2-Nonenal, (E)-


Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SPB-5HP-5MSHP-5MSDB-5MSDB-5MS
Column length (m) 60.30.30.30.30.
Carrier gas  HeHeHeHe
Substrate      
Column diameter (mm) 0.320.250.250.250.25
Phase thickness (μm) 1.0.50.50.250.25
Tstart (C) 40.35.35.35.35.
Tend (C) 230.225.225.225.225.
Heat rate (K/min) 3.4.4.10.10.
Initial hold (min) 2.5.5.5.5.
Final hold (min) 10.30.30.25.25.
I 1164.1171.1161.1156.1168.
ReferenceEngel and Ratel, 2007Jarunrattanasri, Theerakulkait, et al., 2007Jarunrattanasri, Theerakulkait, et al., 2007Lozano P.R., Drake M., et al., 2007Lozano P.R., Drake M., et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-5DB-PetroDB-PetroRTX-1
Column length (m) 30.60.50.50.60.
Carrier gas He   He
Substrate      
Column diameter (mm) 0.320.320.20.20.22
Phase thickness (μm) 0.51.0.50.50.25
Tstart (C) 40.40.50.50.60.
Tend (C) 265.260.270.270.230.
Heat rate (K/min) 7.4.2.2.2.
Initial hold (min)  2.   
Final hold (min) 5.10.  35.
I 1166.1163.1133.31133.31137.
ReferenceMahattanatawee K., Perez-Cacho P.R., et al., 2007Methven L., Tsoukka M., et al., 2007Pang T., Zhu S., et al., 2007Pang T., Zhu S., et al., 2007Paolini, Muselli, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5DB-5ZB-5SE-54HP-5MS
Column length (m) 30.30.30.50.30.
Carrier gas He HeHeHe
Substrate      
Column diameter (mm) 0.250.320.320.320.25
Phase thickness (μm) 0.250.50.5 0.25
Tstart (C) 50.40.40.40.80.
Tend (C) 250.265.265.240.300.
Heat rate (K/min) 4.7.7.8.4.
Initial hold (min) 4.  2. 
Final hold (min) 10.5.5.5. 
I 1164.1169.1164.1170.1159.9
ReferenceQuijano, Salamanca, et al., 2007Ruiz Perez-Cacho, Mahattanatawee, et al., 2007Ruiz Perez-Cacho, Mahattanatawee, et al., 2007Schlutt B., Moran N., et al., 2007Zeng, Zhao, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-5MSDB-5MSCP Sil 5 CBCP Sil 5 CB
Column length (m) 30.30.30.25.25.
Carrier gas N2HeHeH2He
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.25 0.4
Tstart (C) 60.60.40.80.80.
Tend (C) 220.280.200.270.270.
Heat rate (K/min) 5.3.5.10.10.
Initial hold (min) 10. 5.  
Final hold (min)   45.  
I 1165.1159.1168.1139.1139.
ReferenceFlamini, Tebano, et al., 2006Kukic J., Petrovic S., et al., 2006Whetstine M.E.C., Drake M.A., et al., 2006Ziegenbein, Hanssen, et al., 2006Ziegenbein, Hanssen, et al., 2006, 2
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5MSHP-5DB-5CP-Sil 8CB-MSHP-5
Column length (m) 30.30.30.0.30.
Carrier gas  N2N2HeN2
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 40.60.30.40.60.
Tend (C) 200.220.250.280.220.
Heat rate (K/min) 10.5.3.4.5.
Initial hold (min) 3.10.2.2.10.
Final hold (min) 20. 2.5. 
I 1168.1165.1162.1165.1165.
ReferenceCarunchia Whetstine, Croissant, et al., 2005Celik, Gokturk, et al., 2005Colahan-Sederstrom and Peterson, 2005Elmore, Cooper, et al., 2005Flamini, Luigi Cioni, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-5HP-5HP-5MSDB-5MS
Column length (m) 30.30.30.30.60.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 50.50.50.60.40.
Tend (C) 250.250.250.250.200.
Heat rate (K/min) 4.4.4.4.2.
Initial hold (min) 5.5.5.2. 
Final hold (min) 15.15.15.20.20.
I 1161.1158.1161.1162.1164.
ReferenceMahattanatawee, Goodner, et al., 2005Mahattanatawee, Goodner, et al., 2005Mahattanatawee, Goodner, et al., 2005Pino, Mesa, et al., 2005Seo and Baek, 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-5DB-5MSHP-5MSHP-5MS
Column length (m) 25.25.30.30.30.
Carrier gas HeHe HeHe
Substrate      
Column diameter (mm) 0.20.20.250.250.25
Phase thickness (μm) 1.1.0.250.250.25
Tstart (C) 40.40.40.80.80.
Tend (C) 280.280.200.290.290.
Heat rate (K/min) 5.5.10.2.4.
Initial hold (min)   3.  
Final hold (min) 5.5.20.  
I 1162.1162.1164.1157.61158.5
ReferenceSolina, Baumgartner, et al., 2005Solina, Baumgartner, et al., 2005Whetstine, Cadwallader, et al., 2005Zhao, Liang, et al., 2005Zhao, Liang, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSDB-5HP-5HP-5MSHP-5
Column length (m) 30.30.30.30.30.
Carrier gas He N2HeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.25 
Tstart (C) 80.40.60.60.60.
Tend (C) 290.200.220.280.260.
Heat rate (K/min) 6.10.5.4.3.
Initial hold (min)  5.10.5. 
Final hold (min)  15.   
I 1158.31168.1165.1160.1158.
ReferenceZhao, Liang, et al., 2005Avsar, Karagul-Yuceer, et al., 2004Flamini, Luigi Cioni, et al., 2004Grujic-Jovanovic, Skaltsa, et al., 2004Javidnia, Miri, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5SPB-5SPB-5DB-5HP-5
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHeHeN2
Substrate      
Column diameter (mm) 0.320.250.530.250.25
Phase thickness (μm) 1.0.251.50.250.25
Tstart (C) 40.60.100.60.60.
Tend (C) 230.250.250.240.220.
Heat rate (K/min) 5.4.5.3.5.
Initial hold (min) 4.2.  10.
Final hold (min) 10.20. 30. 
I 1155.1166.1165.1165.1165.
ReferenceMahajan, Goddik, et al., 2004Píno, Marbot, et al., 2004Rodríguez-Burruezo, Kollmannsberger, et al., 2004Bader, Caponi, et al., 2003Campeol, Flamini, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-1HP-5DB-5DB-5
Column length (m) 30.50.30.30.30.
Carrier gas N2HeN2HeHe
Substrate      
Column diameter (mm) 0.250.20.250.250.25
Phase thickness (μm) 0.250.330.250.250.25
Tstart (C) 60.60.60.60.60.
Tend (C) 220.250.220.240.240.
Heat rate (K/min) 5.2.5.3.3.
Initial hold (min) 10.5.10.  
Final hold (min)  20.   
I 1165.1130.1164.1165.1164.
ReferenceCampeol, Flamini, et al., 2003Cavalli, Fernandez, et al., 2003Dural, Bagci, et al., 2003Flamini, Cioni, et al., 2003Flamini, Luigi Cioni, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5DB-5DB-5HP-5DB-5
Column length (m) 30.30.30.30.60.
Carrier gas N2  HeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.35.35.60.40.
Tend (C) 220.250.250.280.275.
Heat rate (K/min) 5.4.4.4.7.
Initial hold (min) 10.2.2.5. 
Final hold (min)  4.4.  
I 1165.1144.1144.1158.1162.
ReferenceFlamini, Luigi Cioni, et al., 2003, 2Peterson and Reineccius, 2003Peterson and Reineccius, 2003, 2Skaltsa, Demetzos, et al., 2003Valim, Rouseff, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5BPX-5DB-5DB-5SPB-5
Column length (m) 30.50.30.30.30.
Carrier gas He He He
Substrate      
Column diameter (mm) 0.250.320.250.320.25
Phase thickness (μm) 1.0.50.250.250.25
Tstart (C) 50.60.60.35.60.
Tend (C) 200.250.240.200.250.
Heat rate (K/min) 2.54.3.10.4.
Initial hold (min)  5. 5.2.
Final hold (min)  20. 30.20.
I 1168.31177.1165.1155.1161.
ReferenceXu, van Stee, et al., 2003Bredie, Mottram, et al., 2002Flamini, Cioni, et al., 2002Karagül-Yüceer, Cadwallader, et al., 2002Pino, Marbot, et al., 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SPB-1DB-5DB-1BPX-5BPX-5
Column length (m) 15.30.60.50.50.
Carrier gas   HeHeHe
Substrate      
Column diameter (mm) 0.250.320.320.320.32
Phase thickness (μm) 0.250.251.0.250.25
Tstart (C) 35.35.40.35.35.
Tend (C) 225.200.220.250.250.
Heat rate (K/min) 6.10.2.4.4.
Initial hold (min) 3.5.5.3.3.
Final hold (min) 10.30. 10.10.
I 1132.1162.1137.1173.1175.
ReferenceChisholm, Wilson, et al., 2001Karagül-Yüceer, Drake, et al., 2001Kim, 2001Oruna-Concha, Duckham, et al., 2001Oruna-Concha, Duckham, et al., 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BPX-5BPX-5CP Sil 5 CBHP-5CP Sil 8 CB
Column length (m) 50.50.50.30.60.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.320.320.320.250.25
Phase thickness (μm) 0.250.250.4 0.25
Tstart (C) 35.35.60.50.40.
Tend (C) 250.250.280.200.280.
Heat rate (K/min) 4.4.3.4.4.
Initial hold (min) 3.3.10.1.2.
Final hold (min) 10.10.60.  
I 1172.1173.1135.1161.1165.
ReferenceOruna-Concha, Duckham, et al., 2001Oruna-Concha, Duckham, et al., 2001Pino, Marbot, et al., 2001Shalit, Katzir, et al., 2001Elmore, Mottram, et al., 2000
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BP-5HP-5HP-5BPX-5BPX-5
Column length (m) 50.30.30.50.50.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.320.250.250.320.32
Phase thickness (μm) 1.0.250.250.250.25
Tstart (C) 40.50.50.50.50.
Tend (C) 190.280.280.250.250.
Heat rate (K/min) 2.4.4.4.4.
Initial hold (min) 5.5.5.5.5.
Final hold (min)    5.5.
I 1146.1158.1157.1171.1172.
ReferenceEscudero, Cacho, et al., 2000Lazari, Skaltsa, et al., 2000Lazari, Skaltsa, et al., 2000, 2Mandin, Duckham, et al., 1999Mandin, Duckham, et al., 1999
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-1HP-5BPX-5DB-5MSBP-1
Column length (m) 25.30.50.30.25.
Carrier gas   He He
Substrate      
Column diameter (mm) 0.20.250.320.320.32
Phase thickness (μm) 0.330.250.500.25 
Tstart (C) 35.35.40.40.5.
Tend (C) 250.250.280.200.250.
Heat rate (K/min) 4.5.34.6.5.
Initial hold (min)    5.5.
Final hold (min) 2.2. 30.30.
I 1132.71159.91178.1162.1134.
ReferenceSiegmund and Pfannhauser, 1999Siegmund and Pfannhauser, 1999Aaslyng, Elmore, et al., 1998Cha and Cadwallader, 1998Sinyinda and Gramshaw, 1998
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillary
Active phase BP-1SE-30DB-1
Column length (m) 25.50.60.
Carrier gas He  
Substrate    
Column diameter (mm) 0.320.320.25
Phase thickness (μm)  0.250.25
Tstart (C) 5.50.35.
Tend (C) 250.250.280.
Heat rate (K/min) 5.4.2.
Initial hold (min) 5. 10.
Final hold (min) 30. 10.
I 1134.1130.1136.
ReferenceSinyinda and Gramshaw, 1998Misharina and Golovnya, 1996Specht and Baltes, 1994
Comment MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

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Notes

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, References