Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Phosphorus mononitride


Gas phase ion energetics data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Quantity Value Units Method Reference Comment
IE (evaluated)11.88 ± 0.01eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)789.4kJ/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity757.0kJ/molN/AHunter and Lias, 1998HL

Ionization energy determinations

IE (eV) Method Reference Comment
11.88 ± 0.01PEBulgin, Dyke, et al., 1977LLK
11.85PEWu and Fehlner, 1975LLK
11.8 ± 0.1EICarlson, Kohl, et al., 1968RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
N+20.0 ± 0.5PEICarlson, Kohl, et al., 1968RDSH

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Bulgin, Dyke, et al., 1977
Bulgin, D.K.; Dyke, J.M.; Morris, A., Vacuum ultraviolet photoelectron spectrum of the PN(X(1)3S+) molecule, J. Chem. Soc. Faraday Trans. 2, 1977, 73, 983. [all data]

Wu and Fehlner, 1975
Wu, M.; Fehlner, T.P., Photoelectron spectroscopy of unstable species. The PN molecule, Chem. Phys. Lett., 1975, 36, 114. [all data]

Carlson, Kohl, et al., 1968
Carlson, K.D.; Kohl, F.J.; Uy, O.M., Mass spectrometry of molecules of the nitrogen family, Advan. Chem. Ser., 1968, 72, 245. [all data]


Notes

Go To: Top, Gas phase ion energetics data, References