5. min, 6. K/min; Column length: 16.6 m; Column diameter: 0.50 mm; Tend: 320. C
CapillarySE-522031.Beernaert, 1979He, 50. C @ 5. min, 6. K/min; Column length: 16.6 m; Column diameter: 0.50 mm; Tend: 320. C
CapillarySE-522037.Beernaert, 1979He, 50. C @ 5. min, 6. K/min; Column length: 16.6 m; Column diameter: 0.50 mm; Tend: 320. C
CapillarySE-522042.Beernaert, 1979He, 50. C @ 5. min, 6. K/min; Column length: 16.6 m; Column diameter: 0.50 mm; Tend: 320. C
CapillarySE-522044.Beernaert, 1979He, 50. C @ 5. min, 6. K/min; Column length: 16.6 m; Column diameter: 0.50 mm; Tend: 320. C
CapillarySE-522020.Carugno and Rossi, 1967N2, 1.8 K/min; Column length: 65. m; Column diameter: 0.3 mm; Tstart: 100. C; Tend: 300. C

Van Den Dool and Kratz RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryHP-12020.45Dimitriou-Christidis, Harris, et al., 200330. m/0.25 mm/0.25 «mu»m; Program: 60C => 7C/min => 225C => 15C/min => 300C(11.43min)
CapillaryHP-52068.42Dimitriou-Christidis, Harris, et al., 200330. m/0.25 mm/0.25 «mu»m; Program: 60C => 7C/min => 225C => 15C/min => 300C(11.43min)
CapillaryDB-52084.Havenga and Rohwer, 199930. m/0.25 mm/0.25 «mu»m, He; Program: 60 0C 7 0C/min -> 130 0C 5 0C/min -> 200 0C 6 0C/min -> 260 0C 20 0C/min -> 320 0C (4 min)
Capillary5 % Phenyl methyl siloxane2037.Yasuhara, Shiraishi, et al., 199725. m/0.31 mm/0.52 «mu»m, He; Program: 50C(2min) => (20C/min) => 120C => (7C/min) => 310C(10min)
CapillaryMethyl Silicone2015.Oda, Ichikawa, et al., 1996Program: 50C (2min) => 20C/min => 160C => 5C/min => 210C => 10C/min => 300C

Normal alkane RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryC103H2082098.Dumitrescu, Buda, et al., 2000H2, 5. K/min; Phase thickness: 0.25 «mu»m; Tstart: 80. C; Tend: 275. C
CapillaryC103H2082089.Dumitrescu, Buda, et al., 2000H2, 4. K/min; Phase thickness: 0.25 «mu»m; Tstart: 100. C; Tend: 275. C
CapillaryHP-52052.Miao and Wu, 199930. m/0.32 mm/0.25 «mu»m, 50. C @ 2. min, 5. K/min; Tend: 310. C
CapillaryHP-52053.Miao and Wu, 199930. m/0.32 mm/0.25 «mu»m, 50. C @ 2. min, 5. K/min; Tend: 310. C
CapillaryHP-52057.Miao and Wu, 199930. m/0.32 mm/0.25 «mu»m, 50. C @ 2. min, 5. K/min; Tend: 310. C
CapillaryHP-52058.Miao and Wu, 199930. m/0.32 mm/0.25 «mu»m, 50. C @ 2. min, 5. K/min; Tend: 310. C
CapillaryHP-52060.Miao and Wu, 199930. m/0.32 mm/0.25 «mu»m, 50. C @ 2. min, 5. K/min; Tend: 310. C
CapillaryHP-52061.Miao and Wu, 199930. m/0.32 mm/0.25 «mu»m, 50. C @ 2. min, 5. K/min; Tend: 310. C
CapillaryHP-52079.Miao and Wu, 199930. m/0.32 mm/0.25 «mu»m, 50. C @ 2. min, 5. K/min; Tend: 310. C
CapillaryHP-52080.Miao and Wu, 199930. m/0.32 mm/0.25 «mu»m, 50. C @ 2. min, 5. K/min; Tend: 310. C
CapillaryUltra-12031.Elizalde-González, Hutfliess, et al., 199650. m/0.2 mm/0.33 «mu»m, H2, 3. K/min, 300. C @ 35. min; Tstart: 60. C
CapillarySE-542045.Harland, Cumming, et al., 1986He, 50. C @ 2. min, 8. K/min, 250. C @ 12. min; Column length: 25. m; Column diameter: 0.32 mm

Normal alkane RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryHP-5MS2062.Vichi, Pizzale, et al., 200530. m/0.25 mm/0.25 «mu»m; Program: 40C(3min) => 4C/min => 75C => 8C/min => 250C
CapillaryMethyl Silicone2028.Oda, Yasuhara, et al., 199825. m/0.25 mm/0.25 «mu»m, He; Program: 50 0C (2 min) 20 0C/min -> 160 0C 5 0C/min -> 210 0C 10 0C/min -> 300 0C
CapillaryMethyl Silicone2006.Zenkevich, 1996Program: not specified
CapillaryPolydimethyl siloxane, unknown content of Ph-groups2084.Geldon, 1989Program: not specified
CapillaryPolydimethyl siloxane, unknown content of Ph-groups2085.Geldon, 1989Program: not specified
CapillaryOV-1, SE-30, Methyl silicone, SP-2100, OV-101, DB-1, etc.2030.Waggott and Davies, 1984Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified
PackedOV-1012091.Kaliszan and Lamparczyk, 1978Program: not specified

Lee's RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
PackedMethyl Silicone175.341.94Shlyakhov, 1984 
PackedMethyl Silicone200.340.99Shlyakhov, 1984 
PackedMethyl Silicone200.343.44Shlyakhov, 1984 
PackedMethyl Silicone235.343.15Shlyakhov, 1984 
PackedMethyl Silicone240.342.27Shlyakhov, 1984 
PackedMethyl Silicone260.343.16Shlyakhov, 1984 
PackedMethyl Silicone300.344.01Shlyakhov, 1984 

Lee's RI, non-polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
CapillaryPE-5344.3Jamoussi, Kanzari, et al., 200720. m/0.18 mm/0.18 «mu»m, 50. C @ 1.5 min, 8. K/min; Tend: 345. C
CapillaryHP-5337.0Wang, Hou, et al., 200730. m/0.30 mm/0.25 «mu»m, Helium, 50. C @ 5. min, 5. K/min, 200. C @ 15. min
CapillaryHP-5337.Shao, Wang, et al., 200630. m/0.3 mm/0.25 «mu»m, He, 50. C @ 5. min, 5. K/min, 200. C @ 15. min
Capillary5 % Phenyl methyl siloxane344.01Skrbic and Onjia, 20062. K/min; Tstart: 50. C; Tend: 250. C
Capillary5 % Phenyl methyl siloxane340.90Skrbic and Onjia, 200680. C @ 2. min, 8. K/min, 300. C @ 10. min
CapillaryHP-5344.85Pedersen, Durant, et al., 200530. m/0.25 mm/0.25 «mu»m, Helium, 50. C @ 1.5 min, 6. K/min, 310. C @ 10. min
CapillaryHP-5344.49Marynowski, Pieta, et al., 200460. m/0.25 mm/0.25 «mu»m, He, 3. K/min; Tstart: 35. C; Tend: 300. C
CapillaryDB-5MS344.78Chen, Keeran, et al., 200230. m/0.25 mm/0.5 «mu»m, 40. C @ 1. min, 10. K/min; Tend: 310. C
CapillaryDB-5MS344.83Chen, Keeran, et al., 200230. m/0.25 mm/0.5 «mu»m, 40. C @ 1. min, 4. K/min; Tend: 310. C
CapillaryPTE-5344.99Wang, Jia, et al., 200030. m/0.25 mm/0.25 «mu»m, 60. C @ 1.5 min, 8. K/min, 300. C @ 12.5 min
CapillaryHP-5344.49Miao and Wu, 199950. C @ 2. min, 5. K/min; Tend: 310. C
CapillaryHP-5344.51Miao and Wu, 199950. C @ 2. min, 5. K/min; Tend: 310. C
CapillaryHP-5344.56Miao and Wu, 199950. C @ 2. min, 5. K/min; Tend: 310. C
CapillaryHP-5344.60Miao and Wu, 199950. C @ 2. min, 5. K/min; Tend: 310. C
CapillaryHP-5344.64Miao and Wu, 199950. C @ 2. min, 5. K/min; Tend: 310. C
CapillaryHP-5344.67Miao and Wu, 199950. C @ 2. min, 5. K/min; Tend: 310. C
CapillaryHP-5344.74Miao and Wu, 199950. C @ 2. min, 5. K/min; Tend: 310. C
CapillaryHP-5344.75Miao and Wu, 199950. C @ 2. min, 5. K/min; Tend: 310. C
CapillaryHP-5344.54Piao, Chu, et al., 199930. m/0.25 mm/0.25 «mu»m, 50. C @ 2. min, 4. K/min, 280. C @ 20. min
CapillaryHP-5344.68Piao, Chu, et al., 199930. m/0.25 mm/0.25 «mu»m, 50. C @ 2. min, 4. K/min, 280. C @ 20. min
CapillaryDB-5344.8Durlak, Biswas, et al., 199830. m/0.25 mm/0.25 «mu»m, 15. K/min; Tstart: 50. C; Tend: 300. C
CapillaryDB-5344.8Durlak, Biswas, et al., 199830. m/0.25 mm/0.25 «mu»m, 15. K/min; Tstart: 50. C; Tend: 300. C
CapillarySE-54344.67Chen, 19964. K/min; Column length: 30. m; Column diameter: 0.25 mm; Tstart: 50. C; Tend: 300. C
CapillarySE-52344.85Shaogang and Xiaobai, 199440. C @ 2. min, 4. K/min, 300. C @ 20. min; Column length: 30. m; Column diameter: 0.25 mm
CapillaryDB-5344.8Donnelly, Abdel-Hamid, et al., 199330. m/0.32 mm/0.25 «mu»m, He, 40. C @ 3. min, 8. K/min, 285. C @ 29.5 min
CapillarySPB-5345.0Knobloch and Engewald, 199340. C @ 2. min, 4. K/min; Column length: 30. m; Column diameter: 0.25 mm; Tend: 300. C
CapillarySE-54344.55Guillén, Blanco, et al., 198920. m/0.22 mm/0.20 «mu»m, He, 4. K/min; Tstart: 50. C; Tend: 300. C
CapillarySE-52344.62Hasegawa, Muragishi, et al., 19883. K/min; Column length: 25. m; Column diameter: 0.25 mm; Tstart: 130. C; Tend: 260. C
CapillaryDB-5344.35Sye, Lin, et al., 198830. m/0.32 mm/0.25 «mu»m, 80. C @ 1. min, 3. K/min; Tend: 290. C
CapillaryDB-5344.49Wise, Benner, et al., 198830. m/0.25 mm/0.25 «mu»m, 40. C @ 2. min, 4. K/min, 280. C @ 5. min
CapillaryDB-5344.68Rostad and Pereira, 198630. m/0.26 mm/0.25 «mu»m, He, 50. C @ 4. min, 6. K/min, 300. C @ 20. min
CapillaryDB-5344.43Tong, Centen, et al., 1985He, 4. K/min; Column length: 30. m; Column diameter: 0.25 mm; Tstart: 90. C; Tend: 325. C
PackedMethyl Silicone340.66Shlyakhov, 19842. K/min; Tstart: 100. C; Tend: 275. C
CapillaryDB-5344.560Tong, Shore, et al., 1984He, 80. C @ 1. min, 3. K/min, 300. C @ 10. min; Column length: 30. m; Column diameter: 0.32 mm
CapillaryDB-5344.7Viau, Studak, et al., 1984Helium, 4. K/min; Column length: 30. m; Column diameter: 0.32 mm; Tstart: 90. C; Tend: 250. C
CapillarySE-52344.51Vassilaros, Kong, et al., 198220. m/0.30 mm/0.25 «mu»m, H2, 40. C @ 2. min, 4. K/min; Tend: 265. C
CapillarySE-52344.01Lee, Vassilaros, et al., 197912. m/0.3 mm/0.34 «mu»m, He, 2. K/min; Tstart: 50. C; Tend: 250. C

Lee's RI, non-polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillaryDB-5344.6Fuentes, Font, et al., 2007Column length: 60. m; Program: not specified
CapillaryHP-5MS344.96Wang, Li, et al., 200730. m/0.25 mm/0.25 «mu»m, He; Program: 60C(2min) => 6C/min => 258C => 2C/min => 300C(4min)
CapillaryHP-5MS344.49Wang, Li, et al., 2007, 230. m/0.25 mm/0.25 «mu»m, He; Program: not specified
CapillaryHP-5MS344.96Wang, Li, et al., 2007, 230. m/0.25 mm/0.25 «mu»m, He; Program: not specified
Capillary5 % Phenyl methyl siloxane340.10Skrbic and Onjia, 2006Program: 70 0C (2 min) 30 0C/min -> 150 0C 5 0C/min -> 200 0C 4 0C/min -> 310 0C (5 min)
CapillaryDB-5MS338.2Aracil, Font, et al., 2005Column length: 60. m; Column diameter: 0.25 mm; Program: not specified
CapillaryHP-5MS389.98Cheng, Liu, et al., 200530. m/0.30 mm/0.25 «mu»m, He; Program: 50 0C (2 min) 8 0C/min -> 120 0C (3 min) 10 0C/min -> 230 0C
CapillaryLM-5340.21Ré-Poppi and Santiago-Silva, 200530. m/0.25 mm/0.25 «mu»m, He; Program: 60C(2min) => 15C/min => 180C => 5C/min => 280C (10min)
CapillaryLM-5340.44Ré-Poppi and Santiago-Silva, 200530. m/0.25 mm/0.25 «mu»m, He; Program: 60C(2min) => 15C/min => 180C => 5C/min => 280C (10min)
CapillaryUltra-1338.5Sremac, Skrbic, et al., 200550. m/0.32 mm/0.50 «mu»m, Nitrogen; Program: 40-100 0C 3-15 0C/min -> 290 0C
CapillaryUltra-1344.0Sremac, Skrbic, et al., 200550. m/0.32 mm/0.50 «mu»m, Nitrogen; Program: 40-100 0C 3-15 0C/min -> 290 0C
CapillaryDB-5344.9Lundstedt, Haglund, et al., 200330. m/0.25 mm/0.25 «mu»m; Program: not specified
CapillaryLM-5340.35Ré-Poppi and Santiago-Silva, 200230. m/0.25 mm/0.25 «mu»m, He; Program: 60C(2min) => 15C/min => 180C => 5C/min => 280C(5min)
CapillaryLM-5340.44Ré-Poppi and Santiago-Silva, 200230. m/0.25 mm/0.25 «mu»m, He; Program: 60C(2min) => 15C/min => 180C => 5C/min => 280C(5min)
CapillaryHP-5342.65Reckendorf, 199725. m/0.2 mm/0.11 «mu»m, He; Program: 106C(0.2min) => 40C/min => 120C => 3C/min => 310C(10min)
CapillaryDB-5343.25Zamperlini, Silva, et al., 199730. m/0.25 mm/0.25 «mu»m, He; Program: 90C (1min) => 10C/min => 120C => 4C/min => 310C (20min)
CapillaryDB-5343.31Zamperlini, Silva, et al., 199730. m/0.25 mm/0.25 «mu»m, He; Program: 90C (1min) => 10C/min => 120C => 4C/min => 310C (20min)
CapillarySE-54344.01Chen, 1996Column length: 30. m; Column diameter: 0.25 mm; Program: not specified
CapillarySE-52344.51Shaogang and Xiaobai, 1994Column length: 30. m; Column diameter: 0.25 mm; Program: not specified
CapillarySE-54343.24Guillen, Iglesias, et al., 1992Program: not specified
CapillarySE-54344.6Peterman and Delfino, 199015. m/0.25 mm/0.25 «mu»m, He; Program: 125 0C (15 min) 1 0C/min -> 131 0C 4 0C/min -> 247 0C 8 0C/min -> 280 0C (15 min)
CapillaryDB-5340.11Takada, Onda, et al., 1990He; Program: 70C(2min) => 30C/min => 150C => 5C/min => 200C => 4C/min => 310C
CapillaryDB-5344.01Naikwadi, Charbonneau, et al., 1987Column length: 30. m; Column diameter: 0.32 mm; Program: not specified
CapillaryDB-5345.32Naikwadi, Charbonneau, et al., 1987Column length: 30. m; Column diameter: 0.32 mm; Program: not specified
CapillaryOV-101344.6Tucminen, Wickstrom, et al., 1986Program: not specified
CapillarySE-52340.05Shlyakhov, 1984Program: not specified
CapillarySE-52340.88Shlyakhov, 1984Program: not specified
CapillarySE-52341.74Shlyakhov, 1984Program: not specified
CapillarySE-52342.74Shlyakhov, 1984Program: not specified
CapillarySE-52343.25Shlyakhov, 1984Program: not specified
CapillarySE-52343.65Shlyakhov, 1984Program: not specified
CapillarySE-52344.01Shlyakhov, 1984Program: not specified
CapillarySE-52345.00Shlyakhov, 1984Program: not specified

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, NIST Free Links, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

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Notes

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