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1-Decanamine

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Phase change data

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director

Quantity Value Units Method Reference Comment
Tboil490.2KN/AAldrich Chemical Company Inc., 1990BS
Tboil493.7KN/AWeast and Grasselli, 1989BS
Tboil493.KN/AAmerican Tokyo Kasei, 1988BS
Tboil493.65KN/ASudaricov, Phrolov, et al., 1963Uncertainty assigned by TRC = 1. K; TRC
Quantity Value Units Method Reference Comment
Tfus288.15KN/AZvejnieks, 1954Uncertainty assigned by TRC = 0.3 K; TRC
Tfus289.26KN/ARalston, Hoerr, et al., 1944Uncertainty assigned by TRC = 0.5 K; TRC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Gas phase ion energetics data

Go To: Top, Phase change data, Mass spectrum (electron ionization), Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias

Data compiled as indicated in comments:
MM - Michael M. Meot-Ner (Mautner)
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Quantity Value Units Method Reference Comment
Proton affinity (review)930.4kJ/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity896.5kJ/molN/AHunter and Lias, 1998HL

Gas basicity at 298K

Gas basicity (review) (kJ/mol) Reference Comment
879.5 ± 9.2Gross, Rodriguez-Cruz, et al., 1995T = 300K; 3-Fluoropyridine; i-Propylamine. Reference GBs readjusted to Hunter and Lias, 1998. Cited uncertainty is half of the «DELTA»GB between the bracketing bases; MM

Ionization energy determinations

IE (eV) Method Reference Comment
8.5PEAue and Bowers, 1979LLK
8.63 ± 0.05PIIskakov and Potapov, 1971LLK

Mass spectrum (electron ionization)

Go To: Top, Phase change data, Gas phase ion energetics data, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-NW-3942
NIST MS number 232416

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


Gas Chromatography

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
PackedSE-30180.1241.Oszczapowicz, Osek, et al., 1985N2, Chromosorb A AW; Column length: 3. m

Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillarySE-541249.Woolley, Markides, et al., 198620. m/0.05 mm/0.25 «mu»m, He, 40. C @ 2. min, 4. K/min; Tend: 180. C
CapillarySE-541252.Woolley, Markides, et al., 198620. m/0.05 mm/0.25 «mu»m, He, 40. C @ 2. min, 4. K/min; Tend: 180. C
CapillarySE-541252.Woolley, Markides, et al., 198620. m/0.05 mm/0.25 «mu»m, He, 40. C @ 2. min, 4. K/min; Tend: 180. C
CapillarySE-541254.Woolley, Markides, et al., 198620. m/0.05 mm/0.25 «mu»m, He, 40. C @ 2. min, 4. K/min; Tend: 180. C
CapillarySE-541254.Woolley, Markides, et al., 198620. m/0.05 mm/0.25 «mu»m, He, 40. C @ 2. min, 4. K/min; Tend: 180. C
CapillarySE-541255.Woolley, Markides, et al., 198620. m/0.05 mm/0.25 «mu»m, He, 40. C @ 2. min, 4. K/min; Tend: 180. C
CapillarySE-541256.Woolley, Markides, et al., 198620. m/0.05 mm/0.25 «mu»m, He, 40. C @ 2. min, 4. K/min; Tend: 180. C
CapillarySE-541256.Woolley, Markides, et al., 198620. m/0.05 mm/0.25 «mu»m, He, 40. C @ 2. min, 4. K/min; Tend: 180. C
CapillarySE-541256.Woolley, Markides, et al., 198620. m/0.05 mm/0.25 «mu»m, He, 40. C @ 2. min, 4. K/min; Tend: 180. C
CapillarySE-541259.Woolley, Markides, et al., 198620. m/0.05 mm/0.25 «mu»m, He, 40. C @ 2. min, 4. K/min; Tend: 180. C
CapillarySE-541265.Woolley, Markides, et al., 198620. m/0.05 mm/0.25 «mu»m, He, 40. C @ 2. min, 4. K/min; Tend: 180. C

Van Den Dool and Kratz RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryDB-11236.Peng, 200015. m/0.53 mm/1. «mu»m, He; Program: 40C(3min) => 8C/min => 200(1min) => 5C/min => 300C(25min)
CapillaryMethyl Silicone1237.Peng, Yang, et al., 1991Program: not specified
PackedSE-301240.Peng, Ding, et al., 1988Supelcoport; Chromosorb; Column length: 3.05 m; Program: 40C(5min) => 10C/min => 200C or 250C (60min)

Van Den Dool and Kratz RI, polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryHP-Wax1517.Peng, 200015. m/0.53 mm/1. «mu»m, He, 40. C @ 3. min, 5. K/min, 220. C @ 30. min

Normal alkane RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryUltra-11232.Okumura, 199125. m/0.32 mm/0.25 «mu»m, He, 3. K/min; Tstart: 80. C; Tend: 260. C

Normal alkane RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillarySolgel-1 (SGE)1239.SGE Co., 200830. m/0.25 mm/0.25 «mu»m; Program: not specified
CapillarySolgel-1 (SGE)1240.SGE Co., 200830. m/0.25 mm/0.25 «mu»m; Program: not specified
CapillarySolgel-1 (SGE)1241.SGE Co., 200830. m/0.25 mm/0.25 «mu»m; Program: not specified

Normal alkane RI, polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillaryDB-Wax1522.Peng, Yang, et al., 1991, 2Program: not specified

References

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

American Tokyo Kasei, 1988
American Tokyo Kasei, TCI American Organic Chemical 88/89 Catalog, American Tokyo Kasei, Portland, OR, 1988, 1610. [all data]

Sudaricov, Phrolov, et al., 1963
Sudaricov, B.N.; Phrolov, U.G.; Ilichev, V.A.I.; Pushcov, A.A.; Zaharov-Narcissov, O.I.; Ochkin, A.B., Physicochemical Properties of Certain n-Aliphatic Amines, Tr. Inst. - Mosk. Khim. -Tekhnol. Inst. im. D. I. Mendele- eva, 1963, 43, 21. [all data]

Zvejnieks, 1954
Zvejnieks, A., Preparation and Properties of Some Pure Fatty and Rosin Amines., Sven. Kem. Tidskr., 1954, 66, 316. [all data]

Ralston, Hoerr, et al., 1944
Ralston, A.W.; Hoerr, C.W.; Pool, W.O.; Harwood, H.J., Solubilities of High-Molecular-Weight Normal Aliphatic Primary Amines., J. Org. Chem., 1944, 9, 102-12. [all data]

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Gross, Rodriguez-Cruz, et al., 1995
Gross, D.S.; Rodriguez-Cruz, S.E.; Bock, S.; Williams, E.R., Measurement of the Coulomb Energy and Dielectric Polarizability of Gas-Phase Diprotonated Diaminoalkanes, J. Phys. Chem., 1995, 99, 4034. [all data]

Aue and Bowers, 1979
Aue, D.H.; Bowers, M.T., Chapter 9. Stabilities of positive ions from equilibrium gas phase basicity measurements in Ions Chemistry,, ed. M.T. Bowers, 1979. [all data]

Iskakov and Potapov, 1971
Iskakov, L.I.; Potapov, V.K., Dissociative photoionization of n-alkylamines, Khim. Vys. Energ., 1971, 5, 534. [all data]

Oszczapowicz, Osek, et al., 1985
Oszczapowicz, J.; Osek, J.; Ciszkowski, K.; Krawczyk, W.; Ostrowski, M., Retention Indices of Dimethylbenzamidines and Benzylideneamines on a Non-Polar Column, J. Chromatogr., 1985, 330, 79-85, https://doi.org/10.1016/S0021-9673(01)81964-6 . [all data]

Woolley, Markides, et al., 1986
Woolley, C.L.; Markides, K.E.; Lee, M.L.; Bartle, K.D., Deactivation of small diameter fused silica capillary columns with organosilicon hydrides, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1986, 9, 9, 506-514, https://doi.org/10.1002/jhrc.1240090904 . [all data]

Peng, 2000
Peng, C.T., Prediction of retention indices. V. Influence of electronic effects and column polarity on retention index, J. Chromatogr. A, 2000, 903, 1-2, 117-143, https://doi.org/10.1016/S0021-9673(00)00901-8 . [all data]

Peng, Yang, et al., 1991
Peng, C.T.; Yang, Z.C.; Maltby, D., Prediction of retention indexes. III. Silylated derivatives of polar compounds, J. Chromatogr., 1991, 586, 1, 113-129, https://doi.org/10.1016/0021-9673(91)80029-G . [all data]

Peng, Ding, et al., 1988
Peng, C.T.; Ding, S.F.; Hua, R.L.; Yang, Z.C., Prediction of Retention Indexes I. Structure-Retention Index Relationship on Apolar Columns, J. Chromatogr., 1988, 436, 137-172, https://doi.org/10.1016/S0021-9673(00)94575-8 . [all data]

Okumura, 1991
Okumura, T., retention indices of environmental chemicals on methyl silicone capillary column, Journal of Environmental Chemistry (Japan), 1991, 1, 2, 333-358, https://doi.org/10.5985/jec.1.333 . [all data]

SGE Co., 2008
SGE Co., The Importance of Low Bleed Columns for GC-MS; Technical Article, The Importance of Low Bleed Columns for GC-MS, SGE Co., 2008, 2, retrieved from http://www.sge-com. [all data]

Peng, Yang, et al., 1991, 2
Peng, C.T.; Yang, Z.C.; Ding, S.F., Prediction of rentention idexes. II. Structure-retention index relationship on polar columns, J. Chromatogr., 1991, 586, 1, 85-112, https://doi.org/10.1016/0021-9673(91)80028-F . [all data]


Notes

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Gas Chromatography, References