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D-Fructose, 5TMS derivative


Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NIST Mass Spectrometry Data Center
NIST MS number 332829

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Gas Chromatography

Go To: Top, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillaryOV-1180.1867.Garcia-Raso, Fernandez-Diaz, et al., 1989Column length: 25. m; Column diameter: 0.22 mm
CapillarySE-54180.1867.García-Raso, Martínez-Castro, et al., 1987Column length: 40. m; Column diameter: 0.18 mm
CapillarySE-54180.1875.García-Raso, Martínez-Castro, et al., 1987Column length: 40. m; Column diameter: 0.18 mm

Kovats' RI, polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillaryFFAP170.1859.Garcia-Raso, Fernandez-Diaz, et al., 1989Column length: 24. m; Column diameter: 0.22 mm

Van Den Dool and Kratz RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryVF-5MS1805.1Tret'yakov, 200730. m/0.25 mm/0.25 «mu»m, He; Program: Multi-step temperature program; T(initial)=60C; T(final)=270C

Normal alkane RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryHP-51842.Isidorov, Kotowska, et al., 200530. m/0.25 mm/0.25 «mu»m, He, 5. K/min; Tstart: 50. C; Tend: 300. C

Normal alkane RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryOV-1011864.Binder and Haddon, 1984Helium; Column length: 42. m; Column diameter: 0.50 mm; Program: 60 0C (0.5 min) 30 0C/min -> 170 0C 3 0C/min -> 220 0C
CapillaryOV-1011855.Binder and Haddon, 1984Helium; Column length: 42. m; Column diameter: 0.50 mm; Program: 80 0C (0.5 min) 30 0C/min -> 170 0C 3 0C/min -> 220 0C

References

Go To: Top, Mass spectrum (electron ionization), Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Garcia-Raso, Fernandez-Diaz, et al., 1989
Garcia-Raso, A.; Fernandez-Diaz, M.; Paez, M.I.; Sanz, J.; Martinez-Castro, I., Gas Chromatographic Retention of Carbohydrate Trimethylsilyl Ethers. III. Ketohexoses, J. Chromatogr., 1989, 471, 205-216, https://doi.org/10.1016/S0021-9673(00)94168-2 . [all data]

García-Raso, Martínez-Castro, et al., 1987
García-Raso, A.; Martínez-Castro, I.; Páez, M.I.; Sanz, J.; García-Raso, J.; Saura-Calixto, F., Gas Chromatographic Behaviour of Carbohydrate Trimethylsilyl Ethers. I. Aldopentoses, J. Chromatogr., 1987, 398, 9-20, https://doi.org/10.1016/S0021-9673(01)96491-X . [all data]

Tret'yakov, 2007
Tret'yakov, K.V., Retention Data. NIST Mass Spectrometry Data Center., NIST Mass Spectrometry Data Center, 2007. [all data]

Isidorov, Kotowska, et al., 2005
Isidorov, V.A.; Kotowska, U.; Vinogorova, V.T., GC Identification of organic compounds based on partition coefficients of their TMS derivatives in a hexane-acetonitrile system and retention indices, Anal. Sci., 2005, 21, 12, 1483-1489, https://doi.org/10.2116/analsci.21.1483 . [all data]

Binder and Haddon, 1984
Binder, R.B.; Haddon, W.F., Analysis of O-methylinositols by gas-liquid chromatography-mass spectrometry, Carbohydrate Research, 1984, 129, 21-32, https://doi.org/10.1016/0008-6215(84)85295-7 . [all data]


Notes

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