Cyclohexene, 3-(1,5-dimethyl-4-hexenyl)-6-methylene-, [S-(R*,S*)]-


Normal alkane RI, polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxRTX-WaxDB-WaxSupelcowax-10Supelcowax-10
Column length (m) 30.60.60.30.30.
Carrier gas HydrogenHeN2 He
Substrate      
Column diameter (mm) 0.250.220.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 30.60.70.40.50.
Tend (C) 230.230.230.210.250.
Heat rate (K/min) 8.2.2.2.4.
Initial hold (min) 5. 2.2.1.
Final hold (min) 10.35.20.33.10.
I 1767.1761.1764.1771.1754.
ReferenceKarlsson, Birgersson, et al., 2009Paolini, Tomi, et al., 2008Choi, 2006Garneau F.X., Collin G., et al., 2006Wong, Sivasothy, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CP-WaxCP-Wax 52CBCP-Wax 52CBCarbowaxSupelcowax-10
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHe He
Substrate      
Column diameter (mm) 0.320.320.320.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 40.40.40.40.50.
Tend (C) 180.220.220.200.220.
Heat rate (K/min) 5.4.4.4.4.
Initial hold (min) 2.1.1. 3.
Final hold (min)     30.
I 1752.1776.1776.1764.1729.
ReferenceKa, Choi, et al., 2005Rohloff and Bones, 2005Rohloff and Bones, 2005Szafranek, Chrapkowska, et al., 2005Wong, Lee, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxHP-InnowaxInnowaxDB-WaxDB-Wax
Column length (m) 60.50.60.60.60.
Carrier gas Helium HeN2N2
Substrate      
Column diameter (mm) 0.250.20.250.250.25
Phase thickness (μm)  0.2 0.250.25
Tstart (C) 70.50.60.70.70.
Tend (C) 210.220.220.230.230.
Heat rate (K/min) 2.4.4.2.2.
Initial hold (min)  5.10.2.2.
Final hold (min) 60. 10.20.20.
I 1771.1787.1783.1750.1772.
ReferenceMookdasanit, Tamura, et al., 2003Stashenko, Jaramillo, et al., 2003Suleimenov, Atazharova, et al., 2003Tu, Onishi, et al., 2003Tu, Onishi, et al., 2003, 2
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Carbowax 20MDB-WaxDB-WaxInnowaxInnowax
Column length (m) 30.60.60.60.60.
Carrier gas HeN2N2HeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.3250.250.250.250.25
Tstart (C) 50.70.70.60.60.
Tend (C) 215.230.230.220.220.
Heat rate (K/min) 4.2.2.4. 
Initial hold (min)  2. 10.10.
Final hold (min) 20.20. 10. 
I 1776.1760.1782.1783.1783.
ReferenceKasali, Winterhalter, et al., 2002Tu, Onishi, et al., 2002Tu, Thanh, et al., 2002Baser, Özek, et al., 2000Kaya, Baser, et al., 1999
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxSupelcowax-10TC-WaxDB-WaxCarbowax 20M
Column length (m) 30.30.60.60.45.
Carrier gas N2  HeHydrogen
Substrate      
Column diameter (mm) 0.250.250.250.250.32
Phase thickness (μm) 0.25  0.251.0
Tstart (C) 45.60.80.50.60.
Tend (C) 220.240.240.180.200.
Heat rate (K/min) 3.4.3.2.52.
Initial hold (min)   5.5.5.
Final hold (min)      
I 1794.1770.1776.1773.1755.
ReferenceMolleken U., Sinnwell V., et al., 1998Zunino, Novillo-Newton, et al., 1997Shuichi, Masazumi, et al., 1996Stashenko, Puertas, et al., 1996Kollmannsberger, Nitz, et al., 1992
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillary
Active phase DB-WaxSupelcowax-10Supelcowax-10
Column length (m) 60.30.30.
Carrier gas H2 He
Substrate    
Column diameter (mm) 0.25  
Phase thickness (μm) 0.25  
Tstart (C) 50.50.50.
Tend (C) 238.240.240.
Heat rate (K/min) 4.4.4.
Initial hold (min)  2.2.
Final hold (min) 13.10.10.
I 1778.1776.1776.
Referencevan Beek, Kleis, et al., 1989Ramaswami, Briscese, et al., 1988Ramaswami, Briscese, et al., 1986
Comment MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Normal alkane RI, polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Karlsson, Birgersson, et al., 2009
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Wong, Lee, et al., 2005
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Mookdasanit, Tamura, et al., 2003
Mookdasanit, J.; Tamura, H.; Yoshizawa T.; Tokunaga T.; Nakanishi, K., Trace Volatile Compounds in Essential Oil of Citrus Sudachi by Means of Modified Solvent Extraction Method, Food Sci Technol. Res., 2003, 9, 1, 54-61, https://doi.org/10.3136/fstr.9.54 . [all data]

Stashenko, Jaramillo, et al., 2003
Stashenko, E.E.; Jaramillo, B.E.; Martínez, J.R., Comparación de la composición química y de la actividad antioxidante in vitro de los metabolitos secundarios volátiles de plantas de la familia verbenaceae, Rev. Acad. Colomb. Cienc. Exactas Fis. Nat., 2003, 27, 105, 579-597. [all data]

Suleimenov, Atazharova, et al., 2003
Suleimenov, E.M.; Atazharova, G.A.; Demirchi, B.; Baser, K.H.C.; Adekenov, S.M., Essential oil composition of Artemisia Lercheana and A. Sieversiana of Kazakhstan flora in Recent problems of development of new medicines of natural origin, Proceedings of symposium, St.Petersburg - Pushkin, 2003, 382-385. [all data]

Tu, Onishi, et al., 2003
Tu, N.T.M.; Onishi, Y.; Son, U.S.; Ogawa, E.; Ukeda, H.; Sawamura, M., Characteristic odour components of Citrus inflata Hort. Ex Tanaka (Mochiyu) cold-pressed peel oil, Flavour Fragr. J., 2003, 18, 5, 454-459, https://doi.org/10.1002/ffj.1252 . [all data]

Tu, Onishi, et al., 2003, 2
Tu, N.T.M.; Onishi, Y.; Choi, H.S.; Kondo, Y.; Ukeda, H.; Sawamura, M., Characteristic odour components of Citrus sp. (Kiyookadaidai) cold-pressed peel oil, Flavour Fragr. J., 2003, 18, 6, 515-520, https://doi.org/10.1002/ffj.1260 . [all data]

Kasali, Winterhalter, et al., 2002
Kasali, A.A.; Winterhalter, P.; Adio, A.M.; Knapp, H.; Bonnlander, B., Chromenes in Ageratum conyzoides L., Flavour Fragr. J., 2002, 17, 4, 247-250, https://doi.org/10.1002/ffj.1099 . [all data]

Tu, Onishi, et al., 2002
Tu, N.T.M.; Onishi, Y.; Choi, H.-S.; Kondo, Y.; Bassore, S.M.; Ukeda, H.; Sawamura, M., Characteristic odor components of Citrus sphaerocarpa Tanaka (Kabosu) cold-pressed peel oil, J. Agric. Food Chem., 2002, 50, 10, 2908-2913, https://doi.org/10.1021/jf011578a . [all data]

Tu, Thanh, et al., 2002
Tu, N.T.M.; Thanh, L.X.; Une, A.; Ukeda, H.; Sawamura, M., Volatile constituents of Vietnamese pummelo, orange, tangerine and lime peel oils, Flavour Fragr. J., 2002, 17, 3, 169-174, https://doi.org/10.1002/ffj.1076 . [all data]

Baser, Özek, et al., 2000
Baser, K.H.C.; Özek, T.; Demirci, B.; Kürkcüoglu, M.; Aytac, Z.; Duman, H., Composition of the essential oils of Zosima absinthifolia (Vent.) Link and Ferula elaeochytris Korovin from Turkey, Flavour Fragr. J., 2000, 15, 6, 371-372, https://doi.org/10.1002/1099-1026(200011/12)15:6<371::AID-FFJ919>3.0.CO;2-Z . [all data]

Kaya, Baser, et al., 1999
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Molleken U., Sinnwell V., et al., 1998
Molleken U.; Sinnwell V.; Kubeczka K.H., TThe essential oil composition of fruits from Smyrnium perfoliatum, Phytochemistry, 1998, 47, 6, 1079-1083, https://doi.org/10.1016/S0031-9422(98)80076-9 . [all data]

Zunino, Novillo-Newton, et al., 1997
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Notes

Go To: Top, Normal alkane RI, polar column, temperature ramp, References