Tris(trimethylsilyl)silane
- Formula: C9H28Si4
- Molecular weight: 248.6606
- IUPAC Standard InChI: InChI=1S/C9H28Si4/c1-11(2,3)10(12(4,5)6)13(7,8)9/h10H,1-9H3
- IUPAC Standard InChIKey: SQMFULTZZQBFBM-UHFFFAOYSA-N
- CAS Registry Number: 1873-77-4
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Options:
Gas phase ion energetics data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
De-protonation reactions
C9H27Si4- + =
By formula: C9H27Si4- + H+ = C9H28Si4
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 350.8 ± 2.8 | kcal/mol | D-EA | Brinkman, Berger, et al., 1994 | gas phase; DH revised: Laarhoven, Mulder, et al., 1999 |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 343.0 ± 2.9 | kcal/mol | H-TS | Brinkman, Berger, et al., 1994 | gas phase; DH revised: Laarhoven, Mulder, et al., 1999 |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Brinkman, Berger, et al., 1994
Brinkman, E.A.; Berger, S.; Brauman, J.I.,
alpha-Silyl-substituent stabilization of carbanions and silyl anions,
J. Am. Chem. Soc., 1994, 116, 18, 8304, https://doi.org/10.1021/ja00097a042
. [all data]
Laarhoven, Mulder, et al., 1999
Laarhoven, L.J.J.; Mulder, P.; Wayner, D.D.M.,
Determination of bond dissociation enthalpies in solution by photoacoustic calorimetry,
Acc. Chem. Res., 1999, 32, 4, 342-349, https://doi.org/10.1021/ar9703443
. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.