Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Iodide


Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 1 to 50

Iodide + Water = (Iodide bullet Water)

By formula: I- + H2O = (I- bullet H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar10.4 ± 0.7kcal/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Deltar15.3cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Deltar19.3cal/mol*KHPMSKeesee and Castleman, 1980gas phase; M
Deltar16.3cal/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Deltar5.5 ± 0.3kcal/molAVGN/AAverage of 6 values; Individual data points

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
5.3300.HPMSBanic and Iribarne, 1985gas phase; electric fields; M

(Iodide bullet Water) + Water = (Iodide bullet 2Water)

By formula: (I- bullet H2O) + H2O = (I- bullet 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar9.90 ± 0.20kcal/molTDAsKeesee and Castleman, 1980gas phase; B,M
Deltar9.50kcal/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Deltar9.50 ± 0.20kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar9.8 ± 1.0kcal/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Deltar9.8 ± 1.0kcal/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar17.6cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Deltar20.3cal/mol*KHPMSKeesee and Castleman, 1980gas phase; M
Deltar19.0cal/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Deltar4.0 ± 0.5kcal/molAVGN/AAverage of 6 values; Individual data points

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
4.1300.HPMSBanic and Iribarne, 1985gas phase; electric fields; M

Iodide + Carbon dioxide = (Iodide bullet Carbon dioxide)

By formula: I- + CO2 = (I- bullet CO2)

Quantity Value Units Method Reference Comment
Deltar3.7 ± 1.8kcal/molN/APiani, Becucci, et al., 2008gas phase; Stated electron affinity is the Vertical Detachment Energy; B
Deltar4.0 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
Deltar4.7 ± 2.0kcal/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B,M
Deltar3.20kcal/molN/AGomez, Taylor, et al., 2002gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B
Deltar5.60 ± 0.10kcal/molTDAsKeesee, Lee, et al., 1980gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar13.4cal/mol*KPHPMSHiraoka, Mizuse, et al., 1987gas phase; M
Deltar18.2cal/mol*KHPMSKeesee, Lee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Deltar0.7 ± 2.0kcal/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B
Deltar0.80 ± 0.10kcal/molTDAsBanic and Iribarne, 1985gas phase; B,M
Deltar0.40 ± 0.10kcal/molTDAsKeesee, Lee, et al., 1980gas phase; B

(Iodide bullet 2Water) + Water = (Iodide bullet 3Water)

By formula: (I- bullet 2H2O) + H2O = (I- bullet 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar9.30 ± 0.30kcal/molTDAsKeesee and Castleman, 1980gas phase; B,M
Deltar8.5 ± 2.3kcal/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Deltar9.20 ± 0.20kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar9.4 ± 1.0kcal/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Deltar9.4 ± 1.0kcal/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar20.4cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Deltar21.0cal/mol*KHPMSKeesee and Castleman, 1980gas phase; M
Deltar21.3cal/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Deltar3.00kcal/molTDAsKeesee and Castleman, 1980gas phase; B
Deltar3.10 ± 0.80kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Deltar3.3 ± 2.0kcal/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

Iodide + Acetonitrile = (Iodide bullet Acetonitrile)

By formula: I- + C2H3N = (I- bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar11.9 ± 2.0kcal/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
Deltar11.10 ± 0.40kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B
Deltar11.1 ± 1.1kcal/molLPESDessent, Bailey, et al., 1995gas phase; B
Deltar11.00 ± 0.20kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar12.kcal/molPHPMSCaldwell, Masucci, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar13.8cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Deltar18.2cal/mol*KPHPMSYamdagni and Kebarle, 1972gas phase; M
Quantity Value Units Method Reference Comment
Deltar6.4 ± 2.0kcal/molTDAsYamdagni and Kebarle, 1972gas phase; B
Deltar6.6 ± 2.0kcal/molIMRETanabe, Morgon, et al., 1996gas phase; Anchored to H2O..I- of Caldwell and Kebarle, 1984; B
Deltar6.90 ± 0.50kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

Iodide + Methyl Alcohol = (Iodide bullet Methyl Alcohol)

By formula: I- + CH4O = (I- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar11.90 ± 0.20kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar11.3 ± 1.0kcal/molTDAsCaldwell and Kebarle, 1984gas phase; B,M
Deltar11.2kcal/molPHPMSHiraoka and Yamabe, 1991gas phase; M
Deltar11.kcal/molPHPMSCaldwell, Masucci, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar17.1cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Deltar17.8cal/mol*KPHPMSCaldwell and Kebarle, 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar5.76kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar6.0 ± 1.0kcal/molTDAsCaldwell and Kebarle, 1984gas phase; B
Deltar5.7 ± 2.0kcal/molIMRETanabe, Morgon, et al., 1996gas phase; Anchored to H2O..I- of Caldwell and Kebarle, 1984; B

Iodide + Methane, iodo- = (Iodide bullet Methane, iodo-)

By formula: I- + CH3I = (I- bullet CH3I)

Quantity Value Units Method Reference Comment
Deltar8.53 ± 0.20kcal/molN/AVan Duzor, Wei, et al., 2010gas phase; B
Deltar7.80 ± 0.20kcal/molTDAsHiraoka, Fujita, et al., 1905gas phase; B
Deltar8.40 ± 0.50kcal/molN/AArnold, Neumark, et al., 1995gas phase; ZEKE data, shift relative to bare I-; B
Deltar8.30 ± 0.50kcal/molPDisCyr, Bishea, et al., 1992gas phase; B
Deltar9.0 ± 2.0kcal/molTDAsDougherty and Roberts, 1974gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar16.4cal/mol*KHPMSDougherty and Roberts, 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar2.73 ± 0.20kcal/molTDAsHiraoka, Fujita, et al., 1905gas phase; B
Deltar4.10 ± 0.30kcal/molTDAsDougherty and Roberts, 1974gas phase; B

(Iodide bullet Acetonitrile) + Acetonitrile = (Iodide bullet 2Acetonitrile)

By formula: (I- bullet C2H3N) + C2H3N = (I- bullet 2C2H3N)

Quantity Value Units Method Reference Comment
Deltar10.40 ± 0.20kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar11.10 ± 0.70kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B
Deltar11.10 ± 0.40kcal/molN/ADessent, Bailey, et al., 1995gas phase; Vertical Detachment Energy: 2.25±0.08 eV.; B
Deltar10.50kcal/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar18.4cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Deltar20.8cal/mol*KPHPMSYamdagni and Kebarle, 1972gas phase; M
Quantity Value Units Method Reference Comment
Deltar4.90 ± 0.80kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Deltar4.30kcal/molTDAsYamdagni and Kebarle, 1972gas phase; B

Iodide + Sulfur dioxide = (Iodide bullet Sulfur dioxide)

By formula: I- + O2S = (I- bullet O2S)

Quantity Value Units Method Reference Comment
Deltar14.3 ± 2.0kcal/molTDAsCaldwell and Kebarle, 1985gas phase; B,M
Deltar12.90 ± 0.10kcal/molTDAsKeesee, Lee, et al., 1980gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar17.6cal/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; M
Deltar20.2cal/mol*KHPMSKeesee, Lee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Deltar9.0 ± 2.6kcal/molTDAsCaldwell and Kebarle, 1985gas phase; B
Deltar1.70 ± 0.10kcal/molTDAsBanic and Iribarne, 1985gas phase; B
Deltar6.80 ± 0.20kcal/molTDAsKeesee, Lee, et al., 1980gas phase; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
9.0301.HPMSBanic and Iribarne, 1985gas phase; electric fields; M

(Iodide bullet 2Carbon dioxide) + Carbon dioxide = (Iodide bullet 3Carbon dioxide)

By formula: (I- bullet 2CO2) + CO2 = (I- bullet 3CO2)

Quantity Value Units Method Reference Comment
Deltar2.20kcal/molN/AGomez, Taylor, et al., 2002gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B
Deltar3.7 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
Deltar4.6 ± 1.0kcal/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar18.4cal/mol*KPHPMSHiraoka, Mizuse, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar-0.6 ± 2.0kcal/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B

(Iodide bullet 4Carbon dioxide) + Carbon dioxide = (Iodide bullet 5Carbon dioxide)

By formula: (I- bullet 4CO2) + CO2 = (I- bullet 5CO2)

Quantity Value Units Method Reference Comment
Deltar1.70kcal/molN/AGomez, Taylor, et al., 2002gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B
Deltar3.1 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
Deltar4.3 ± 1.0kcal/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar19.0cal/mol*KPHPMSHiraoka, Mizuse, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar-1.4 ± 2.0kcal/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B

(Iodide bullet Carbon dioxide) + Carbon dioxide = (Iodide bullet 2Carbon dioxide)

By formula: (I- bullet CO2) + CO2 = (I- bullet 2CO2)

Quantity Value Units Method Reference Comment
Deltar3.6 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
Deltar4.7 ± 1.0kcal/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B,M
Deltar2.60kcal/molN/AGomez, Taylor, et al., 2002gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B
Quantity Value Units Method Reference Comment
Deltar17.3cal/mol*KPHPMSHiraoka, Mizuse, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar0.7 ± 2.0kcal/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B

(Iodide bullet 3Water) + Water = (Iodide bullet 4Water)

By formula: (I- bullet 3H2O) + H2O = (I- bullet 4H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar9.20 ± 0.40kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar6.9 ± 2.3kcal/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Quantity Value Units Method Reference Comment
Deltar23.6cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar2.1 ± 1.6kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Deltar2.2 ± 2.0kcal/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

(Iodide bullet 5Carbon dioxide) + Carbon dioxide = (Iodide bullet 6Carbon dioxide)

By formula: (I- bullet 5CO2) + CO2 = (I- bullet 6CO2)

Quantity Value Units Method Reference Comment
Deltar3.0 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
Deltar1.80kcal/molN/AGomez, Taylor, et al., 2002gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B
Deltar4.2kcal/molPHPMSHiraoka, Mizuse, et al., 1987gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar19.cal/mol*KN/AHiraoka, Mizuse, et al., 1987gas phase; Entropy change calculated or estimated; M

(Iodide bullet 2Acetonitrile) + Acetonitrile = (Iodide bullet 3Acetonitrile)

By formula: (I- bullet 2C2H3N) + C2H3N = (I- bullet 3C2H3N)

Quantity Value Units Method Reference Comment
Deltar9.20 ± 0.20kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar9.70 ± 0.70kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B
Deltar9.30kcal/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar19.9cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Deltar22.1cal/mol*KPHPMSYamdagni and Kebarle, 1972gas phase; M
Quantity Value Units Method Reference Comment
Deltar3.20 ± 0.80kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Deltar2.70kcal/molTDAsYamdagni and Kebarle, 1972gas phase; B

(Iodide bullet 4Water) + Water = (Iodide bullet 5Water)

By formula: (I- bullet 4H2O) + H2O = (I- bullet 5H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar9.00kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; Entropy estimated; B,M
Deltar4.20kcal/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Quantity Value Units Method Reference Comment
Deltar25.cal/mol*KN/AHiraoka, Mizuse, et al., 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar1.50kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; Entropy estimated; B

Iodide + Ethanol = (Iodide bullet Ethanol)

By formula: I- + C2H6O = (I- bullet C2H6O)

Quantity Value Units Method Reference Comment
Deltar13.00 ± 0.20kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar12.1 ± 1.0kcal/molTDAsCaldwell and Kebarle, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar18.9cal/mol*KPHPMSCaldwell and Kebarle, 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar6.11kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar6.4 ± 1.0kcal/molTDAsCaldwell and Kebarle, 1984gas phase; B
Deltar6.0 ± 2.0kcal/molIMRETanabe, Morgon, et al., 1996gas phase; Anchored to H2O..I- of Caldwell and Kebarle, 1984; B

(Iodide bullet 3Carbon dioxide) + Carbon dioxide = (Iodide bullet 4Carbon dioxide)

By formula: (I- bullet 3CO2) + CO2 = (I- bullet 4CO2)

Quantity Value Units Method Reference Comment
Deltar1.80kcal/molN/AGomez, Taylor, et al., 2002gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B
Deltar3.6 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
Deltar4.5 ± 1.0kcal/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B
Quantity Value Units Method Reference Comment
Deltar-1.0 ± 2.0kcal/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B

Iodide + Iodine = I3-

By formula: I- + I2 = I3-

Quantity Value Units Method Reference Comment
Deltar32.5 ± 2.4kcal/molN/ATaylor, Asmis, et al., 1999gas phase; B
Deltar30.1 ± 1.4kcal/molCIDTDo, Klein, et al., 1997gas phase; B
Deltar85.10kcal/molTherFinch, Gates, et al., 1977gas phase; This value is far more bound than expected from other studies; B
Deltar32.60kcal/molN/ACheck, Faust, et al., 2001gas phase; FeF3-(t); ; «DELTA»S(EA)=2.8; B
Quantity Value Units Method Reference Comment
Deltar22.50kcal/molN/ACheck, Faust, et al., 2001gas phase; FeF3-(t); ; «DELTA»S(EA)=2.8; B

Iodide + Phenol, 4-chloro- = (Iodide bullet Phenol, 4-chloro-)

By formula: I- + C6H5ClO = (I- bullet C6H5ClO)

Quantity Value Units Method Reference Comment
Deltar20.5 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar21.cal/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar11.6 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
11.6423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Iodide + Phenol, 3-chloro- = (Iodide bullet Phenol, 3-chloro-)

By formula: I- + C6H5ClO = (I- bullet C6H5ClO)

Quantity Value Units Method Reference Comment
Deltar21.1 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar21.cal/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar12.2 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
12.2423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Iodide + Phenol, 4-fluoro- = (Iodide bullet Phenol, 4-fluoro-)

By formula: I- + C6H5FO = (I- bullet C6H5FO)

Quantity Value Units Method Reference Comment
Deltar19.6 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar21.cal/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar10.7 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
10.5423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Iodide + Phenol, 3-fluoro- = (Iodide bullet Phenol, 3-fluoro-)

By formula: I- + C6H5FO = (I- bullet C6H5FO)

Quantity Value Units Method Reference Comment
Deltar19.4 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar21.cal/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar10.5 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
10.7423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Iodide + Phenol, 3-nitro- = (Iodide bullet Phenol, 3-nitro-)

By formula: I- + C6H5NO3 = (I- bullet C6H5NO3)

Quantity Value Units Method Reference Comment
Deltar23.2 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar21.cal/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar14.3 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
14.3423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Iodide + Benzonitrile, 4-hydroxy- = (Iodide bullet Benzonitrile, 4-hydroxy-)

By formula: I- + C7H5NO = (I- bullet C7H5NO)

Quantity Value Units Method Reference Comment
Deltar23.8 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar21.cal/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar14.9 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
14.9423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Iodide + Benzonitrile, 3-hydroxy- = (Iodide bullet Benzonitrile, 3-hydroxy-)

By formula: I- + C7H5NO = (I- bullet C7H5NO)

Quantity Value Units Method Reference Comment
Deltar23.0 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar21.cal/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar14.1 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
14.1423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Iodide + p-Cresol = (Iodide bullet p-Cresol)

By formula: I- + C7H8O = (I- bullet C7H8O)

Quantity Value Units Method Reference Comment
Deltar16.4 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar21.cal/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar7.5 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
7.5423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Iodide + Phenol = (Iodide bullet Phenol)

By formula: I- + C6H6O = (I- bullet C6H6O)

Quantity Value Units Method Reference Comment
Deltar17.3 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar21.cal/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar8.4 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
8.4423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Iodide + Hydrogen bromide = (Iodide bullet Hydrogen bromide)

By formula: I- + HBr = (I- bullet HBr)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar16.1 ± 2.0kcal/molTDEqCaldwell and Kebarle, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar19.6cal/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; switching reaction(I-)SO2; M
Quantity Value Units Method Reference Comment
Deltar10.2 ± 2.6kcal/molTDEqCaldwell and Kebarle, 1985gas phase; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
10.2300.PHPMSCaldwell and Kebarle, 1985gas phase; switching reaction(I-)SO2; M

Iodide + Hydrogen iodide = (Iodide bullet Hydrogen iodide)

By formula: I- + HI = (I- bullet HI)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar17.0 ± 2.0kcal/molTDEqCaldwell and Kebarle, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar24.4cal/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; switching reaction(I-)SO2; M
Quantity Value Units Method Reference Comment
Deltar9.7 ± 2.6kcal/molTDEqCaldwell and Kebarle, 1985gas phase; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
9.7300.PHPMSCaldwell and Kebarle, 1985gas phase; switching reaction(I-)SO2; M

Iodide + Hydrogen cation = Hydrogen iodide

By formula: I- + H+ = HI

Quantity Value Units Method Reference Comment
Deltar314.350 ± 0.020kcal/molD-EAPelaez, Blondel, et al., 2009gas phase; Given: 3.0590463(38) eV; B
Deltar313.60kcal/molN/ACheck, Faust, et al., 2001gas phase; Fe(CO)2-(q); ; «DELTA»S(EA)=5.0; B
Quantity Value Units Method Reference Comment
Deltar309.280 ± 0.060kcal/molH-TSPelaez, Blondel, et al., 2009gas phase; Given: 3.0590463(38) eV; B
Deltar308.50kcal/molN/ACheck, Faust, et al., 2001gas phase; Fe(CO)2-(q); ; «DELTA»S(EA)=5.0; B

Iodide + Hydrogen chloride = (Iodide bullet Hydrogen chloride)

By formula: I- + HCl = (I- bullet HCl)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar14.8 ± 2.0kcal/molTDAsCaldwell and Kebarle, 1985gas phase; B,M
Deltar14.2kcal/molHPMSKeesee, Lee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Deltar20.0cal/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; M
Deltar22.7cal/mol*KHPMSKeesee, Lee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Deltar8.8 ± 2.6kcal/molTDAsCaldwell and Kebarle, 1985gas phase; B

(Iodide bullet 2Nitrous oxide) + Nitrous oxide = (Iodide bullet 3Nitrous oxide)

By formula: (I- bullet 2N2O) + N2O = (I- bullet 3N2O)

Quantity Value Units Method Reference Comment
Deltar2.7 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
Deltar3.2kcal/molPHPMSHiraoka, Aruga, et al., 1993gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar15.cal/mol*KN/AHiraoka, Aruga, et al., 1993gas phase; Entropy change calculated or estimated; M

(Iodide bullet 2Methyl Alcohol) + Methyl Alcohol = (Iodide bullet 3Methyl Alcohol)

By formula: (I- bullet 2CH4O) + CH4O = (I- bullet 3CH4O)

Quantity Value Units Method Reference Comment
Deltar7.70 ± 0.60kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar9.8 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar22.4cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar3.41kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar3.1 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Iodide bullet Methyl Alcohol) + Methyl Alcohol = (Iodide bullet 2Methyl Alcohol)

By formula: (I- bullet CH4O) + CH4O = (I- bullet 2CH4O)

Quantity Value Units Method Reference Comment
Deltar9.50 ± 0.20kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar11.1 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar22.6cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar4.25kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar4.4 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

Iodide + Formic acid = (Iodide bullet Formic acid)

By formula: I- + CH2O2 = (I- bullet CH2O2)

Quantity Value Units Method Reference Comment
Deltar18.9 ± 1.0kcal/molTDAsCaldwell and Kebarle, 1984gas phase; B,M
Deltar12.9 ± 2.1kcal/molCIDTWalker and Sunderlin, 1999gas phase; Authors suggest real value somewhere between this and Caldwell and Kebarle, 1984; B
Quantity Value Units Method Reference Comment
Deltar20.7cal/mol*KPHPMSCaldwell and Kebarle, 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar12.7 ± 1.0kcal/molTDAsCaldwell and Kebarle, 1984gas phase; B

Iodide + Isopropyl Alcohol = (Iodide bullet Isopropyl Alcohol)

By formula: I- + C3H8O = (I- bullet C3H8O)

Quantity Value Units Method Reference Comment
Deltar13.10 ± 0.20kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar12.2 ± 1.0kcal/molTDAsCaldwell and Kebarle, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar19.1cal/mol*KPHPMSCaldwell and Kebarle, 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar6.33kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar6.5 ± 1.0kcal/molTDAsCaldwell and Kebarle, 1984gas phase; B

Iodide + 2-Propanol, 2-methyl- = (Iodide bullet 2-Propanol, 2-methyl-)

By formula: I- + C4H10O = (I- bullet C4H10O)

Quantity Value Units Method Reference Comment
Deltar13.10 ± 0.30kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar12.1 ± 1.0kcal/molTDAsCaldwell and Kebarle, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar18.7cal/mol*KPHPMSCaldwell and Kebarle, 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar6.15kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar6.5 ± 1.0kcal/molTDAsCaldwell and Kebarle, 1984gas phase; B

Iodide + Ammonia = (Iodide bullet Ammonia)

By formula: I- + H3N = (I- bullet H3N)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar7.40 ± 0.30kcal/molTDAsEvans, Keesee, et al., 1987gas phase; B,M
Deltar7.4 ± 1.0kcal/molTDAsCaldwell, Masucci, et al., 1989gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar20.9cal/mol*KHPMSEvans, Keesee, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar1.20 ± 0.60kcal/molTDAsEvans, Keesee, et al., 1987gas phase; B

(Iodide bullet 6Carbon dioxide) + Carbon dioxide = (Iodide bullet 7Carbon dioxide)

By formula: (I- bullet 6CO2) + CO2 = (I- bullet 7CO2)

Quantity Value Units Method Reference Comment
Deltar3.3 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
Deltar1.90kcal/molN/AGomez, Taylor, et al., 2002gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B

(Iodide bullet 7Carbon dioxide) + Carbon dioxide = (Iodide bullet 8Carbon dioxide)

By formula: (I- bullet 7CO2) + CO2 = (I- bullet 8CO2)

Quantity Value Units Method Reference Comment
Deltar3.1 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
Deltar1.90kcal/molN/AGomez, Taylor, et al., 2002gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B

(Iodide bullet Nitrous oxide) + Nitrous oxide = (Iodide bullet 2Nitrous oxide)

By formula: (I- bullet N2O) + N2O = (I- bullet 2N2O)

Quantity Value Units Method Reference Comment
Deltar2.9 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
Deltar3.3 ± 0.3kcal/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar14.2cal/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(Iodide bullet 7Methyl Alcohol) + Methyl Alcohol = (Iodide bullet 8Methyl Alcohol)

By formula: (I- bullet 7CH4O) + CH4O = (I- bullet 8CH4O)

Quantity Value Units Method Reference Comment
Deltar9.1 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; Entropy estimated.; B,M
Quantity Value Units Method Reference Comment
Deltar28.cal/mol*KN/AHiraoka and Yamabe, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar0.8 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; Entropy estimated.; B

(Iodide bullet 3Acetonitrile) + Acetonitrile = (Iodide bullet 4Acetonitrile)

By formula: (I- bullet 3C2H3N) + C2H3N = (I- bullet 4C2H3N)

Quantity Value Units Method Reference Comment
Deltar7.80 ± 0.10kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar7.40 ± 0.80kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar19.3cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar2.00 ± 0.40kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

(Iodide bullet 4Acetonitrile) + Acetonitrile = (Iodide bullet 5Acetonitrile)

By formula: (I- bullet 4C2H3N) + C2H3N = (I- bullet 5C2H3N)

Quantity Value Units Method Reference Comment
Deltar7.10 ± 0.30kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar10.60 ± 0.90kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar18.9cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar1.4 ± 1.4kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

Iodide + Nitrous oxide = (Iodide bullet Nitrous oxide)

By formula: I- + N2O = (I- bullet N2O)

Quantity Value Units Method Reference Comment
Deltar2.7 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
Deltar3.8 ± 0.3kcal/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar14.1cal/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

Iodide + Benzene = (Iodide bullet Benzene)

By formula: I- + C6H6 = (I- bullet C6H6)

Quantity Value Units Method Reference Comment
Deltar6.1 ± 2.0kcal/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B,M
Deltar9.1 ± 1.0kcal/molTDAsCaldwell, Masucci, et al., 1989gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar14.2cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar1.8 ± 2.6kcal/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B

Iodide + Dimethyl Sulfoxide = (Iodide bullet Dimethyl Sulfoxide)

By formula: I- + C2H6OS = (I- bullet C2H6OS)

Quantity Value Units Method Reference Comment
Deltar15.70kcal/molTDAsMagnera, Caldwell, et al., 1984gas phase; B,M
Deltar16.kcal/molPHPMSCaldwell, Masucci, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar21.7cal/mol*KPHPMSMagnera, Caldwell, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar9.20kcal/molTDAsMagnera, Caldwell, et al., 1984gas phase; B

Iodide = BrI2-

By formula: I- = BrI2-

Quantity Value Units Method Reference Comment
Deltar33.88 ± 0.23kcal/molPDisCrider, Harrison, et al., 2011gas phase; B
Deltar35.70kcal/molN/ACheck, Faust, et al., 2001gas phase; FeF2-(q); ; «DELTA»S(EA)=4.5; B
Quantity Value Units Method Reference Comment
Deltar25.80kcal/molN/ACheck, Faust, et al., 2001gas phase; FeF2-(q); ; «DELTA»S(EA)=4.5; B

Iodide + Xenon = IXe-

By formula: I- + Xe = IXe-

Quantity Value Units Method Reference Comment
Deltar1.60kcal/molN/ALenzer, Furlanetto, et al., 1998gas phase; B
Deltar2.80kcal/molTDAsWada, Kikkawa, et al., 2007gas phase; Entropy estimated; B
Quantity Value Units Method Reference Comment
Deltar-1.97kcal/molTDAsWada, Kikkawa, et al., 2007gas phase; Entropy estimated; B

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka, Mizuse, et al., 1988
Hiraoka, K.; Mizuse, S.; Yamabe, S., Solvation of Halide Ions with H2O and CH3CN in the Gas Phase, J. Phys. Chem., 1988, 92, 13, 3943, https://doi.org/10.1021/j100324a051 . [all data]

Keesee and Castleman, 1980
Keesee, R.G.; Castleman, A.W., Jr., Gas phase studies of hydration complexes of Cl- and I- and comparison to electrostatic calculations in the gas phase, Chem. Phys. Lett., 1980, 74, 139. [all data]

Arshadi, Yamdagni, et al., 1970
Arshadi, M.; Yamdagni, R.; Kebarle, P., Hydration of Halide Negative Ions in the Gas Phase. II. Comparison of Hydration Energies for the Alkali Positive and Halide Negative Ions, J. Phys. Chem., 1970, 74, 7, 1475, https://doi.org/10.1021/j100702a014 . [all data]

Banic and Iribarne, 1985
Banic, C.M.; Iribarne, J.V., Equilibrium Constants for Clustering of Neutral Molecules about Gaseous Ions, J. Chem. Phys., 1985, 83, 12, 6432, https://doi.org/10.1063/1.449543 . [all data]

Markovich, Pollack, et al., 1994
Markovich, G.; Pollack, S.; Giniger, R.; Cheshnovsky, O., Photoelectron spectroscopy of Cl-, Br-, and I- solvated in water clusters, J. Chem. Phys., 1994, 101, 11, 9344, https://doi.org/10.1063/1.467965 . [all data]

Payzant, Yamdagni, et al., 1971
Payzant, J.D.; Yamdagni, R.; Kebarle, P., Hydration of CN-, NO2-, NO3-, and HO- in the gas phase, Can. J. Chem., 1971, 49, 3308. [all data]

Piani, Becucci, et al., 2008
Piani, G.; Becucci, M.; Bowen, M.S.; Oakman, J.; Hu, Q.; Continetti, R.E., Photodetachment and dissociation dynamics of microsolvated iodide clusters, Phys. Scripta, 2008, 78, 5, 058110, https://doi.org/10.1088/0031-8949/78/05/058110 . [all data]

Arnold, Bradforth, et al., 1995
Arnold, D.W.; Bradforth, S.E.; Kim, E.H.; Neumark, D.M., Study of I-(CO2)n, Br-(CO2)n, and I-(N2O)n clusters by anion photoelectron spectroscopy, J. Chem. Phys., 1995, 102, 9, 3510, https://doi.org/10.1063/1.468576 . [all data]

Hiraoka, Mizuse, et al., 1987
Hiraoka, K.; Mizuse, S.; Yamabe, S., Stability and Structure of Cluster Ions: Halide Ions with CO2, J. Chem. Phys., 1987, 87, 6, 3647, https://doi.org/10.1063/1.452962 . [all data]

Gomez, Taylor, et al., 2002
Gomez, H.; Taylor, T.R.; Neumark, D.M., Anion photoelectron spectroscopy of I-2(-)(CO2)(n)(n=1-8) clusters, J. Chem. Phys., 2002, 116, 14, 6111-6117, https://doi.org/10.1063/1.1458246 . [all data]

Keesee, Lee, et al., 1980
Keesee, R.G.; Lee, N.; Castleman, A.W., Jr., Properties of clusters in the gas phase: V. Complexes of neutral molecules onto negative ions, J. Chem. Phys., 1980, 73, 2195. [all data]

Kebarle, Arshadi, et al., 1968
Kebarle, P.; Arshadi, M.; Scarborough, J., Hydration of Negative Ions in the Gas Phase, J. Chem. Phys., 1968, 49, 2, 817, https://doi.org/10.1063/1.1670145 . [all data]

Yamdagni and Kebarle, 1972
Yamdagni, R.; Kebarle, P., Solvation of negative ions by protic and aprotic solvents. Gas phase solvation of halide ions by acetonitrile and water molecules, J. Am. Chem. Soc., 1972, 94, 2940. [all data]

Markovich, Perera, et al., 1996
Markovich, G.; Perera, L.; Berkowitz, M.L.; Cheshnovsky, O., The Solvation of Cl-, Br-, and I- in Acetonitrile Cluster: Photoelectron Spectroscopy and Molecular Dynamics Simulations., J. Chem. Phys., 1996, 105, 7, 2675, https://doi.org/10.1063/1.472131 . [all data]

Dessent, Bailey, et al., 1995
Dessent, C.E.H.; Bailey, C.G.; Johnson, M.A., Dipole-bound excited states of the I-center dot CH3CN and I-center dot(CH3CN)2 ion-molecule complexes: Evidence for asymmetric solvation, J. Chem. Phys., 1995, 103, 6, 2006, https://doi.org/10.1063/1.469727 . [all data]

Caldwell, Masucci, et al., 1989
Caldwell, G.W.; Masucci, J.A.; Ikonomou, M.G., Negative Ion Chemical Ionization Mass Spectrometry - Binding of Molecules to Bromide and Iodide Anions, Org. Mass Spectrom., 1989, 24, 1, 8, https://doi.org/10.1002/oms.1210240103 . [all data]

Tanabe, Morgon, et al., 1996
Tanabe, F.K.J.; Morgon, N.H.; Riveros, J.M., Relative Bromide and Iodide Affinity of Simple Solvent Molecules Determined by FT-ICR, J. Phys. Chem., 1996, 100, 8, 2862-2866, https://doi.org/10.1021/jp952290p . [all data]

Caldwell and Kebarle, 1984
Caldwell, G.; Kebarle, P., Binding energies and structural effects in halide anion-ROH and -RCOOH complexes from gas phase equilibria measurements, J. Am. Chem. Soc., 1984, 106, 967. [all data]

Bogdanov, Peschke, et al., 1999
Bogdanov, B.; Peschke, M.; Tonner, D.S.; Szulejko, J.E.; McMahon, T.B., Stepwise solvation of halides by alcohol molecules in the gas phase, Int. J. Mass Spectrom., 1999, 187, 707-725, https://doi.org/10.1016/S1387-3806(98)14180-5 . [all data]

Hiraoka and Yamabe, 1991
Hiraoka, K.; Yamabe, S., Solvation of Halide Ions with CH3OH in the gas Phase, Int. J. Mass Spectrom. Ion Proc., 1991, 109, 133, https://doi.org/10.1016/0168-1176(91)85101-Q . [all data]

Van Duzor, Wei, et al., 2010
Van Duzor, M.; Wei, J.; Mbaiwa, F.; Mabbs, R., I-center dot CH3X (X=Cl, Br, I) photodetachment: The effect of electron-molecule interactions in cluster anion photodetachment spectra and angular distributions, J. Chem. Phys., 2010, 133, 14, 144303, https://doi.org/10.1063/1.3487739 . [all data]

Hiraoka, Fujita, et al., 1905
Hiraoka, K.; Fujita, K.; Ishida, M.; Ichikawa, T.; Okada, H.; Hiizumi, K.; Wada, A.; Takao, K.; Yamabe, S.; Tsuchida, N., Gas-phase Ion/Molecule Reactions in C5F8, J. Phys. Chem. A (2005), 1905, 109, 6, 1049-1056., https://doi.org/10.1021/jp040251k . [all data]

Arnold, Neumark, et al., 1995
Arnold, C.C.; Neumark, D.M.; Cyr, D.M.; Johnson, M.A., Negative ion zero electron kinetic energy spectroscopy of I-center dot CH3I, J. Phys. Chem., 1995, 99, 6, 1633, https://doi.org/10.1021/j100006a002 . [all data]

Cyr, Bishea, et al., 1992
Cyr, D.M.; Bishea, G.A.; Scarton, M.G.; Johnson, M.A., Observation of Charge-Transfer Excited States in the I-.CH3I, I-.CH3Br, and I-.CH2Br2 S(N)2 Reaction Intermediates Using Photofragmentation, J. Chem. Phys., 1992, 97, 8, 5911, https://doi.org/10.1063/1.463752 . [all data]

Dougherty and Roberts, 1974
Dougherty, R.C.; Roberts, J.D., SN2 reactions in the gas phase. Nucleophilicity effects, Org. Mass Spectrom., 1974, 8, 81. [all data]

Caldwell and Kebarle, 1985
Caldwell, G.; Kebarle, P., The hydrogen bond energies of the bihalide ions XHX- and YHX-, Can. J. Chem., 1985, 63, 1399. [all data]

Taylor, Asmis, et al., 1999
Taylor, T.R.; Asmis, K.R.; Zanni, M.T.; Neumark, D.M., Characterization of the I-3 radical by anion photoelectron spectroscopy, J. Chem. Phys., 1999, 110, 16, 7607-7609, https://doi.org/10.1063/1.478672 . [all data]

Do, Klein, et al., 1997
Do, K.; Klein, T.P.; Pommerening, C.A.; Sunderlin, L.S., A New Flowing Afterglow-Guided Ion Beam Tandem Mass Spectrometer. Applications to the Thermochemistry of Polyiodide Ions, J. Am. Soc. Mass Spectrom., 1997, 8, 7, 688, https://doi.org/10.1016/S1044-0305(97)00116-5 . [all data]

Finch, Gates, et al., 1977
Finch, A.; Gates, P.N.; Peake, S.J., Thermochemistry of polyhalides. III. Cesium and rubidium tetrachloroiodates, J. Inorg. Nucl. Chem., 1977, 39, 2135. [all data]

Check, Faust, et al., 2001
Check, C.E.; Faust, T.O.; Bailey, J.M.; Wright, B.J.; Gilbert, T.M.; Sunderlin, L.S., Addition of Polarization and Diffuse Functions to the LANL2DZ Basis Set for P-Block Elements, J. Phys. Chem. A,, 2001, 105, 34, 8111, https://doi.org/10.1021/jp011945l . [all data]

Paul and Kebarle, 1990
Paul, G.J.C.; Kebarle, P., Stabilities in the Gas Phase of the Hydrogen Bonded Complexes, YC6H4OH-X-, of Substituted Phenols, YC6H4OH, with the Halide Anions X-(Cl-, Br-), Can. J. Chem., 1990, 68, 11, 2070, https://doi.org/10.1139/v90-316 . [all data]

Pelaez, Blondel, et al., 2009
Pelaez, R.J.; Blondel, C.; Delsart, C.; Drag, C., Pulsed photodetachment microscopy and the electron affinity of iodine, J. Phys. B: Atom. Mol. Opt. Phys., 2009, 42, 12, 125001, https://doi.org/10.1088/0953-4075/42/12/125001 . [all data]

Hiraoka, Aruga, et al., 1993
Hiraoka, K.; Aruga, K.; Fujimaki, S.; Yamabe, S., Comparative Study of the Gas Phase Bond Strengths of CO2 and N2O with the Halide Ions, J. Am. Soc. Mass Spectrom., 1993, 4, 1, 58, https://doi.org/10.1016/1044-0305(93)85043-W . [all data]

Walker and Sunderlin, 1999
Walker, B.W.; Sunderlin, L.S., The thermochemistry of formic acid halide anion clusters, Int. J. Mass Spectrom., 1999, 184, 2-3, 183-189, https://doi.org/10.1016/S1387-3806(99)00008-1 . [all data]

Evans, Keesee, et al., 1987
Evans, D.H.; Keesee, R.G.; Castleman Jr., The Association of Ammonia with Halide Ions in the Gas Phase, J. Chem. Phys., 1987, 86, 5, 2927, https://doi.org/10.1063/1.452043 . [all data]

Hiraoka, Mizuse, et al., 1988, 2
Hiraoka, K.; Mizuse, S.; Yamabe, S., Determination of the Stabilities and Structures of X-(C6H6) Clusters (X = Cl, Br, and I), Chem. Phys. Lett., 1988, 147, 2-3, 174, https://doi.org/10.1016/0009-2614(88)85078-4 . [all data]

Magnera, Caldwell, et al., 1984
Magnera, T.F.; Caldwell, G.; Sumner, J.; Ikuta, S.; Kebarle, P., Solvation of the halide anions in dimethyl sulfoxide. Factors involved in enhanced reactivity of negative ions in dipolar aprotic solvents, J. Am. Chem. Soc., 1984, 106, 6140. [all data]

Crider, Harrison, et al., 2011
Crider, P.E.; Harrison, A.W.; Neumark, D.M., Two- and three-body photodissociation dynamics of diiodobromide (I2Br-) anion, J. Chem. Phys., 2011, 134, 13, 134306, https://doi.org/10.1063/1.3571474 . [all data]

Lenzer, Furlanetto, et al., 1998
Lenzer, T.; Furlanetto, M.R.; Asmis, K.R.; Neumark, D.M., Zero electron kinetic energy and photoelectron spectroscopy of the XeI- anion, J. Chem. Phys., 1998, 109, 24, 10754-10766, https://doi.org/10.1063/1.477774 . [all data]

Wada, Kikkawa, et al., 2007
Wada, A.; Kikkawa, A.; Sugiyama, T.; Hiraoka, K., Thermochemical Stabilities of the Gas-phase Cluster Ions of Halide Ions with Rare Gas Atoms, Int. J. Mass Spectrom.., 2007, 267, 1-3, 284-287, https://doi.org/10.1016/j.ijms.2007.02.053 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, References