Oxalic acid, 2TMS derivative

• Formula: C₈H₁₈O₄Si₂
• Molecular weight: 234.3971
• IUPAC Standard InChI: InChI=1S/C8H18O4Si2/c1-13(2,3)11-7(9)8(10)12-14(4,5)6/h1-6H3 Copy

  
• IUPAC Standard InChIKey: DDCDOSJHFOGNRO-UHFFFAOYSA-N Copy
• CAS Registry Number: 18294-04-7
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Other names: Ethanedioic acid, bis(trimethylsilyl) ester; Oxalic acid, bis(trimethylsilyl) ester; Bis(trimethylsilyl) oxalate; Oxalic acid (2TMS); Oxalic acid, bis-TMS; Oxalic acid, diTMS; Oxalic acid, bis-TMS ester; Oxalic acid, bistrimethylsilyl; ester; Oxalic acid, TMS
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• Information on this page:
  • Normal alkane RI, non-polar column, temperature ramp
  • References
  • Notes
• Other data available:
  • Mass spectrum (electron ionization)
  • Gas Chromatography
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Normal alkane RI, non-polar column, temperature ramp

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

References

Go To: Top, Normal alkane RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Erxleben, Gessler, et al., 2012
Erxleben, A.; Gessler, A.; Vervliet-Scheebaum, M.; Reski, R., Metabolite profiling of the moss Physcomitrella patens reveals evolutionary conservation of osmoprotective substances, Plant Cell Rep., 2012, 31, 2, 427-436, https://doi.org/10.1007/s00299-011-1177-9 . [all data]

Isidorov, Kotowska, et al., 2005
Isidorov, V.A.; Kotowska, U.; Vinogorova, V.T., GC Identification of organic compounds based on partition coefficients of their TMS derivatives in a hexane-acetonitrile system and retention indices, Anal. Sci., 2005, 21, 12, 1483-1489, https://doi.org/10.2116/analsci.21.1483 . [all data]

Lee, Yanamandra, et al., 2002
Lee, B.Y.; Yanamandra, K.; Thurmon, T.F., Quantitative estimation of organic analytes with a capillary column, Am. Clin. Lab., 2002, May, 30-34. [all data]

Richards, Wong, et al., 1992
Richards, M.; Wong, Y.S.; Tan, W.C.; Tan, I.K.; Ng, T.L., Profiling urinary organic acids for the diagnosis of inborn errors of metabolism by GC/MS, Bull. Sing. N.I. Chem., 1992, 20, 135-143. [all data]

Butts and Rainey, 1971
Butts, W.C.; Rainey, W.T., Jr., Gas Chromatography and Mass Spectrometry of the Trimethylsilyl Derivatives of Inorganic Anions, Anal. Chem., 1971, 43, 4, 538-542, https://doi.org/10.1021/ac60299a004 . [all data]

Notes

Go To: Top, Normal alkane RI, non-polar column, temperature ramp, References

• Symbols used in this document:
  

  Tend	Final temperature
  Tstart	Initial temperature

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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