Chromium, pentacarbonyl(phosphorus trifluoride)-
- Formula: C5CrF3O5P
- Molecular weight: 280.0156
- CAS Registry Number: 18461-42-2
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔsubH° | 85.5 ± 2.9 | kJ/mol | N/A | Boxhoorn, Jesse, et al., 1978 |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 8.7 | PE | Yarbrough and Hall, 1978 | |
| 8.70 | EI | Muller, Fenderl, et al., 1971 | |
| 8.56 | PE | Daamen, Boxhoorn, et al., 1978 | Vertical value |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Boxhoorn, Jesse, et al., 1978
Boxhoorn, G.; Jesse, A.C.; Ernsting, J.M.; Oskam, A.,
Thermochim. Acta, 1978, 27, 261. [all data]
Yarbrough and Hall, 1978
Yarbrough, L.W., II; Hall, M.B.,
Photoelectron spectra of substituted chromium, molybdenum, and tungsten pentacarbonyls. Relative π-acceptor and σ-donor properties of various phosphorus ligands,
Inorg. Chem., 1978, 17, 2269. [all data]
Muller, Fenderl, et al., 1971
Muller, J.; Fenderl, K.; Mertschenk, B.,
Die Donor-Akzeptor-Eigenschaften des Liganden Trifluorphosphin in Ubergangsmetallkomplexen,
Chem. Ber., 1971, 104, 700. [all data]
Daamen, Boxhoorn, et al., 1978
Daamen, H.; Boxhoorn, G.; Oskam, A.,
U. V. photoelectron (He I and He II) studies of M(CO)5PX3 (M=Cr, Mo, W and X=F, Cl, Br),
Inorg. Chim. Acta, 1978, 28, 263. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, References
- Symbols used in this document:
ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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