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Rhodium, positive ion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Rh+ + Propene = (Rh+ bullet Propene)

By formula: Rh+ + C3H6 = (Rh+ bullet C3H6)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
118. CIDChen and Armetrout, 1995gas phase; «DELTA»rH>=, guided ion beam CID; M

Rh+ + Acetylene = (Rh+ bullet Acetylene)

By formula: Rh+ + C2H2 = (Rh+ bullet C2H2)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
129. CIDChen and Armetrout, 1995gas phase; «DELTA»rH>=, guided ion beam CID; M

Rh+ + Allene = (Rh+ bullet Allene)

By formula: Rh+ + C3H4 = (Rh+ bullet C3H4)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
222. (+19.,-0.) CIDChen and Armetrout, 1995gas phase; guided ion beam CID; M

Rh+ + Ethylene = (Rh+ bullet Ethylene)

By formula: Rh+ + C2H4 = (Rh+ bullet C2H4)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
161. (+3.,-0.) CIDChen and Armetrout, 1995gas phase; guided ion beam CID; M

Rh+ + Carbon monosulfide = (Rh+ bullet Carbon monosulfide)

By formula: Rh+ + CS = (Rh+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar234. ± 19.kJ/molCIDTRodgers and Armentrout, 2000RCD

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chen and Armetrout, 1995
Chen, Y.M.; Armetrout, P.B., Activation of C2H6, C3H8, and c-C3H6 by Gas-Phase Rh+ and the Thermochemistry of Rh-Ligand Complexes, J. Am. Chem. Soc., 1995, 117, 36, 9291, https://doi.org/10.1021/ja00141a022 . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]


Notes

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