trans-1,2-Dimethylcyclopropane


Kovats' RI, non-polar column, isothermal

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type PackedPackedPackedPackedPacked
Active phase SqualaneSqualaneSqualaneSqualaneSqualane
Column length (m)      
Carrier gas      
Substrate      
Column diameter (mm)      
Phase thickness (μm)      
Temperature (C) 20.27.50.67.70.
I 481.479.479.480.480.
ReferenceBogoslovsky, Anvaer, et al., 1978Bogoslovsky, Anvaer, et al., 1978Bogoslovsky, Anvaer, et al., 1978Bogoslovsky, Anvaer, et al., 1978Bogoslovsky, Anvaer, et al., 1978
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type PackedPackedCapillaryCapillaryCapillary
Active phase SqualaneSqualaneSqualaneSqualaneSqualane
Column length (m)   100.100.100.
Carrier gas   N2N2 
Substrate      
Column diameter (mm)   0.250.250.25
Phase thickness (μm)      
Temperature (C) 86.90.50.70.120.
I 480.481.479.480.481.0
ReferenceBogoslovsky, Anvaer, et al., 1978Bogoslovsky, Anvaer, et al., 1978Rijks and Cramers, 1974Rijks and Cramers, 1974Schomburg and Dielmann, 1973
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryPackedPackedPacked
Active phase SqualaneSqualaneSqualaneSqualaneSqualane
Column length (m) 100.100.15.15.15.
Carrier gas   HeHeHe
Substrate   Chromosorb PChromosorb PChromosorb P
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm)      
Temperature (C) 70.70.27.49.67.
I 480.480.479.480.480.
ReferenceCramers, Rijks, et al., 1970Cramers, Rijks, et al., 1970Hively and Hinton, 1968Hively and Hinton, 1968Hively and Hinton, 1968
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type Packed
Active phase Squalane
Column length (m) 15.
Carrier gas He
Substrate Chromosorb P
Column diameter (mm) 0.25
Phase thickness (μm)  
Temperature (C) 86.
I 480.
ReferenceHively and Hinton, 1968
Comment MSDC-RI

References

Go To: Top, Kovats' RI, non-polar column, isothermal, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bogoslovsky, Anvaer, et al., 1978
Bogoslovsky, Yu.N.; Anvaer, B.I.; Vigdergauz, M.S., Chromatographic constants in gas chromatography (in Russian), Standards Publ. House, Moscow, 1978, 192. [all data]

Rijks and Cramers, 1974
Rijks, J.A.; Cramers, C.A., High precision capillary gas chromatography of hydrocarbons, Chromatographia, 1974, 7, 3, 99-106, https://doi.org/10.1007/BF02269819 . [all data]

Schomburg and Dielmann, 1973
Schomburg, G.; Dielmann, G., Use of retention increments for identification and correlation of saturated and unsaturated cyclopropane hydrocarbons by means of Kovats indices, Anal. Chem., 1973, 45, 9, 1647-1658, https://doi.org/10.1021/ac60331a021 . [all data]

Cramers, Rijks, et al., 1970
Cramers, C.A.; Rijks, J.A.; Pacáková, V.; de Andrade, I.R., The application of precision gas chromatography to the identification of types of hydrocarbons, J. Chromatogr., 1970, 51, 13-21, https://doi.org/10.1016/S0021-9673(01)96835-9 . [all data]

Hively and Hinton, 1968
Hively, R.A.; Hinton, R.E., Variation of the retention index with temperature on squalane substrates, J. Gas Chromatogr., 1968, 6, 4, 203-217, https://doi.org/10.1093/chromsci/6.4.203 . [all data]


Notes

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