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Tungsten pentafluoride


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
B - John E. Bartmess

View reactions leading to F5W+ (ion structure unspecified)

Electron affinity determinations

EA (eV) Method Reference Comment
<3.49948IMRBGeorge and Beauchamp, 1979EA: WF5 < WF6; B
>1.80 ± 0.30NBAECompton, Reinhardt, et al., 1978From WF6; B
1.25 ± 0.20EIAEDe Wall and Neuert, 1977From WF6; B
1.25 ± 0.30NBAEDispert and Lacmann, 1977From WF6; B
>0.40 ± 0.20EIAEHildebrand, 1977From WF6; B
0.80 ± 0.20EIAEThynne and Harland, 1973From WF6; B

Ionization energy determinations

IE (eV) Method Reference Comment
14.9 ± 0.1PEVovna, Dudin, et al., 1979LLK
10.03 ± 0.10EIHildenbrand, 1975LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

George and Beauchamp, 1979
George, P.M.; Beauchamp, J.L., The electron and fluoride affinites of tungsten hexafluoride by ICR spectroscopy, Chem. Phys., 1979, 36, 345. [all data]

Compton, Reinhardt, et al., 1978
Compton, R.N.; Reinhardt, P.W.; Cooper, C.D., Collisional ionization between fast alkali atoms and selected hexafluoride molecules, J. Chem. Phys., 1978, 68, 2023. [all data]

De Wall and Neuert, 1977
De Wall, R.; Neuert, H., Die Bildung Negativer Ionen bei Elektronenstoss auf WF6, Z. Naturfor., 1977, 32A, 1968. [all data]

Dispert and Lacmann, 1977
Dispert, H.; Lacmann, K., Formation of WF6- and its dissociative products by collisional ionization, Chem. Phys. Lett., 1977, 45, 311. [all data]

Hildebrand, 1977
Hildebrand, D.L., Studies of Some Negative Ion Processes Involving the Tungsten Fluorides, Int. J. Mass Spectrom. Ion Phys., 1977, 25, 2, 121, https://doi.org/10.1016/0020-7381(77)80042-9 . [all data]

Thynne and Harland, 1973
Thynne, J.C.J.; Harland, P.W., Negative Ion Formation by Tungsten Fluoride, Int. J. Mass Spectrom. Ion Phys., 1973, 11, 137. [all data]

Vovna, Dudin, et al., 1979
Vovna, V.I.; Dudin, A.S.; Avkhutskii, L.M.; Lopatin, S.N.; Ippolitov, E.G., Photoelectron spectra and electronic spectra of volatile rhenium fluorides [and oxide fluorides], Russ. J. Inorg. Chem., 1979, 24, 1135. [all data]

Hildenbrand, 1975
Hildenbrand, D.L., Thermochemistry of the gaseous tungsten fluorides, Chem. Phys. Lett., 1975, 62, 3074. [all data]


Notes

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