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1,1'-Biphenyl, 4-chloro-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil564.2KN/AWeast and Grasselli, 1989BS
Tboil555.KN/AFrinton Laboratories Inc., 1986BS
Quantity Value Units Method Reference Comment
Ttriple348.55KN/AGeidarov, Karasharli, et al., 1977Uncertainty assigned by TRC = 0.02 K; TRC
Ttriple348.55KN/AGeidarov, Dzhafarov, et al., 1975Uncertainty assigned by TRC = 0.02 K; TRC
Ttriple347.9KN/AGeidarov, Dzhafarov, et al., 1974Uncertainty assigned by TRC = 0.1 K; TRC
Quantity Value Units Method Reference Comment
Deltavap71.6 ± 0.7kJ/molCGCPuri, Chickos, et al., 2001AC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
66.8368.GCFalconer and Bidleman, 1994Based on data from 343. - 393. K.; AC
65.9466.AStephenson and Malanowski, 1987Based on data from 451. - 536. K.; AC
59.0384.AStephenson and Malanowski, 1987Based on data from 369. - 566. K. See also Stull, 1947.; AC
67.8378.TEFerro, Piacente, et al., 1983Based on data from 348. - 409. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
369.6 - 566.15.077492752.545-23.404Stull, 1947Coefficents calculated by NIST from author's data.

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Method Reference Comment
86.0 ± 0.9278.GSWania, Shiu, et al., 1994Based on data from 253. - 303. K.; AC
73.7 ± 0.7326.TE,MEFerro, Piacente, et al., 1983Based on data from 306. - 346. K.; AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
13.318348.55Geidarov, Dzhafarov, et al., 1975, 2DH
13.318348.55Geidarov, Karasharli, et al., 1977, 2DH
13.32348.6Acree, 1991AC

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
38.21348.55Geidarov, Dzhafarov, et al., 1975, 2DH
38.21348.55Geidarov, Karasharli, et al., 1977, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Frinton Laboratories Inc., 1986
Frinton Laboratories Inc., Catalog Number 11, Frinton Laboratories Inc., Vineland, NJ, 1986, 99. [all data]

Geidarov, Karasharli, et al., 1977
Geidarov, K.I.; Karasharli, K.A.; Dzhafarov, O.I., Analysis of the results of the thermodynamic investigation of diphenyl devivatives, Azerb. Khim. Zh., 1977, 1977, 112-5. [all data]

Geidarov, Dzhafarov, et al., 1975
Geidarov, K.I.; Dzhafarov, O.I.; Karasharli, K.A.; Kostryukov, V.N., True heat capacity of p-chlorobiphenyl at 12 to 370 K, Zh. Fiz. Khim., 1975, 49, 493-4. [all data]

Geidarov, Dzhafarov, et al., 1974
Geidarov, K.I.; Dzhafarov, O.I.; Karasharli, K.A.; Kostryukov, V.N., The heat capacity of 2-chlorobiphenyl in the range 12 - 327 k, Zh. Fiz. Khim., 1974, 48, 1147-9. [all data]

Puri, Chickos, et al., 2001
Puri, Swati; Chickos, James S.; Welsh, William J., Determination of Vaporization Enthalpies of Polychlorinated Biphenyls by Correlation Gas Chromatography, Anal. Chem., 2001, 73, 7, 1480-1484, https://doi.org/10.1021/ac001246p . [all data]

Falconer and Bidleman, 1994
Falconer, Renee L.; Bidleman, Terry F., Vapor pressures and predicted particle/gas distributions of polychlorinated biphenyl congeners as functions of temperature and ortho-chlorine substitution, Atmospheric Environment, 1994, 28, 3, 547-554, https://doi.org/10.1016/1352-2310(94)90130-9 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Ferro, Piacente, et al., 1983
Ferro, Daniela; Piacente, Vincenzo; Scardala, Paolo, Torsion---Knudsen effusion vapour-pressure measurement of o, m and p-chlorobiphenyls, Thermochimica Acta, 1983, 68, 2-3, 329-339, https://doi.org/10.1016/0040-6031(83)80235-4 . [all data]

Wania, Shiu, et al., 1994
Wania, Frank; Shiu, Wan-Ying; Mackay, Donald, Measurement of the Vapor Pressure of Several Low-Volatility Organochlorine Chemicals at Low Temperatures with a Gas Saturation Method, J. Chem. Eng. Data, 1994, 39, 3, 572-577, https://doi.org/10.1021/je00015a039 . [all data]

Geidarov, Dzhafarov, et al., 1975, 2
Geidarov, Kh.I.; Dzhafarov, O.I.; Karasharli, K.A.; Kostryukov, V.N., True heat capacity of p-chlorobiphenyl at 12 to 370 K, Zhur. Fiz. Khim., 1975, 49, 493-494. [all data]

Geidarov, Karasharli, et al., 1977, 2
Geidarov, Kh.I.; Karasharli, K.A.; Dzhafarov, O.I., Analysis of the results of the thermodynamic investigation of diphenyl derivatives, Azerb. Khim. Zhur., 1977, (5), 112-115. [all data]

Acree, 1991
Acree, William E., Thermodynamic properties of organic compounds: enthalpy of fusion and melting point temperature compilation, Thermochimica Acta, 1991, 189, 1, 37-56, https://doi.org/10.1016/0040-6031(91)87098-H . [all data]


Notes

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