dicesium oxide

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to Cs2O+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
Proton affinity (review)1442.9kJ/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity1412.2kJ/molN/AHunter and Lias, 1998HL

Ionization energy determinations

IE (eV) Method Reference Comment
4.37SButman, Kudin, et al., 1984LBLHLM
4.5EIGusarov, Gorokhov, et al., 1967RDSH
4.45 ± 0.06EIEmel'yanov, Gusarov, et al., 1967RDSH

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Butman, Kudin, et al., 1984
Butman, M.F.; Kudin, L.S.; Krasnov, K.S., The Mass-spectrometric determination of the proton affinity of the molecules M2O (M = Na, K, Rb, Cs), Russ. J. Inorg. Chem., 1984, 29, 1228, In original 2150. [all data]

Gusarov, Gorokhov, et al., 1967
Gusarov, A.V.; Gorokhov, L.N.; Efimova, A.G., Mass-spectrometer study of the evaporation products of cesium carbonate, Teplofiz. Vysokikh Temperatur, 1967, 5, 783, In original 699. [all data]

Emel'yanov, Gusarov, et al., 1967
Emel'yanov, A.M.; Gusarov, A.V.; Gorokhov, L.N.; Sadovnikova, N.A., Electron-impact studies of the vapors of cesium oxide and hydroxide, Teor. i Eksperim, Khim., 1967, 3, 226, In original 126. [all data]


Notes

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