Reaction data
+
= (
•
)
- Reaction by formula: I- + H2O = (I- • H2O)
- Comments:
- Bond type: Hydrogen bond (negative ion to hydride)
- Information on this page:
- Other data available:
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Enthalpy of reaction at standard conditions (nominally 298.15 K, 1 atm.)
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
ΔrH° (kcal/mol) | Method | Reference | Comment |
---|---|---|---|
10.4 ± 1.0 | N/A | Markovich, Giniger, et al., 1991 | gas phase; For photodissociation of bond plus electron loss, agrees with thermo threshold; B |
10.1 ± 1.0 | TDAs | Caldwell and Kebarle, 1984 | gas phase; B |
10.30 ± 0.30 | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B,M |
11.10 ± 0.10 | TDAs | Keesee and Castleman, 1980 | gas phase; B,M |
10.20 | TDAs | Arshadi, Yamdagni, et al., 1970 | gas phase; B,M |
10. | PHPMS | Caldwell, Masucci, et al., 1989 | gas phase; M |
References
Go To: Top, Enthalpy of reaction at standard conditions (nominally 298.15 K, 1 atm.), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Markovich, Giniger, et al., 1991
Markovich, G.; Giniger, R.; Levin, M.; Cheshnovsky, O.,
Photoelectron Spectroscopy of Iodine Anion Solvated in Water Clusters,
J. Chem. Phys., 1991, 95, 12, 9416, https://doi.org/10.1063/1.461172
. [all data]
Caldwell and Kebarle, 1984
Caldwell, G.; Kebarle, P.,
Binding energies and structural effects in halide anion-ROH and -RCOOH complexes from gas phase equilibria measurements,
J. Am. Chem. Soc., 1984, 106, 967. [all data]
Hiraoka, Mizuse, et al., 1988
Hiraoka, K.; Mizuse, S.; Yamabe, S.,
Solvation of Halide Ions with H2O and CH3CN in the Gas Phase,
J. Phys. Chem., 1988, 92, 13, 3943, https://doi.org/10.1021/j100324a051
. [all data]
Keesee and Castleman, 1980
Keesee, R.G.; Castleman, A.W., Jr.,
Gas phase studies of hydration complexes of Cl- and I- and comparison to electrostatic calculations in the gas phase,
Chem. Phys. Lett., 1980, 74, 139. [all data]
Arshadi, Yamdagni, et al., 1970
Arshadi, M.; Yamdagni, R.; Kebarle, P.,
Hydration of Halide Negative Ions in the Gas Phase. II. Comparison of Hydration Energies for the Alkali Positive and Halide Negative Ions,
J. Phys. Chem., 1970, 74, 7, 1475, https://doi.org/10.1021/j100702a014
. [all data]
Caldwell, Masucci, et al., 1989
Caldwell, G.W.; Masucci, J.A.; Ikonomou, M.G.,
Negative Ion Chemical Ionization Mass Spectrometry - Binding of Molecules to Bromide and Iodide Anions,
Org. Mass Spectrom., 1989, 24, 1, 8, https://doi.org/10.1002/oms.1210240103
. [all data]
Notes
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- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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