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D-Fructose, 5TMS derivative


Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillaryOV-1180.1867.Garcia-Raso, Fernandez-Diaz, et al., 1989Column length: 25. m; Column diameter: 0.22 mm
CapillarySE-54180.1867.García-Raso, Martínez-Castro, et al., 1987Column length: 40. m; Column diameter: 0.18 mm
CapillarySE-54180.1875.García-Raso, Martínez-Castro, et al., 1987Column length: 40. m; Column diameter: 0.18 mm

Kovats' RI, polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillaryFFAP170.1859.Garcia-Raso, Fernandez-Diaz, et al., 1989Column length: 24. m; Column diameter: 0.22 mm

Van Den Dool and Kratz RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryVF-5MS1805.1Tret'yakov, 200730. m/0.25 mm/0.25 «mu»m, He; Program: Multi-step temperature program; T(initial)=60C; T(final)=270C

Normal alkane RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryHP-51842.Isidorov, Kotowska, et al., 200530. m/0.25 mm/0.25 «mu»m, He, 5. K/min; Tstart: 50. C; Tend: 300. C

Normal alkane RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryOV-1011864.Binder and Haddon, 1984Helium; Column length: 42. m; Column diameter: 0.50 mm; Program: 60 0C (0.5 min) 30 0C/min -> 170 0C 3 0C/min -> 220 0C
CapillaryOV-1011855.Binder and Haddon, 1984Helium; Column length: 42. m; Column diameter: 0.50 mm; Program: 80 0C (0.5 min) 30 0C/min -> 170 0C 3 0C/min -> 220 0C

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Garcia-Raso, Fernandez-Diaz, et al., 1989
Garcia-Raso, A.; Fernandez-Diaz, M.; Paez, M.I.; Sanz, J.; Martinez-Castro, I., Gas Chromatographic Retention of Carbohydrate Trimethylsilyl Ethers. III. Ketohexoses, J. Chromatogr., 1989, 471, 205-216, https://doi.org/10.1016/S0021-9673(00)94168-2 . [all data]

García-Raso, Martínez-Castro, et al., 1987
García-Raso, A.; Martínez-Castro, I.; Páez, M.I.; Sanz, J.; García-Raso, J.; Saura-Calixto, F., Gas Chromatographic Behaviour of Carbohydrate Trimethylsilyl Ethers. I. Aldopentoses, J. Chromatogr., 1987, 398, 9-20, https://doi.org/10.1016/S0021-9673(01)96491-X . [all data]

Tret'yakov, 2007
Tret'yakov, K.V., Retention Data. NIST Mass Spectrometry Data Center., NIST Mass Spectrometry Data Center, 2007. [all data]

Isidorov, Kotowska, et al., 2005
Isidorov, V.A.; Kotowska, U.; Vinogorova, V.T., GC Identification of organic compounds based on partition coefficients of their TMS derivatives in a hexane-acetonitrile system and retention indices, Anal. Sci., 2005, 21, 12, 1483-1489, https://doi.org/10.2116/analsci.21.1483 . [all data]

Binder and Haddon, 1984
Binder, R.B.; Haddon, W.F., Analysis of O-methylinositols by gas-liquid chromatography-mass spectrometry, Carbohydrate Research, 1984, 129, 21-32, https://doi.org/10.1016/0008-6215(84)85295-7 . [all data]


Notes

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