Cyclopentane, tetradecyl-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-374.4 ± 3.1kJ/molCcbProsen, Johnson, et al., 1946Heat of combustion of the gas

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δcliquid-12533.3 ± 2.9kJ/molCcbProsen, Johnson, et al., 1946Heat of combustion of the gas; Corresponding Δfliquid = -374.2 kJ/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tfus281.KN/ASchmidt, 1942Uncertainty assigned by TRC = 1.5 K; TRC
Tfus281.2KN/ASchmidt and Gemassmer, 1940Uncertainty assigned by TRC = 1. K; TRC
Quantity Value Units Method Reference Comment
Δvap95.4kJ/molN/AReid, 1972AC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Reference Comment
73.6490.Dykyj, Svoboda, et al., 1999Based on data from 475. to 648. K.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillaryOV-101190.1962.Kusmierz, Malinski, et al., 1985Column length: 22. m; Column diameter: 0.3 mm
CapillaryApiezon L190.1975.4Kusmierz, Malinski, et al., 1985He; Column length: 20. m; Column diameter: 0.3 mm
CapillarySE-52190.1966.8Kusmierz, Malinski, et al., 1985He; Column length: 40. m; Column diameter: 0.3 mm
PackedMethyl Silicone130.1974.Antheaume and Guiochon, 1965 

Kovats' RI, polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillaryCarbowax 20M150.1986.7Kusmierz, Malinski, et al., 1985He; Column length: 30. m; Column diameter: 0.25 mm

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Prosen, Johnson, et al., 1946
Prosen, E.J.; Johnson, W.H.; Rossini, F.D., Heats of formation and combustion of the normal alkylcyclopentanes and cyclohexanes and the increment per CH2 group for several homologous series of hydrocarbons, J. Res. NBS, 1946, 37, 51-56. [all data]

Schmidt, 1942
Schmidt, A.W., Physical properties of aliphatic compounds, Ber. Dtsch. Chem. Ges. B, 1942, 75, 1399. [all data]

Schmidt and Gemassmer, 1940
Schmidt, A.W.; Gemassmer, A., Physical data of monoalkylcyclopentanes ???., Ber. Dtsch. Chem. Ges. B, 1940, 73, 359-66. [all data]

Reid, 1972
Reid, Robert C., Handbook on vapor pressure and heats of vaporization of hydrocarbons and related compounds, R. C. Wilhort and B. J. Zwolinski, Texas A Research Foundation. College Station, Texas(1971). 329 pages.$10.00, AIChE J., 1972, 18, 6, 1278-1278, https://doi.org/10.1002/aic.690180637 . [all data]

Dykyj, Svoboda, et al., 1999
Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.L.; Hall, K.R., Vapor Pressure of Chemicals: Part A. Vapor Pressure and Antoine Constants for Hydrocarbons and Sulfur, Selenium, Tellurium and Hydrogen Containing Organic Compounds, Springer, Berlin, 1999, 373. [all data]

Kusmierz, Malinski, et al., 1985
Kusmierz, J.; Malinski, E.; Czerwiec, W.; Szafranek, J., Kováts retention indices of high-molecular-weight monomethyl-, cyclopentyl-, cyclohexyl- and phenylalkanes, J. Chromatogr., 1985, 331, 219-228, https://doi.org/10.1016/0021-9673(85)80027-3 . [all data]

Antheaume and Guiochon, 1965
Antheaume, J.; Guiochon, G., Application de la chromatographie en phase gazeuse à l'étude de la composition des fractions moyennes d'un brut pétrolier, Bull. Soc. Chim. Fr., 1965, 2, 298-307. [all data]


Notes

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