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Cyclohexane, decyl-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil560.KN/ASchlenk, 1951Uncertainty assigned by TRC = 3. K; TRC
Quantity Value Units Method Reference Comment
Tfus271.45KN/AAnonymous, 1968Uncertainty assigned by TRC = 0.5 K; TRC
Tfus271.4KN/AStreiff, Hulme, et al., 1955Uncertainty assigned by TRC = 0.04 K; TRC
Tfus271.4KN/AStreiff, Hulme, et al., 1955Uncertainty assigned by TRC = 0.04 K; TRC
Tfus271.43KN/AStreiff, Hulme, et al., 1955Uncertainty assigned by TRC = 0.03 K; TRC
Tfus271.14KN/ABoord, Greenlee, et al., 1949Uncertainty assigned by TRC = 0.4 K; TRC
Quantity Value Units Method Reference Comment
Ttriple271.43KN/AFinke, Messerly, et al., 1965Uncertainty assigned by TRC = 0.02 K; TRC
Ttriple271.420KN/AWaddington, 1951Uncertainty assigned by TRC = 0.05 K; TRC
Ttriple271.440KN/AWaddington, 1951Uncertainty assigned by TRC = 0.02 K; TRC
Quantity Value Units Method Reference Comment
Deltavap78.7 ± 0.8kJ/molCFuchs and Peacock, 1978ALS
Deltavap79.7kJ/molN/AReid, 1972AC
Deltavap78.764kJ/molVFinke, Messerly, et al., 1965, 2ALS

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
76.7386.AStephenson and Malanowski, 1987Based on data from 371. - 425. K.; AC
61.6484.A,MMStephenson and Malanowski, 1987Based on data from 469. - 571. K. See also Camin, Forziati, et al., 1954.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
469.96 - 570.664.156111909.265-110.713Camin, Forziati, et al., 1954Coefficents calculated by NIST from author's data.

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
38.62271.4Acree, 1991AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Schlenk, 1951
Schlenk, W., Justus Liebigs Ann. Chem., 1951, 573, 142-62. [all data]

Anonymous, 1968
Anonymous, R., Properties of hydrocarbon of high molecular weight, Am. Pet. Inst. Res. Proj. 42, Penn. State Univ., 1968. [all data]

Streiff, Hulme, et al., 1955
Streiff, A.J.; Hulme, A.R.; Cowie, P.A.; Krouskop, N.C.; Rossini, F.D., Purification, Purity, and Freezing Points of Sixty-four American Petroleum Institute Standard and Research Hydrocarbons, Anal. Chem., 1955, 27, 411. [all data]

Boord, Greenlee, et al., 1949
Boord, C.E.; Greenlee, K.W.; Perilstein, W.L.; Derfer, J.M., The Synthesis, Purification and Prop. of Hydrocarbons of Low Mol. Wt., Am. Pet. Inst. Res. Proj. 45, Eleventh Annu. Rep., Ohio State Univ., 1949. [all data]

Finke, Messerly, et al., 1965
Finke, H.L.; Messerly, J.F.; Todd, S.S., Thermodynamic properties of n-propyl-, n-butyl-, and n-decyl-substituted cyclohexane from 10 to 370 K, J. Phys. Chem., 1965, 69, 2094-2100. [all data]

Waddington, 1951
Waddington, G., Personal Commun., U. S. Bur. Mines, Bartlesville, OK, 1951. [all data]

Fuchs and Peacock, 1978
Fuchs, R.; Peacock, L.A., Heats of vaporization of monoalkylcyclohexanes by the gas chromatography-calorimetry method, Can. J. Chem., 1978, 56, 2493-24. [all data]

Reid, 1972
Reid, Robert C., Handbook on vapor pressure and heats of vaporization of hydrocarbons and related compounds, R. C. Wilhort and B. J. Zwolinski, Texas A Research Foundation. College Station, Texas(1971). 329 pages.$10.00, AIChE J., 1972, 18, 6, 1278-1278, https://doi.org/10.1002/aic.690180637 . [all data]

Finke, Messerly, et al., 1965, 2
Finke, H.L.; Messerly, J.F.; Todd, S.S., Thermodynamic properties of n-propyl-,n-butyl-, and n-decyl-substituted cyclohexane from 10 to 370°K., Ber. Bunsenges. Phys. Chem., 1965, 69, 2094. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Camin, Forziati, et al., 1954
Camin, David L.; Forziati, Alphonse F.; Rossini, Frederick D., Physical Properties of n-Hexadecane, n-Decylcyclopentane, n-Decylcyclohexane, 1-Hexadecene and n-Decylbenzene, J. Phys. Chem., 1954, 58, 5, 440-442, https://doi.org/10.1021/j150515a015 . [all data]

Acree, 1991
Acree, William E., Thermodynamic properties of organic compounds: enthalpy of fusion and melting point temperature compilation, Thermochimica Acta, 1991, 189, 1, 37-56, https://doi.org/10.1016/0040-6031(91)87098-H . [all data]


Notes

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