Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Cobalt [«mu»3-(bromomethylidyne)]nonacarbonyltri-,triangulo


Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafgas-1079. ± 15.kJ/molReviewMartinho SimõesThe enthalpy of formation relies on 2.97 ± 0.08 kJ/mol for the enthalpy of formation of Br2 in a carbon tetrachloride solution and on 12.9 ± 0.4 kJ/mol for the solution enthalpy of CBr4(cr) in carbon tetrachloride Gardner, Cartner, et al., 1975

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafsolid-1179. ± 15.kJ/molReviewMartinho SimõesThe enthalpy of formation relies on 2.97 ± 0.08 kJ/mol for the enthalpy of formation of Br2 in a carbon tetrachloride solution and on 12.9 ± 0.4 kJ/mol for the solution enthalpy of CBr4(cr) in carbon tetrachloride Gardner, Cartner, et al., 1975

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltasub99.6 ± 1.7kJ/molN/APilcher and Skinner, 1983See also Cardner, Gartner, et al., 1975.; AC
Deltasub99.6 ± 1.7kJ/molRSCGardner, Cartner, et al., 1975MS

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Gardner, Cartner, et al., 1975
Gardner, P.J.; Cartner, A.; Cunninghame, R.G.; Robinson, B.H., J. Chem. Soc., Dalton Trans., 1975, 2582.. [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Cardner, Gartner, et al., 1975
Cardner, Peter J.; Gartner, Anthony; Cunninghame, Robert G.; Robinson, Brian H., Bond energies in dicobalt octacarbonyl and bromo- and chloro-methylidynetricobalt enneacarbonyls, J. Chem. Soc., Dalton Trans., 1975, 23, 2582, https://doi.org/10.1039/dt9750002582 . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References