Bicyclo[2.1.0]pentane

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

Hydrogen + Bicyclo[2.1.0]pentane = Cyclopentane

By formula: H2 + C5H8 = C5H10

Quantity Value Units Method Reference Comment
Δr-235. ± 0.4kJ/molChydRoth, Klarner, et al., 1980liquid phase; solvent: Heptane
Δr-230.7 ± 1.5kJ/molChydTurner, Goebel, et al., 1968liquid phase; solvent: Acetic acid

2,3-Diazabicyclo[2.2.1]-hept-2-ene = Bicyclo[2.1.0]pentane + Nitrogen

By formula: C5H8N2 = C5H8 + N2

Quantity Value Units Method Reference Comment
Δr-22. ± 10.kJ/molCphaHerman and Goodman, 1989solid phase; solvent: Acetonitrile/water

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Roth, Klarner, et al., 1980
Roth, W.R.; Klarner, F.-G.; Lennartz, H.-W., Heats of hydrogenation. II. Heat of hydrogenation of bicyclo[2.1.0]pent-2-ene, an antiaromatic system, Chem. Ber., 1980, 113, 1806-1818. [all data]

Turner, Goebel, et al., 1968
Turner, R.B.; Goebel, P.; Mallon, B.J.; Doering, W.E.; Coburn, J.F., Jr.; Pomerantz, M., Heats of hydrogenation. VIII. Compounds with three- and four-membered rings, J. Am. Chem. Soc., 1968, 90, 4315-4322. [all data]

Herman and Goodman, 1989
Herman, M.S.; Goodman, J.L., Determination of the enthalpy and reaction volume changes of organic photoreactions using photoacoustic calorimetry, J. Am. Chem. Soc., 1989, 111, 1849-1854. [all data]


Notes

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