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Iodide


Gas phase thermochemistry data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
gas,1 bar169.26J/mol*KReviewChase, 1998Data last reviewed in June, 1982

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 1 to 50

Iodide + Water = (Iodide bullet Water)

By formula: I- + H2O = (I- bullet H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar43. ± 3.kJ/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Deltar64.0J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Deltar80.8J/mol*KHPMSKeesee and Castleman, 1980gas phase; M
Deltar68.2J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Deltar23. ± 1.kJ/molAVGN/AAverage of 6 values; Individual data points

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
22.300.HPMSBanic and Iribarne, 1985gas phase; electric fields; M

(Iodide bullet Water) + Water = (Iodide bullet 2Water)

By formula: (I- bullet H2O) + H2O = (I- bullet 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar41.4 ± 0.84kJ/molTDAsKeesee and Castleman, 1980gas phase; B,M
Deltar39.7kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Deltar39.7 ± 0.84kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar41. ± 4.2kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Deltar41. ± 4.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar73.6J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Deltar84.9J/mol*KHPMSKeesee and Castleman, 1980gas phase; M
Deltar79.5J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Deltar17. ± 2.kJ/molAVGN/AAverage of 6 values; Individual data points

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
17.300.HPMSBanic and Iribarne, 1985gas phase; electric fields; M

Iodide + Carbon dioxide = (Iodide bullet Carbon dioxide)

By formula: I- + CO2 = (I- bullet CO2)

Quantity Value Units Method Reference Comment
Deltar15. ± 7.5kJ/molN/APiani, Becucci, et al., 2008gas phase; Stated electron affinity is the Vertical Detachment Energy; B
Deltar17. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
Deltar20. ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B,M
Deltar13.4kJ/molN/AGomez, Taylor, et al., 2002gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B
Deltar23.4 ± 0.42kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar56.1J/mol*KPHPMSHiraoka, Mizuse, et al., 1987gas phase; M
Deltar76.1J/mol*KHPMSKeesee, Lee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Deltar3. ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B
Deltar3.3 ± 0.42kJ/molTDAsBanic and Iribarne, 1985gas phase; B,M
Deltar1.7 ± 0.42kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B

(Iodide bullet 2Water) + Water = (Iodide bullet 3Water)

By formula: (I- bullet 2H2O) + H2O = (I- bullet 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar38.9 ± 1.3kJ/molTDAsKeesee and Castleman, 1980gas phase; B,M
Deltar36. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Deltar38.5 ± 0.84kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar39. ± 4.2kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Deltar39. ± 4.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar85.4J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Deltar87.9J/mol*KHPMSKeesee and Castleman, 1980gas phase; M
Deltar89.1J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Deltar12.6kJ/molTDAsKeesee and Castleman, 1980gas phase; B
Deltar13.0 ± 3.3kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Deltar14. ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

Iodide + Acetonitrile = (Iodide bullet Acetonitrile)

By formula: I- + C2H3N = (I- bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar49.8 ± 8.4kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
Deltar46.4 ± 1.7kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
Deltar46.4 ± 4.6kJ/molLPESDessent, Bailey, et al., 1995gas phase; B
Deltar46.02 ± 0.84kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar50.kJ/molPHPMSCaldwell, Masucci, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar57.7J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Deltar76.1J/mol*KPHPMSYamdagni and Kebarle, 1972gas phase; M
Quantity Value Units Method Reference Comment
Deltar27. ± 8.4kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B
Deltar28. ± 8.4kJ/molIMRETanabe, Morgon, et al., 1996gas phase; Anchored to H2O..I- of Caldwell and Kebarle, 1984; B
Deltar28.9 ± 2.1kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

Iodide + Methyl Alcohol = (Iodide bullet Methyl Alcohol)

By formula: I- + CH4O = (I- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar49.79 ± 0.84kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar47.3 ± 4.2kJ/molTDAsCaldwell and Kebarle, 1984gas phase; B,M
Deltar46.9kJ/molPHPMSHiraoka and Yamabe, 1991gas phase; M
Deltar46.kJ/molPHPMSCaldwell, Masucci, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar71.5J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Deltar74.5J/mol*KPHPMSCaldwell and Kebarle, 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar24.1kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar25. ± 4.2kJ/molTDAsCaldwell and Kebarle, 1984gas phase; B
Deltar24. ± 8.4kJ/molIMRETanabe, Morgon, et al., 1996gas phase; Anchored to H2O..I- of Caldwell and Kebarle, 1984; B

Iodide + Methane, iodo- = (Iodide bullet Methane, iodo-)

By formula: I- + CH3I = (I- bullet CH3I)

Quantity Value Units Method Reference Comment
Deltar35.7 ± 0.84kJ/molN/AVan Duzor, Wei, et al., 2010gas phase; B
Deltar32.6 ± 0.84kJ/molTDAsHiraoka, Fujita, et al., 1905gas phase; B
Deltar35.1 ± 2.1kJ/molN/AArnold, Neumark, et al., 1995gas phase; ZEKE data, shift relative to bare I-; B
Deltar34.7 ± 2.1kJ/molPDisCyr, Bishea, et al., 1992gas phase; B
Deltar38. ± 8.4kJ/molTDAsDougherty and Roberts, 1974gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar68.6J/mol*KHPMSDougherty and Roberts, 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar11.4 ± 0.84kJ/molTDAsHiraoka, Fujita, et al., 1905gas phase; B
Deltar17.2 ± 1.3kJ/molTDAsDougherty and Roberts, 1974gas phase; B

(Iodide bullet Acetonitrile) + Acetonitrile = (Iodide bullet 2Acetonitrile)

By formula: (I- bullet C2H3N) + C2H3N = (I- bullet 2C2H3N)

Quantity Value Units Method Reference Comment
Deltar43.51 ± 0.84kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar46.4 ± 2.9kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
Deltar46.4 ± 1.7kJ/molN/ADessent, Bailey, et al., 1995gas phase; Vertical Detachment Energy: 2.25±0.08 eV.; B
Deltar43.93kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar77.0J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Deltar87.0J/mol*KPHPMSYamdagni and Kebarle, 1972gas phase; M
Quantity Value Units Method Reference Comment
Deltar20.5 ± 3.3kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Deltar18.0kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B

Iodide + Sulfur dioxide = (Iodide bullet Sulfur dioxide)

By formula: I- + O2S = (I- bullet O2S)

Quantity Value Units Method Reference Comment
Deltar59.8 ± 8.4kJ/molTDAsCaldwell and Kebarle, 1985gas phase; B,M
Deltar53.97 ± 0.42kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar73.6J/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; M
Deltar84.5J/mol*KHPMSKeesee, Lee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Deltar38. ± 11.kJ/molTDAsCaldwell and Kebarle, 1985gas phase; B
Deltar7.11 ± 0.42kJ/molTDAsBanic and Iribarne, 1985gas phase; B
Deltar28.5 ± 0.84kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
38.301.HPMSBanic and Iribarne, 1985gas phase; electric fields; M

(Iodide bullet 2Carbon dioxide) + Carbon dioxide = (Iodide bullet 3Carbon dioxide)

By formula: (I- bullet 2CO2) + CO2 = (I- bullet 3CO2)

Quantity Value Units Method Reference Comment
Deltar9.20kJ/molN/AGomez, Taylor, et al., 2002gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B
Deltar15. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
Deltar19. ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar77.0J/mol*KPHPMSHiraoka, Mizuse, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar-3. ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B

(Iodide bullet 4Carbon dioxide) + Carbon dioxide = (Iodide bullet 5Carbon dioxide)

By formula: (I- bullet 4CO2) + CO2 = (I- bullet 5CO2)

Quantity Value Units Method Reference Comment
Deltar7.11kJ/molN/AGomez, Taylor, et al., 2002gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B
Deltar13. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
Deltar18. ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar79.5J/mol*KPHPMSHiraoka, Mizuse, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar-5.9 ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B

(Iodide bullet Carbon dioxide) + Carbon dioxide = (Iodide bullet 2Carbon dioxide)

By formula: (I- bullet CO2) + CO2 = (I- bullet 2CO2)

Quantity Value Units Method Reference Comment
Deltar15. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
Deltar20. ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B,M
Deltar10.9kJ/molN/AGomez, Taylor, et al., 2002gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B
Quantity Value Units Method Reference Comment
Deltar72.4J/mol*KPHPMSHiraoka, Mizuse, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar3. ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B

(Iodide bullet 3Water) + Water = (Iodide bullet 4Water)

By formula: (I- bullet 3H2O) + H2O = (I- bullet 4H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar38.5 ± 1.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar29. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Quantity Value Units Method Reference Comment
Deltar98.7J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar8.8 ± 6.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Deltar9.2 ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

(Iodide bullet 5Carbon dioxide) + Carbon dioxide = (Iodide bullet 6Carbon dioxide)

By formula: (I- bullet 5CO2) + CO2 = (I- bullet 6CO2)

Quantity Value Units Method Reference Comment
Deltar13. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
Deltar7.53kJ/molN/AGomez, Taylor, et al., 2002gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B
Deltar18.kJ/molPHPMSHiraoka, Mizuse, et al., 1987gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar79.J/mol*KN/AHiraoka, Mizuse, et al., 1987gas phase; Entropy change calculated or estimated; M

(Iodide bullet 2Acetonitrile) + Acetonitrile = (Iodide bullet 3Acetonitrile)

By formula: (I- bullet 2C2H3N) + C2H3N = (I- bullet 3C2H3N)

Quantity Value Units Method Reference Comment
Deltar38.5 ± 0.84kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar40.6 ± 2.9kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
Deltar38.9kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar83.3J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Deltar92.5J/mol*KPHPMSYamdagni and Kebarle, 1972gas phase; M
Quantity Value Units Method Reference Comment
Deltar13.4 ± 3.3kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Deltar11.3kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B

(Iodide bullet 4Water) + Water = (Iodide bullet 5Water)

By formula: (I- bullet 4H2O) + H2O = (I- bullet 5H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar37.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; Entropy estimated; B,M
Deltar17.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KN/AHiraoka, Mizuse, et al., 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar6.28kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; Entropy estimated; B

Iodide + Ethanol = (Iodide bullet Ethanol)

By formula: I- + C2H6O = (I- bullet C2H6O)

Quantity Value Units Method Reference Comment
Deltar54.39 ± 0.84kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar50.6 ± 4.2kJ/molTDAsCaldwell and Kebarle, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar79.1J/mol*KPHPMSCaldwell and Kebarle, 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar25.6kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar27. ± 4.2kJ/molTDAsCaldwell and Kebarle, 1984gas phase; B
Deltar25. ± 8.4kJ/molIMRETanabe, Morgon, et al., 1996gas phase; Anchored to H2O..I- of Caldwell and Kebarle, 1984; B

(Iodide bullet 3Carbon dioxide) + Carbon dioxide = (Iodide bullet 4Carbon dioxide)

By formula: (I- bullet 3CO2) + CO2 = (I- bullet 4CO2)

Quantity Value Units Method Reference Comment
Deltar7.53kJ/molN/AGomez, Taylor, et al., 2002gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B
Deltar15. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
Deltar19. ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B
Quantity Value Units Method Reference Comment
Deltar-4.2 ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B

Iodide + Iodine = I3-

By formula: I- + I2 = I3-

Quantity Value Units Method Reference Comment
Deltar136. ± 10.kJ/molN/ATaylor, Asmis, et al., 1999gas phase; B
Deltar126. ± 5.9kJ/molCIDTDo, Klein, et al., 1997gas phase; B
Deltar356.1kJ/molTherFinch, Gates, et al., 1977gas phase; This value is far more bound than expected from other studies; B
Deltar136.4kJ/molN/ACheck, Faust, et al., 2001gas phase; FeF3-(t); ; «DELTA»S(EA)=2.8; B
Quantity Value Units Method Reference Comment
Deltar94.14kJ/molN/ACheck, Faust, et al., 2001gas phase; FeF3-(t); ; «DELTA»S(EA)=2.8; B

Iodide + Phenol, 4-chloro- = (Iodide bullet Phenol, 4-chloro-)

By formula: I- + C6H5ClO = (I- bullet C6H5ClO)

Quantity Value Units Method Reference Comment
Deltar85.8 ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar88.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar48.5 ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
48.5423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Iodide + Phenol, 3-chloro- = (Iodide bullet Phenol, 3-chloro-)

By formula: I- + C6H5ClO = (I- bullet C6H5ClO)

Quantity Value Units Method Reference Comment
Deltar88.3 ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar88.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar51.0 ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
51.0423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Iodide + Phenol, 4-fluoro- = (Iodide bullet Phenol, 4-fluoro-)

By formula: I- + C6H5FO = (I- bullet C6H5FO)

Quantity Value Units Method Reference Comment
Deltar82.0 ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar88.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar44.8 ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
43.9423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Iodide + Phenol, 3-fluoro- = (Iodide bullet Phenol, 3-fluoro-)

By formula: I- + C6H5FO = (I- bullet C6H5FO)

Quantity Value Units Method Reference Comment
Deltar81.2 ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar88.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar43.9 ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
44.8423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Iodide + Phenol, 3-nitro- = (Iodide bullet Phenol, 3-nitro-)

By formula: I- + C6H5NO3 = (I- bullet C6H5NO3)

Quantity Value Units Method Reference Comment
Deltar97.1 ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar88.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar59.8 ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
59.8423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Iodide + Benzonitrile, 4-hydroxy- = (Iodide bullet Benzonitrile, 4-hydroxy-)

By formula: I- + C7H5NO = (I- bullet C7H5NO)

Quantity Value Units Method Reference Comment
Deltar99.6 ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar88.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar62.3 ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
62.3423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Iodide + Benzonitrile, 3-hydroxy- = (Iodide bullet Benzonitrile, 3-hydroxy-)

By formula: I- + C7H5NO = (I- bullet C7H5NO)

Quantity Value Units Method Reference Comment
Deltar96.2 ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar88.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar59.0 ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
59.0423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Iodide + p-Cresol = (Iodide bullet p-Cresol)

By formula: I- + C7H8O = (I- bullet C7H8O)

Quantity Value Units Method Reference Comment
Deltar68.6 ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar88.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar31. ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
31.423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Iodide + Phenol = (Iodide bullet Phenol)

By formula: I- + C6H6O = (I- bullet C6H6O)

Quantity Value Units Method Reference Comment
Deltar72.4 ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar88.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar35. ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
35.423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Iodide + Hydrogen bromide = (Iodide bullet Hydrogen bromide)

By formula: I- + HBr = (I- bullet HBr)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar67.4 ± 8.4kJ/molTDEqCaldwell and Kebarle, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar82.0J/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; switching reaction(I-)SO2; M
Quantity Value Units Method Reference Comment
Deltar43. ± 11.kJ/molTDEqCaldwell and Kebarle, 1985gas phase; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
42.7300.PHPMSCaldwell and Kebarle, 1985gas phase; switching reaction(I-)SO2; M

Iodide + Hydrogen iodide = (Iodide bullet Hydrogen iodide)

By formula: I- + HI = (I- bullet HI)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar71.1 ± 8.4kJ/molTDEqCaldwell and Kebarle, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar102.J/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; switching reaction(I-)SO2; M
Quantity Value Units Method Reference Comment
Deltar41. ± 11.kJ/molTDEqCaldwell and Kebarle, 1985gas phase; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
41.300.PHPMSCaldwell and Kebarle, 1985gas phase; switching reaction(I-)SO2; M

Iodide + Hydrogen cation = Hydrogen iodide

By formula: I- + H+ = HI

Quantity Value Units Method Reference Comment
Deltar1315.24 ± 0.084kJ/molD-EAPelaez, Blondel, et al., 2009gas phase; Given: 3.0590463(38) eV; B
Deltar1312.1kJ/molN/ACheck, Faust, et al., 2001gas phase; Fe(CO)2-(q); ; «DELTA»S(EA)=5.0; B
Quantity Value Units Method Reference Comment
Deltar1294.03 ± 0.25kJ/molH-TSPelaez, Blondel, et al., 2009gas phase; Given: 3.0590463(38) eV; B
Deltar1290.8kJ/molN/ACheck, Faust, et al., 2001gas phase; Fe(CO)2-(q); ; «DELTA»S(EA)=5.0; B

Iodide + Hydrogen chloride = (Iodide bullet Hydrogen chloride)

By formula: I- + HCl = (I- bullet HCl)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar61.9 ± 8.4kJ/molTDAsCaldwell and Kebarle, 1985gas phase; B,M
Deltar59.4kJ/molHPMSKeesee, Lee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Deltar83.7J/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; M
Deltar95.0J/mol*KHPMSKeesee, Lee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Deltar37. ± 11.kJ/molTDAsCaldwell and Kebarle, 1985gas phase; B

(Iodide bullet 2Nitrous oxide) + Nitrous oxide = (Iodide bullet 3Nitrous oxide)

By formula: (I- bullet 2N2O) + N2O = (I- bullet 3N2O)

Quantity Value Units Method Reference Comment
Deltar11. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
Deltar13.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar63.J/mol*KN/AHiraoka, Aruga, et al., 1993gas phase; Entropy change calculated or estimated; M

(Iodide bullet 2Methyl Alcohol) + Methyl Alcohol = (Iodide bullet 3Methyl Alcohol)

By formula: (I- bullet 2CH4O) + CH4O = (I- bullet 3CH4O)

Quantity Value Units Method Reference Comment
Deltar32.2 ± 2.5kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar41. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar93.7J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar14.3kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar13. ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Iodide bullet Methyl Alcohol) + Methyl Alcohol = (Iodide bullet 2Methyl Alcohol)

By formula: (I- bullet CH4O) + CH4O = (I- bullet 2CH4O)

Quantity Value Units Method Reference Comment
Deltar39.7 ± 0.84kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar46.4 ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar94.6J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar17.8kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar18. ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B

Iodide + Formic acid = (Iodide bullet Formic acid)

By formula: I- + CH2O2 = (I- bullet CH2O2)

Quantity Value Units Method Reference Comment
Deltar79.1 ± 4.2kJ/molTDAsCaldwell and Kebarle, 1984gas phase; B,M
Deltar54.0 ± 8.8kJ/molCIDTWalker and Sunderlin, 1999gas phase; Authors suggest real value somewhere between this and Caldwell and Kebarle, 1984; B
Quantity Value Units Method Reference Comment
Deltar86.6J/mol*KPHPMSCaldwell and Kebarle, 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar53.1 ± 4.2kJ/molTDAsCaldwell and Kebarle, 1984gas phase; B

Iodide + Isopropyl Alcohol = (Iodide bullet Isopropyl Alcohol)

By formula: I- + C3H8O = (I- bullet C3H8O)

Quantity Value Units Method Reference Comment
Deltar54.81 ± 0.84kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar51.0 ± 4.2kJ/molTDAsCaldwell and Kebarle, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar79.9J/mol*KPHPMSCaldwell and Kebarle, 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar26.5kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar27. ± 4.2kJ/molTDAsCaldwell and Kebarle, 1984gas phase; B

Iodide + 2-Propanol, 2-methyl- = (Iodide bullet 2-Propanol, 2-methyl-)

By formula: I- + C4H10O = (I- bullet C4H10O)

Quantity Value Units Method Reference Comment
Deltar54.8 ± 1.3kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar50.6 ± 4.2kJ/molTDAsCaldwell and Kebarle, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar78.2J/mol*KPHPMSCaldwell and Kebarle, 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar25.7kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar27. ± 4.2kJ/molTDAsCaldwell and Kebarle, 1984gas phase; B

Iodide + Ammonia = (Iodide bullet Ammonia)

By formula: I- + H3N = (I- bullet H3N)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar31.0 ± 1.3kJ/molTDAsEvans, Keesee, et al., 1987gas phase; B,M
Deltar31. ± 4.2kJ/molTDAsCaldwell, Masucci, et al., 1989gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar87.4J/mol*KHPMSEvans, Keesee, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar5.0 ± 2.5kJ/molTDAsEvans, Keesee, et al., 1987gas phase; B

(Iodide bullet 6Carbon dioxide) + Carbon dioxide = (Iodide bullet 7Carbon dioxide)

By formula: (I- bullet 6CO2) + CO2 = (I- bullet 7CO2)

Quantity Value Units Method Reference Comment
Deltar14. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
Deltar7.95kJ/molN/AGomez, Taylor, et al., 2002gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B

(Iodide bullet 7Carbon dioxide) + Carbon dioxide = (Iodide bullet 8Carbon dioxide)

By formula: (I- bullet 7CO2) + CO2 = (I- bullet 8CO2)

Quantity Value Units Method Reference Comment
Deltar13. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
Deltar7.95kJ/molN/AGomez, Taylor, et al., 2002gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B

(Iodide bullet Nitrous oxide) + Nitrous oxide = (Iodide bullet 2Nitrous oxide)

By formula: (I- bullet N2O) + N2O = (I- bullet 2N2O)

Quantity Value Units Method Reference Comment
Deltar12. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
Deltar14. ± 1.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar59.4J/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(Iodide bullet 7Methyl Alcohol) + Methyl Alcohol = (Iodide bullet 8Methyl Alcohol)

By formula: (I- bullet 7CH4O) + CH4O = (I- bullet 8CH4O)

Quantity Value Units Method Reference Comment
Deltar38. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; Entropy estimated.; B,M
Quantity Value Units Method Reference Comment
Deltar120.J/mol*KN/AHiraoka and Yamabe, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar3. ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; Entropy estimated.; B

(Iodide bullet 3Acetonitrile) + Acetonitrile = (Iodide bullet 4Acetonitrile)

By formula: (I- bullet 3C2H3N) + C2H3N = (I- bullet 4C2H3N)

Quantity Value Units Method Reference Comment
Deltar32.6 ± 0.42kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar31.0 ± 3.3kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar80.8J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar8.4 ± 1.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

(Iodide bullet 4Acetonitrile) + Acetonitrile = (Iodide bullet 5Acetonitrile)

By formula: (I- bullet 4C2H3N) + C2H3N = (I- bullet 5C2H3N)

Quantity Value Units Method Reference Comment
Deltar29.7 ± 1.3kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar44.4 ± 3.8kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar79.1J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar5.9 ± 5.9kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

Iodide + Nitrous oxide = (Iodide bullet Nitrous oxide)

By formula: I- + N2O = (I- bullet N2O)

Quantity Value Units Method Reference Comment
Deltar11. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
Deltar16. ± 1.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar59.0J/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

Iodide + Benzene = (Iodide bullet Benzene)

By formula: I- + C6H6 = (I- bullet C6H6)

Quantity Value Units Method Reference Comment
Deltar26. ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B,M
Deltar38. ± 4.2kJ/molTDAsCaldwell, Masucci, et al., 1989gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar59.4J/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar8. ± 11.kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B

Iodide + Dimethyl Sulfoxide = (Iodide bullet Dimethyl Sulfoxide)

By formula: I- + C2H6OS = (I- bullet C2H6OS)

Quantity Value Units Method Reference Comment
Deltar65.69kJ/molTDAsMagnera, Caldwell, et al., 1984gas phase; B,M
Deltar67.kJ/molPHPMSCaldwell, Masucci, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar90.8J/mol*KPHPMSMagnera, Caldwell, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar38.5kJ/molTDAsMagnera, Caldwell, et al., 1984gas phase; B

Iodide = BrI2-

By formula: I- = BrI2-

Quantity Value Units Method Reference Comment
Deltar141.8 ± 0.96kJ/molPDisCrider, Harrison, et al., 2011gas phase; B
Deltar149.4kJ/molN/ACheck, Faust, et al., 2001gas phase; FeF2-(q); ; «DELTA»S(EA)=4.5; B
Quantity Value Units Method Reference Comment
Deltar107.9kJ/molN/ACheck, Faust, et al., 2001gas phase; FeF2-(q); ; «DELTA»S(EA)=4.5; B

Iodide + Xenon = IXe-

By formula: I- + Xe = IXe-

Quantity Value Units Method Reference Comment
Deltar6.69kJ/molN/ALenzer, Furlanetto, et al., 1998gas phase; B
Deltar11.7kJ/molTDAsWada, Kikkawa, et al., 2007gas phase; Entropy estimated; B
Quantity Value Units Method Reference Comment
Deltar-8.24kJ/molTDAsWada, Kikkawa, et al., 2007gas phase; Entropy estimated; B

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Hiraoka, Mizuse, et al., 1988
Hiraoka, K.; Mizuse, S.; Yamabe, S., Solvation of Halide Ions with H2O and CH3CN in the Gas Phase, J. Phys. Chem., 1988, 92, 13, 3943, https://doi.org/10.1021/j100324a051 . [all data]

Keesee and Castleman, 1980
Keesee, R.G.; Castleman, A.W., Jr., Gas phase studies of hydration complexes of Cl- and I- and comparison to electrostatic calculations in the gas phase, Chem. Phys. Lett., 1980, 74, 139. [all data]

Arshadi, Yamdagni, et al., 1970
Arshadi, M.; Yamdagni, R.; Kebarle, P., Hydration of Halide Negative Ions in the Gas Phase. II. Comparison of Hydration Energies for the Alkali Positive and Halide Negative Ions, J. Phys. Chem., 1970, 74, 7, 1475, https://doi.org/10.1021/j100702a014 . [all data]

Banic and Iribarne, 1985
Banic, C.M.; Iribarne, J.V., Equilibrium Constants for Clustering of Neutral Molecules about Gaseous Ions, J. Chem. Phys., 1985, 83, 12, 6432, https://doi.org/10.1063/1.449543 . [all data]

Markovich, Pollack, et al., 1994
Markovich, G.; Pollack, S.; Giniger, R.; Cheshnovsky, O., Photoelectron spectroscopy of Cl-, Br-, and I- solvated in water clusters, J. Chem. Phys., 1994, 101, 11, 9344, https://doi.org/10.1063/1.467965 . [all data]

Payzant, Yamdagni, et al., 1971
Payzant, J.D.; Yamdagni, R.; Kebarle, P., Hydration of CN-, NO2-, NO3-, and HO- in the gas phase, Can. J. Chem., 1971, 49, 3308. [all data]

Piani, Becucci, et al., 2008
Piani, G.; Becucci, M.; Bowen, M.S.; Oakman, J.; Hu, Q.; Continetti, R.E., Photodetachment and dissociation dynamics of microsolvated iodide clusters, Phys. Scripta, 2008, 78, 5, 058110, https://doi.org/10.1088/0031-8949/78/05/058110 . [all data]

Arnold, Bradforth, et al., 1995
Arnold, D.W.; Bradforth, S.E.; Kim, E.H.; Neumark, D.M., Study of I-(CO2)n, Br-(CO2)n, and I-(N2O)n clusters by anion photoelectron spectroscopy, J. Chem. Phys., 1995, 102, 9, 3510, https://doi.org/10.1063/1.468576 . [all data]

Hiraoka, Mizuse, et al., 1987
Hiraoka, K.; Mizuse, S.; Yamabe, S., Stability and Structure of Cluster Ions: Halide Ions with CO2, J. Chem. Phys., 1987, 87, 6, 3647, https://doi.org/10.1063/1.452962 . [all data]

Gomez, Taylor, et al., 2002
Gomez, H.; Taylor, T.R.; Neumark, D.M., Anion photoelectron spectroscopy of I-2(-)(CO2)(n)(n=1-8) clusters, J. Chem. Phys., 2002, 116, 14, 6111-6117, https://doi.org/10.1063/1.1458246 . [all data]

Keesee, Lee, et al., 1980
Keesee, R.G.; Lee, N.; Castleman, A.W., Jr., Properties of clusters in the gas phase: V. Complexes of neutral molecules onto negative ions, J. Chem. Phys., 1980, 73, 2195. [all data]

Kebarle, Arshadi, et al., 1968
Kebarle, P.; Arshadi, M.; Scarborough, J., Hydration of Negative Ions in the Gas Phase, J. Chem. Phys., 1968, 49, 2, 817, https://doi.org/10.1063/1.1670145 . [all data]

Yamdagni and Kebarle, 1972
Yamdagni, R.; Kebarle, P., Solvation of negative ions by protic and aprotic solvents. Gas phase solvation of halide ions by acetonitrile and water molecules, J. Am. Chem. Soc., 1972, 94, 2940. [all data]

Markovich, Perera, et al., 1996
Markovich, G.; Perera, L.; Berkowitz, M.L.; Cheshnovsky, O., The Solvation of Cl-, Br-, and I- in Acetonitrile Cluster: Photoelectron Spectroscopy and Molecular Dynamics Simulations., J. Chem. Phys., 1996, 105, 7, 2675, https://doi.org/10.1063/1.472131 . [all data]

Dessent, Bailey, et al., 1995
Dessent, C.E.H.; Bailey, C.G.; Johnson, M.A., Dipole-bound excited states of the I-center dot CH3CN and I-center dot(CH3CN)2 ion-molecule complexes: Evidence for asymmetric solvation, J. Chem. Phys., 1995, 103, 6, 2006, https://doi.org/10.1063/1.469727 . [all data]

Caldwell, Masucci, et al., 1989
Caldwell, G.W.; Masucci, J.A.; Ikonomou, M.G., Negative Ion Chemical Ionization Mass Spectrometry - Binding of Molecules to Bromide and Iodide Anions, Org. Mass Spectrom., 1989, 24, 1, 8, https://doi.org/10.1002/oms.1210240103 . [all data]

Tanabe, Morgon, et al., 1996
Tanabe, F.K.J.; Morgon, N.H.; Riveros, J.M., Relative Bromide and Iodide Affinity of Simple Solvent Molecules Determined by FT-ICR, J. Phys. Chem., 1996, 100, 8, 2862-2866, https://doi.org/10.1021/jp952290p . [all data]

Caldwell and Kebarle, 1984
Caldwell, G.; Kebarle, P., Binding energies and structural effects in halide anion-ROH and -RCOOH complexes from gas phase equilibria measurements, J. Am. Chem. Soc., 1984, 106, 967. [all data]

Bogdanov, Peschke, et al., 1999
Bogdanov, B.; Peschke, M.; Tonner, D.S.; Szulejko, J.E.; McMahon, T.B., Stepwise solvation of halides by alcohol molecules in the gas phase, Int. J. Mass Spectrom., 1999, 187, 707-725, https://doi.org/10.1016/S1387-3806(98)14180-5 . [all data]

Hiraoka and Yamabe, 1991
Hiraoka, K.; Yamabe, S., Solvation of Halide Ions with CH3OH in the gas Phase, Int. J. Mass Spectrom. Ion Proc., 1991, 109, 133, https://doi.org/10.1016/0168-1176(91)85101-Q . [all data]

Van Duzor, Wei, et al., 2010
Van Duzor, M.; Wei, J.; Mbaiwa, F.; Mabbs, R., I-center dot CH3X (X=Cl, Br, I) photodetachment: The effect of electron-molecule interactions in cluster anion photodetachment spectra and angular distributions, J. Chem. Phys., 2010, 133, 14, 144303, https://doi.org/10.1063/1.3487739 . [all data]

Hiraoka, Fujita, et al., 1905
Hiraoka, K.; Fujita, K.; Ishida, M.; Ichikawa, T.; Okada, H.; Hiizumi, K.; Wada, A.; Takao, K.; Yamabe, S.; Tsuchida, N., Gas-phase Ion/Molecule Reactions in C5F8, J. Phys. Chem. A (2005), 1905, 109, 6, 1049-1056., https://doi.org/10.1021/jp040251k . [all data]

Arnold, Neumark, et al., 1995
Arnold, C.C.; Neumark, D.M.; Cyr, D.M.; Johnson, M.A., Negative ion zero electron kinetic energy spectroscopy of I-center dot CH3I, J. Phys. Chem., 1995, 99, 6, 1633, https://doi.org/10.1021/j100006a002 . [all data]

Cyr, Bishea, et al., 1992
Cyr, D.M.; Bishea, G.A.; Scarton, M.G.; Johnson, M.A., Observation of Charge-Transfer Excited States in the I-.CH3I, I-.CH3Br, and I-.CH2Br2 S(N)2 Reaction Intermediates Using Photofragmentation, J. Chem. Phys., 1992, 97, 8, 5911, https://doi.org/10.1063/1.463752 . [all data]

Dougherty and Roberts, 1974
Dougherty, R.C.; Roberts, J.D., SN2 reactions in the gas phase. Nucleophilicity effects, Org. Mass Spectrom., 1974, 8, 81. [all data]

Caldwell and Kebarle, 1985
Caldwell, G.; Kebarle, P., The hydrogen bond energies of the bihalide ions XHX- and YHX-, Can. J. Chem., 1985, 63, 1399. [all data]

Taylor, Asmis, et al., 1999
Taylor, T.R.; Asmis, K.R.; Zanni, M.T.; Neumark, D.M., Characterization of the I-3 radical by anion photoelectron spectroscopy, J. Chem. Phys., 1999, 110, 16, 7607-7609, https://doi.org/10.1063/1.478672 . [all data]

Do, Klein, et al., 1997
Do, K.; Klein, T.P.; Pommerening, C.A.; Sunderlin, L.S., A New Flowing Afterglow-Guided Ion Beam Tandem Mass Spectrometer. Applications to the Thermochemistry of Polyiodide Ions, J. Am. Soc. Mass Spectrom., 1997, 8, 7, 688, https://doi.org/10.1016/S1044-0305(97)00116-5 . [all data]

Finch, Gates, et al., 1977
Finch, A.; Gates, P.N.; Peake, S.J., Thermochemistry of polyhalides. III. Cesium and rubidium tetrachloroiodates, J. Inorg. Nucl. Chem., 1977, 39, 2135. [all data]

Check, Faust, et al., 2001
Check, C.E.; Faust, T.O.; Bailey, J.M.; Wright, B.J.; Gilbert, T.M.; Sunderlin, L.S., Addition of Polarization and Diffuse Functions to the LANL2DZ Basis Set for P-Block Elements, J. Phys. Chem. A,, 2001, 105, 34, 8111, https://doi.org/10.1021/jp011945l . [all data]

Paul and Kebarle, 1990
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Notes

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