Methyl vinyl sulfide
- Formula: C3H6S
- Molecular weight: 74.145
- IUPAC Standard InChIKey: AMBKPYJJYUKNFI-UHFFFAOYSA-N
- CAS Registry Number: 1822-74-8
- Chemical structure:
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 342.7 | K | N/A | Weast and Grasselli, 1989 | BS |
Tboil | 343.15 | K | N/A | Katritzky, Pinzelli, et al., 1970 | Uncertainty assigned by TRC = 2. K; TRC |
Tboil | 339.75 | K | N/A | Price and Zomlefer, 1950 | Uncertainty assigned by TRC = 0.6 K; TRC |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
View reactions leading to C3H6S+ (ion structure unspecified)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Proton affinity (review) | 858.2 | kJ/mol | N/A | Hunter and Lias, 1998 | HL |
Quantity | Value | Units | Method | Reference | Comment |
Gas basicity | 829.3 | kJ/mol | N/A | Hunter and Lias, 1998 | HL |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
8.45 | PE | Muller, Schafer, et al., 1976 | Vertical value; LLK |
8.44 | PE | Planckaert, Doucet, et al., 1974 | Vertical value; LLK |
8.45 | PE | Bock, Wagner, et al., 1974 | Vertical value; LLK |
8.45 | PE | Bock, Wagner, et al., 1972 | Vertical value; LLK |
UV/Visible spectrum
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Spectrum
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Additional Data
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Source | Price and Zomlefer, 1950 |
---|---|
Owner | INEP CP RAS, NIST OSRD Collection (C) 2007 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
Origin | INSTITUTE OF ENERGY PROBLEMS OF CHEMICAL PHYSICS, RAS |
Source reference | RAS UV No. 10383 |
Instrument | Beckman quartz spectrophotometer |
Boiling point | 69.5 |
Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Packed | Apiezon M | 130. | 608. | Garbuzov, Misharina, et al., 1985 | He or N2, Chromosorb W, AW-DMCS; Column length: 2.1 m |
Packed | Apiezon M | 130. | 608. | Golovnya, Misharina, et al., 1978 | Chromosorb W, AW-DMCS; Column length: 2.1 m |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]
Katritzky, Pinzelli, et al., 1970
Katritzky, A.R.; Pinzelli, R.F.; Sinnot, M.V.; Topsom, R.D.,
Infrared INtensities as a Quantitative Measure of Intramoelcular Inter- actions XV. Monosubstituted Ethylenes,
J. Am. Chem. Soc., 1970, 92, 6861. [all data]
Price and Zomlefer, 1950
Price, C.C.; Zomlefer, J.,
J. Am Chem. Soc., 1950, 72, 14. [all data]
Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G.,
Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update,
J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018
. [all data]
Muller, Schafer, et al., 1976
Muller, C.; Schafer, W.; Schweig, A.; Thon, N.; Vermeer, H.,
Detection of rotational isomers by variable temperature photoelectron spectroscopy. A new technique in the realm of molecular conformational analysis,
J. Am. Chem. Soc., 1976, 98, 5440. [all data]
Planckaert, Doucet, et al., 1974
Planckaert, A.A.; Doucet, J.; Sandorfy, C.,
Comparative study of the vacuum ultraviolet absorption and photoelectron spectra of some simple ethers and thioethers,
J. Chem. Phys., 1974, 60, 4846. [all data]
Bock, Wagner, et al., 1974
Bock, H.; Wagner, G.; Wittel, K.; Sauer, J.; Seebach, D.,
Photoelektronenspektren und molekuleigenschaften. XXXII. n/π-konjugation in heterosubstituierten athylenen,
Chem. Ber., 1974, 107, 1869. [all data]
Bock, Wagner, et al., 1972
Bock, H.; Wagner, G.; Kroner, J.,
Photoelektronenspektren und molekuleigenschaften, XIV. Die delokalisation des schwefel-elektronenpaar in CH3S-substituierten aromaten,
Chem. Ber., 1972, 105, 3850. [all data]
Garbuzov, Misharina, et al., 1985
Garbuzov, V.G.; Misharina, T.A.; Aerov, A.F.; Golovnya, R.V.,
Gas chromatographic retention indices for sulphur(II)-containing organic substances,
J. Anal. Chem. USSR (Engl. Transl.), 1985, 40, 4, 576-586. [all data]
Golovnya, Misharina, et al., 1978
Golovnya, R.V.; Misharina, T.A.; Garbuzov, V.G.,
Gas chromatographic characterization of sulfur-containing compounds. 4. The effect of unsaturated radicals on the retention indices of the vinyl, allyl, and propargyl alkyl sulfides,
Izv. Akad. Nauk SSSR Ser. Khim., 1978, 11, 2266-2270. [all data]
Notes
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Tboil Boiling point - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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