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cis-1,2-Cyclohexanediol

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Condensed phase thermochemistry data

Go To: Top, Phase change data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltacsolid-3521.kJ/molCcbRoth and Muller, 1929Corresponding «DELTA»fsolid = -554.8 kJ/mol (simple calculation by NIST; no Washburn corrections)
Deltacsolid-3516. ± 0.4kJ/molCcbVerkade, Coops, et al., 1928At 288 °K; Corresponding «DELTA»fsolid = -559.8 kJ/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

Go To: Top, Condensed phase thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis

Quantity Value Units Method Reference Comment
Tfus371.15KN/AMilas and Sussman, 1937Uncertainty assigned by TRC = 1. K; TRC

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Method Reference Comment
43.7304.MEStephenson and Malanowski, 1987Based on data from 289. - 320. K. See also Zibberman-Granovskaya, 1940.; AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Method Reference Comment
3.3371.6N/AMaria and Eusebio, 2008AC
20.27373.2DSCZhou, Peng, et al., 2002See also Zhou, Zhang, et al., 2003.; AC
3.32371.6N/AMaria, Costa, et al., 1995AC

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
55.19360.4Maria, Costa, et al., 1995, 2CAL
8.93371.6

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


IR Spectrum

Go To: Top, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Gas Phase Spectrum

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IR spectrum
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Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.

Additional Data

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Owner SRD/NIST
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin EPA-IR VAPOR PHASE LIBRARY
State gas

This IR spectrum is from the NIST/EPA Gas-Phase Infrared Database .


Mass spectrum (electron ionization)

Go To: Top, Condensed phase thermochemistry data, Phase change data, IR Spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-IW-4746
NIST MS number 233304

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


References

Go To: Top, Condensed phase thermochemistry data, Phase change data, IR Spectrum, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Roth and Muller, 1929
Roth, W.A.; Muller, Fr., Die Zersetzungswarme der Stickstoffwasserstoffsaure, Ber., 1929, 62, 1188-1194. [all data]

Verkade, Coops, et al., 1928
Verkade, P.E.; Coops, J., Jr.; Maan, Chr.J., Calorimetrische Untersuchungen. XV. Thermochemische studien uber cycloparaffine und ihre derivate: 1. Experimentelle daten fur funf- und sechsgliedrige cyclische diole, Ann., 1928, 467, 217-239. [all data]

Milas and Sussman, 1937
Milas, N.A.; Sussman, S., The Hydroxylation of Unsaturated Substances. IV. The Catalytic Hydroxylation of Unsaturated Hydrocarbons, J. Am. Chem. Soc., 1937, 59, 2345. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Zibberman-Granovskaya, 1940
Zibberman-Granovskaya, A.A., Russ. J. Phys. Chem., 1940, 14, 759. [all data]

Maria and Eusebio, 2008
Maria, Teresa M.R.; Eusebio, M. Ermelinda S., Molar Heat Capacity of 1,2-Cyclohexanediol Isomers From (173 to 428) K, J. Chem. Eng. Data, 2008, 53, 6, 1316-1320, https://doi.org/10.1021/je800047t . [all data]

Zhou, Peng, et al., 2002
Zhou, C.-R.; Peng, G.-S.; Zhang, Y.-D.; Jiang, D.G.; Wang, F.; Li, J.-J.; Shen, X.-Q., Gaoxiao Huaxue Gongcheng Xuebao, 2002, 16, 3, 237. [all data]

Zhou, Zhang, et al., 2003
Zhou, C.; Zhang, Y.; Jiang, D., Chin. J. Chem. Eng., 2003, 11, 5, 598. [all data]

Maria, Costa, et al., 1995
Maria, Teresa M.R.; Costa, Felisbela S.; Leitão, M. Luísa P.; Redinha, J.S., A calorimetric study of phase transitions for some cyclohexanediols, Thermochimica Acta, 1995, 269-270, 405-413, https://doi.org/10.1016/0040-6031(95)02704-1 . [all data]

Maria, Costa, et al., 1995, 2
Maria, T.M.R.; Costa, F.S.; Leitao, M.L.P.; Redinha, J.S., A calorimetric study of phase transitions for some cyclohexanediols, Thermochim. Acta, 1995, 269-270, 405, https://doi.org/10.1016/0040-6031(95)02704-1 . [all data]


Notes

Go To: Top, Condensed phase thermochemistry data, Phase change data, IR Spectrum, Mass spectrum (electron ionization), References