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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard

Ionization energy determinations

IE (eV) Method Reference Comment
10.8 ± 0.1EIMomigny, Wankenne, et al., 1980LLK
10.98EILifshitz, Shapiro, et al., 1969RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CDO+13.5 ± 0.5D2+HEIMomigny, Wankenne, et al., 1980LLK
CDO+14.2 ± 0.3?EILifshitz, Shapiro, et al., 1969RDSH
CD2O+12.3 ± 0.4HDEIMomigny, Wankenne, et al., 1980LLK
CD3O+11.4 ± 0.5HEIMomigny, Wankenne, et al., 1980LLK
CHDO+12.8 ± 0.3D2EIMomigny, Wankenne, et al., 1980LLK
CHDO+[DCOH+]12.40 ± 0.05D2EIBurgers, Mommers, et al., 1983LBLHLM
CHD2O+13.9 ± 0.2DEIBurgers, Mommers, et al., 1983LBLHLM
CHD2O+11.3 ± 0.3DEIMomigny, Wankenne, et al., 1980LLK
CHD2O+11.60DPIPotapov and Sorokin, 1970RDSH
CHD2O+11.85DEILifshitz, Shapiro, et al., 1969RDSH
CHO+13.1 ± 0.1D2+DEIBurgers, Mommers, et al., 1983LBLHLM
CHO+13.8 ± 0.6D2+DEIMomigny, Wankenne, et al., 1980LLK


Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Momigny, Wankenne, et al., 1980
Momigny, J.; Wankenne, H.; Krier, C., Correlation diagram approach to the dissociative ionization mechanisms of methanol, Int. J. Mass Spectrom. Ion Phys., 1980, 35, 151. [all data]

Lifshitz, Shapiro, et al., 1969
Lifshitz, C.; Shapiro, M.; Sternberg, R., Isotopic effects on metastable transitions. IV. Isotopic methanols, Israel J. Chem., 1969, 7, 391. [all data]

Burgers, Mommers, et al., 1983
Burgers, P.C.; Mommers, A.A.; Holmes, J.L., Ionized oxycarbenes: [COH]+, [HCOH]+, [C(OH)2]+, [HCO2]+, and [COOH]+, their generation, identification, heat of formation, and dissociation characteristics, J. Am. Chem. Soc., 1983, 105, 5976. [all data]

Potapov and Sorokin, 1970
Potapov, V.K.; Sorokin, V.V., Investigation of molecular-ion reactions upon photoionization of methanol and ethanol, Dokl. Akad. Nauk SSSR, 1970, 192, 590, In original 412. [all data]


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