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Spiro[5.5]undecane

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Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Deltafgas-188.3 ± 3.1kJ/molCcbSubach and Zwolinski, 1975ALS
Deltafgas-191.8kJ/molN/AKozin, Mirzaeva, et al., 1964Value computed using «DELTA»fHliquid° value of -248.0±2.0 kj/mol from Kozin, Mirzaeva, et al., 1964 and «DELTA»vapH° value of 56.2 kj/mol from Subach and Zwolinski, 1975.; DRB

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafliquid-244.5 ± 3.0kJ/molCcbSubach and Zwolinski, 1975 
Deltafliquid-248. ± 2.kJ/molCcbKozin, Mirzaeva, et al., 1964 
Quantity Value Units Method Reference Comment
Deltacliquid-6942.4 ± 2.8kJ/molCcbSubach and Zwolinski, 1975Corresponding «DELTA»fliquid = -244.5 kJ/mol (simple calculation by NIST; no Washburn corrections)
Deltacliquid-6939. ± 2.kJ/molCcbKozin, Mirzaeva, et al., 1964Corresponding «DELTA»fliquid = -248. kJ/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tfus248.65KN/AAnonymous, 1968Uncertainty assigned by TRC = 0.5 K; TRC
Tfus248.7KN/AHogenboon, Webb, et al., 1967Uncertainty assigned by TRC = 0.5 K; TRC
Tfus248.7KN/ANaro, 1960Uncertainty assigned by TRC = 0.6 K; TRC
Quantity Value Units Method Reference Comment
Deltavap56.1 ± 0.1kJ/molVSubach and Zwolinski, 1975ALS
Deltavap56.2kJ/molN/ASubach and Zwolinski, 1975DRB
Deltavap56.1kJ/molCSubach and Zwolinski, 1975AC
Quantity Value Units Method Reference Comment
Deltasub63.6 ± 0.8kJ/molCParker, Steele, et al., 1975See also Pedley and Rylance, 1977.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
NIST MS number 4794

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References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Subach and Zwolinski, 1975
Subach, D.J.; Zwolinski, B.J., Enthalpies of combustion, formation, and vaporization of spiro[4,5]decane, spiro[5,5]undecane, and 7-n-Hexadecylspiro[4,5]decane, J. Chem. Eng. Data, 1975, 20, 232-235. [all data]

Kozin, Mirzaeva, et al., 1964
Kozin, M.P.; Mirzaeva, A.K.; Sosina, I.E.; Elagina, N.V.; Skuratov, S.M., The heats of formation of spiro hydrocarbons, Dokl. Phys. Chem. (Engl. Transl.), 1964, 155, 375-377. [all data]

Anonymous, 1968
Anonymous, R., Properties of hydrocarbon of high molecular weight, Am. Pet. Inst. Res. Proj. 42, Penn. State Univ., 1968. [all data]

Hogenboon, Webb, et al., 1967
Hogenboon, D.L.; Webb, W.; Dixon, J.A., J. Chem. Phys., 1967, 46, 2586. [all data]

Naro, 1960
Naro, P.A., , PhD Thesis, 1960. [all data]

Parker, Steele, et al., 1975
Parker, W.; Steele, W.V.; Stirling, W.; Watt, I., A high-precision aneroid static-bomb combustion calorimeter for samples of about 20 mg. The standard enthalpy of formation of bicyclo[3.3.3]undecane, J. Chem. Thermodyn., 1975, 7, 795-802. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., , Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brighton, 1977. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References