p-Cresol, TMS derivative
- Formula: C10H16OSi
- Molecular weight: 180.3189
- IUPAC Standard InChIKey: KWNZPYGXIBVQKX-UHFFFAOYSA-N
- CAS Registry Number: 17902-32-8
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Silane, trimethyl(4-methylphenoxy)-; Silane, trimethyl(p-tolyloxy)-; Trimethyl(p-methylphenoxy)silane; Trimethyl(p-tolyloxy)silane; 4-Methylphenyl trimethylsilyl ether; p-Cresol, trimethylsilyl ether; 4-Methylphenol, TMS ether; Phenol, 4-methyl, TMS; 4-Methylphenol, TMS; p-Cresol, TMS; p-tolyl trimethylsilyl ether
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Van Den Dool and Kratz RI, non-polar column, temperature ramp
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Column type | Capillary | Capillary | Capillary | Packed | Packed |
---|---|---|---|---|---|
Active phase | OV-1 | SE-52 | Ultra-2 | OV-1 | OV-1 |
Column length (m) | 10. | 25. | 25. | 1.8 | 2. |
Carrier gas | He | He | He | N2 | N2 |
Substrate | 100-120 mesh | Supelcoport | |||
Column diameter (mm) | 0.22 | 0.32 | 0.31 | ||
Phase thickness (μm) | 0.17 | 0.52 | 0.52 | ||
Tstart (C) | 70. | 70. | 50. | 70. | 80. |
Tend (C) | 270. | 270. | 300. | 290. | 240. |
Heat rate (K/min) | 5. | 5. | 5. | 28. | 4. |
Initial hold (min) | 0.5 | ||||
Final hold (min) | |||||
I | 1136. | 1152. | 1154. | 1138. | 1129. |
Reference | Lefevere, Verhaeghe, et al., 1989 | Lefevere, Verhaeghe, et al., 1989 | Tuchman, Bowers, et al., 1984 | Tanaka, Hine, et al., 1980 | Mattsson and Petersson, 1977 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
References
Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Lefevere, Verhaeghe, et al., 1989
Lefevere, M.F.; Verhaeghe, B.J.; Declerck, D.H.; Van Bocxlaer, J.F.; De Leenheer, A.P.; De Sagher, R.M.,
Metabolic Profiling of Urinary Organic Acids by Single and Multicolumn Capillary Gas Chromatography,
J. Chromatogr. Sci., 1989, 27, 1, 23-29, https://doi.org/10.1093/chromsci/27.1.23
. [all data]
Tuchman, Bowers, et al., 1984
Tuchman, M.; Bowers, L.D.; Fregien, K.D.; Crippin, P.J.; Krivit, W.,
Capillary Gas Chromatographic Separation of Urinary Organic Acids. Retention Indices of 101 Urinary Acids on a 5% Phenylmethyl Silicone Capillary Column,
J. Chromatogr. Sci., 1984, 22, 5, 198-202, https://doi.org/10.1093/chromsci/22.5.198
. [all data]
Tanaka, Hine, et al., 1980
Tanaka, K.; Hine, D.G.; West-Dull, A.; Lynn, T.B.,
Gas-chromatographic method of analysis for urinary organic acids. I. Retention indices of 155 metabolically important compounds,
Clin. Chem., 1980, 26, 13, 1839-1846. [all data]
Mattsson and Petersson, 1977
Mattsson, M.; Petersson, G.,
Reference GLC Data for the Analysis of Phenolic Compounds as Trimethylsilyl Derivatives,
J. Chromatogr. Sci., 1977, 15, 12, 546-554, https://doi.org/10.1093/chromsci/15.12.546
. [all data]
Notes
Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, References
- Symbols used in this document:
Tend Final temperature Tstart Initial temperature - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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