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Chromium, pentacarbonyl(trimethyl phosphite-P)-, (OC-6-22)-


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
8.0PEYarbrough and Hall, 1978LLK
7.80EIPignataro, Foffani, et al., 1968RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C3H9O3PCr+11.55COEITorroni, Innorta, et al., 1974LLK
C4H9O4PCr+10.14COEITorroni, Innorta, et al., 1974LLK
C5H9O5PCr+9.43COEITorroni, Innorta, et al., 1974LLK
C6H6O6PCr+11.9OCH3+COEITorroni, Innorta, et al., 1974LLK
C6H9O6PCr+8.72COEITorroni, Innorta, et al., 1974LLK
C7H6O7PCr+10.8OCH3EITorroni, Innorta, et al., 1974LLK
C7H9O7PCr+8.25COEITorroni, Innorta, et al., 1974LLK

Mass spectrum (electron ionization)

Go To: Top, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin D.HENNEBERG, MAX-PLANCK INSTITUTE, MULHEIM, WEST GERMANY
NIST MS number 61206

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References

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Yarbrough and Hall, 1978
Yarbrough, L.W., II; Hall, M.B., Photoelectron spectra of substituted chromium, molybdenum, and tungsten pentacarbonyls. Relative «pi»-acceptor and «sigma»-donor properties of various phosphorus ligands, Inorg. Chem., 1978, 17, 2269. [all data]

Pignataro, Foffani, et al., 1968
Pignataro, S.; Foffani, A.; Innorta, G.; Distefano, G., Mass spectra and ionization potentials of group VI-B substituted transition-metal carbonyls, Advan. Mass Spectrom., 1968, 4, 323. [all data]

Torroni, Innorta, et al., 1974
Torroni, S.; Innorta, G.; Foffani, A.; Distefano, G., Interpretation of the mass spectra of substituted chromium and tungsten carbonyls by means of appearance potential measurements, J. Organomet. Chem., 1974, 65, 209. [all data]


Notes

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), References