Bicyclo[3.1.0]hexan-2-ol, 2-methyl-5-(1-methylethyl)-, (1α,2α,5α)-


Normal alkane RI, non-polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5 MSHP-5 MSHP-5 MSDB-1-MSDB-5
Column length (m) 60.30.30.60.30.
Carrier gas HeliumHeliumHeliumHeliumHelium
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 40.60.60.30.60.
Tend (C) 250.220.220.200.240.
Heat rate (K/min) 3.5.5.2.3.
Initial hold (min) 1.10.10.4. 
Final hold (min) 20.  35. 
I 1079.1070.1099.1079.1070.
ReferenceSardashti, Valizadeh, et al., 2013Ogunwande, Flamini, et al., 2010Ogunwande, Flamini, et al., 2010Takeoka, Hobbs, et al., 2010Alim, Goze, et al., 2009
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase RTX-1RTX-1DB-5HP-5SLB-5 MS
Column length (m) 60.60.30.30.30.
Carrier gas HeliumHeliumHeliumN2Helium
Substrate      
Column diameter (mm) 0.220.220.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.45.60.50.
Tend (C) 230.230.250.220.250.
Heat rate (K/min) 2.2.3.5.3.
Initial hold (min)   3.10.2.
Final hold (min) 30.30.5. 10.
I 1053.1054.1068.1070.1069.
ReferenceMuseli, Pau, et al., 2009Museli, Pau, et al., 2009Porto, Decorti, et al., 2009Flamini, Tebano, et al., 2008Lo Presti, Sciarrone, et al., 2008
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase ZB-1ZB-1HP-5 MSHP-5 MSRTX-5
Column length (m) 30.30.30.30.20.
Carrier gas NitrogenNitrogenHeliumHeliumHelium
Substrate      
Column diameter (mm) 0.250.250.250.250.18
Phase thickness (μm) 0.250.250.250.250.20
Tstart (C) 45.45.60.50.50.
Tend (C) 230.230.250.240.280.
Heat rate (K/min) 3.3.2.3.4.
Initial hold (min)   8. 1.
Final hold (min)   15.  
I 1075.1046.1064.1086.1075.
ReferenceMierendorff, Stahl-Biskup, et al., 2008Mierendorff, Stahl-Biskup, et al., 2008Sahraoui, Vian, et al., 2008Sarikurkcu, Tepe, et al., 2008Skalicka-Wozniak, Los, et al., 2008
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5 MSHP-5 MSHP-5 MSDB-5DB-5
Column length (m) 30.30.30.50.50.
Carrier gas HeliumHeliumHeliumNitrogenNitrogen
Substrate      
Column diameter (mm) 0.250.250.250.200.20
Phase thickness (μm) 0.250.250.250.320.32
Tstart (C) 60.50.50.60.60.
Tend (C) 270.230.230.220.220.
Heat rate (K/min) 3.3.3.5.5.
Initial hold (min)  10.10.3.3.
Final hold (min)  10.10.5.5.
I 1102.1065.1098.1097.1064.
ReferenceVictorio, Alviano, et al., 2008Adams, Beauchamp, et al., 2007Adams, Beauchamp, et al., 2007Amiri, 2007Amiri, 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SE-52DB-5DB-5HP-5HP-5
Column length (m) 30.30.30.30.30.
Carrier gas  HeHeN2N2
Substrate      
Column diameter (mm) 0.250.260.260.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 50.60.60.50.50.
Tend (C) 220.240.240.240.240.
Heat rate (K/min) 3.3.3.5.5.
Initial hold (min) 1.  1.1.
Final hold (min) 5.  4.4.
I 1052.1062.1093.1068.1097.
ReferenceBicchi, Cordero, et al., 2007Bos, Woerdenbag, et al., 2007Bos, Woerdenbag, et al., 2007Cheraif, Ben Jannet, et al., 2007Cheraif, Ben Jannet, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-5DB-5HP-5MS5 % Phenyl methyl siloxane
Column length (m) 30.30.30.30.60.
Carrier gas HeliumHeliumHeHeHe
Substrate      
Column diameter (mm) 0.260.260.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.35.60.90.
Tend (C) 290.290.220.250.225.
Heat rate (K/min) 3.3.3.2.3.
Initial hold (min)    8. 
Final hold (min)   40.15.15.
I 1062.1093.1093.1112.1071.
ReferenceElfami, Bos, et al., 2007Elfami, Bos, et al., 2007El-Ghorab A., El-Massry K.F., et al., 2007Ferhat, Meklati, et al., 2007Gil A., Van Baren C.M., et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Col-Elite 5MSHP-1RTX-5 MSRTX-5 MSZB-5
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHeHe 
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 30.60.45.45.60.
Tend (C) 246.240.210.210.220.
Heat rate (K/min) 3.2.3.3.4.
Initial hold (min)     5.
Final hold (min)  20.  20.
I 1074.1044.1070.1104.1070.
ReferenceGudaityte and Venskutonis R.P., 2007Hachicha, Skanji, et al., 2007Hudaib and Aburjai, 2007Hudaib and Aburjai, 2007Mohottalage, Tabacchi, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase ZB-5DB-1DB-1SPB-1DB-1
Column length (m) 30.30.30.30.60.
Carrier gas  HeliumHeliumHeHe
Substrate      
Column diameter (mm) 0.250.250.250.20.25
Phase thickness (μm) 0.250.250.250.20.25
Tstart (C) 60.50.50.70.60.
Tend (C) 220.260.260.220.250.
Heat rate (K/min) 4.2.52.53.5.
Initial hold (min) 5.1.1.  
Final hold (min) 20.20.20.15. 
I 1106.1077.1047.1077.1056.
ReferenceMohottalage, Tabacchi, et al., 2007Monser-Esfahani, Karamkhani, et al., 2007Monser-Esfahani, Karamkhani, et al., 2007Pinto, Salgueiro, et al., 2007Salehi, Fakhari, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-5DB-5HP-5MSHP-5MS
Column length (m) 30.30.30.30.30.
Carrier gas HeHeliumHeliumHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.25  0.250.25
Tstart (C) 50.60.60.60.60.
Tend (C) 240.200.200.280.280.
Heat rate (K/min) 4.2.2.3.3.
Initial hold (min)      
Final hold (min)  20.20.  
I 1066.1053.1068.1033.1065.
ReferenceSefidkon, Abbasi, et al., 2007Tiwary, Nail, et al., 2007Tiwary, Nail, et al., 2007Tzakou, Bazos, et al., 2007Tzakou, Bazos, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5 MSHP-5MSZB-5ZB-5AT-5
Column length (m) 30.30.30.30.60.
Carrier gas HeliumHe  He
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.40.40.40.60.
Tend (C) 280.250.300.300.200.
Heat rate (K/min) 3.3.2.2.4.
Initial hold (min)  5.   
Final hold (min)  10.  20.
I 1070.1060.1070.1097.1067.
ReferenceVagionas, Graikou, et al., 2007Vichi, Riu-Aumatell, et al., 2007Biondi, Sari, et al., 2006Biondi, Sari, et al., 2006Borges, Rojas, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-5HP-5MSHP-5MSDB-5
Column length (m) 30.30.30.30.30.
Carrier gas HeHe  Helium
Substrate      
Column diameter (mm) 0.320.320.250.250.26
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.60.60.60.
Tend (C) 246.246.280.280.290.
Heat rate (K/min) 3.3.4.4.3.
Initial hold (min)      
Final hold (min)      
I 1068.1096.1071.1100.1062.
ReferenceCoronel, Cerda-Garcia-Rojas, et al., 2006Coronel, Cerda-Garcia-Rojas, et al., 2006Ebrahim Sajjadi and Mehregan, 2006Ebrahim Sajjadi and Mehregan, 2006Elfami, Komar, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5BP-1HP-5HP-5HP-1
Column length (m) 30.50.30.30.50.
Carrier gas HeliumHeHeHeHe
Substrate      
Column diameter (mm) 0.260.220.250.250.2
Phase thickness (μm) 0.250.250.250.250.33
Tstart (C) 60.60.50.50.60.
Tend (C) 290.220.300.300.250.
Heat rate (K/min) 3.2.5.5.2.
Initial hold (min)   5.5. 
Final hold (min)  20.5.5.40.
I 1093.1050.1073.1109.1053.
ReferenceElfami, Komar, et al., 2006Fanciullino, Tomi, et al., 2006Figuérédo, Cabassu, et al., 2006Figuérédo, Cabassu, et al., 2006Filippi, Lanfranchi, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-1CP Sil 8 CBCP Sil 5 CB5 % Phenyl methyl siloxane
Column length (m) 30.60.30.30.30.
Carrier gas He  N2Helium
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 50.70.40.50.60.
Tend (C) 250.230.250.200.280.
Heat rate (K/min) 3.2.3.5.3.
Initial hold (min)  2.5.  
Final hold (min) 10.20.20. 30.
I 1072.1056.1074.1057.1041.
ReferenceHavlik, Kokoska, et al., 2006Lan Phi N.T., Nishiyama C., et al., 2006Li, Lee, et al., 2006Martin, Joseph, et al., 2006Marongiu, Piras, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5SE-52HP-5DB-5DB-5
Column length (m) 25.50.30.30.30.
Carrier gas N2HeliumHeHydrogenHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.15 0.250.250.25
Tstart (C) 50.50.60.70.60.
Tend (C) 200.240.220.280.260.
Heat rate (K/min) 4.3.5.4.5.
Initial hold (min) 3. 10.4. 
Final hold (min)      
I 1065.1068.1099.1068.1104.
ReferenceOuamba, Ouabonzi, et al., 2006Ozcan, Chalchat, et al., 2006Pintore G., Chessa M., et al., 2006Pino, Marbot, et al., 2006Sabulal, Dan, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-1DB-5DB-1HP-5MS
Column length (m) 30.60.30.50.30.
Carrier gas HeHeH2N2He
Substrate      
Column diameter (mm) 0.250.250.200.250.25
Phase thickness (μm) 0.25 0.180.250.25
Tstart (C) 40.40.60.90.60.
Tend (C) 240.250.240.240.280.
Heat rate (K/min) 4.4.3.4.3.
Initial hold (min)      
Final hold (min)      
I 1068.1051.1069.1053.1062.
ReferenceSefidkon and Jamzad, 2006Sefidkon, Jamzad, et al., 2006Silva, Oliveira, et al., 2006Velasco-Negueruela, Pérez-Alonso, et al., 2006Basta, Tzakou, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSDB-5Methyl SiliconeHP-5HP-5
Column length (m) 30.50.60.30.30.
Carrier gas He HeHeHe
Substrate      
Column diameter (mm) 0.250.30.30.250.25
Phase thickness (μm) 0.250.25 0.250.25
Tstart (C) 60.60.50.50.50.
Tend (C) 280.240.240.300.300.
Heat rate (K/min) 3.2.3.5.5.
Initial hold (min)    5.5.
Final hold (min)    5.5.
I 1095.1070.1066.1073.1109.
ReferenceBasta, Tzakou, et al., 2005Chagonda and Chalchat, 2005Chalchat and Özcan, 2005Figuérédo, Cabassu, et al., 2005Figuérédo, Cabassu, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSDB-5HP-5HP-5DB-5
Column length (m) 30.30.30.30.30.
Carrier gas  HeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.32
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 50.60.70.70.40.
Tend (C) 250.220.240.240.250.
Heat rate (K/min) 3.4.5.5.5.
Initial hold (min) 10.4.  0.5
Final hold (min) 5.   2.
I 1100.1072.1099.1066.1073.
ReferenceMelkani, Dev, et al., 2005Morteza-Semnani and Saeedi, 2005Oyedeji, Yani, et al., 2005Oyedeji, Yani, et al., 2005Özel, Gögüs, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1DB-1DB-5DB-5HP-5
Column length (m) 60.60.25.25.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.25 
Tstart (C) 50.50.60.60.60.
Tend (C) 250.250.200.200.240.
Heat rate (K/min) 4.4.2.2.5.
Initial hold (min)      
Final hold (min)   80.80. 
I 1096.1036.1079.1091.1068.
ReferenceRasooli and Owlia, 2005Rasooli and Owlia, 2005Rout, Misra, et al., 2005Rout, Misra, et al., 2005Saeidnia, Gohari, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSHP-5MSHP-5MSHP-5MSHP-5MS
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.60.60.60.
Tend (C) 280.275.275.280.280.
Heat rate (K/min) 4.4.4.4.4.
Initial hold (min)      
Final hold (min)      
I 1068.1069.1102.1068.1096.
ReferenceSajjadi S.E. and Eskandari B., 2005Sajjadi and Ghannadi, 2005Sajjadi and Ghannadi, 2005Sajjadi, 2005Sajjadi, 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1DB-5DB-5DB-5DB-5
Column length (m) 60.30.30.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.25  0.250.25
Tstart (C) 60.40.40.60.60.
Tend (C) 250.240.240.230.230.
Heat rate (K/min) 5.4.4.3.3.
Initial hold (min)      
Final hold (min) 10.  20.20.
I 1082.1068.1096.1070.1098.
ReferenceSalehi, Sonboli, et al., 2005Sefidkon and Jamzad, 2005Sefidkon and Jamzad, 2005Skoula and Grayer, 2005Skoula and Grayer, 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSHP-5MSDB-1HP-5MSHP-5MS
Column length (m) 30.30.60.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.60.50.50.
Tend (C) 280.280.250.240.240.
Heat rate (K/min) 3.3.5.3.3.
Initial hold (min)    3.3.
Final hold (min)   10.  
I 1068.1098.1056.1073.1111.
ReferenceSlavkovska, Couladis, et al., 2005Slavkovska, Couladis, et al., 2005Sonboli, Salehi, et al., 2005Tepe B., Sokmen M., et al., 2005Tepe B., Sokmen M., et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSHP-5MSDB-5HP-5HP-5 MS
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHeHeliumHelium
Substrate      
Column diameter (mm) 0.250.250.320.320.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.60.40.60.
Tend (C) 280.280.280.300.275.
Heat rate (K/min) 3.3.3.4.4.
Initial hold (min)      
Final hold (min)    5. 
I 1033.1061.1038.1059.1070.
ReferenceTzakou, Bazos, et al., 2005Tzakou, Bazos, et al., 2005Tzakou and Constantinidis, 2005Utsunomia, Kawata, et al., 2005Ghannadi, Sajjadi, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-5RTX-1DB-5MSNB-30
Column length (m) 25.60.30.30.50.
Carrier gas NitrogenHeN2HeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.2
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.40.60.60.50.
Tend (C) 240.280.300.280.250.
Heat rate (K/min) 3.4.4.3.2.
Initial hold (min)  4.   
Final hold (min)    30. 
I 1068.1066.1087.1039.1057.
ReferenceJAvidnia, Mojab, et al., 2004Kalvandi, Sefidkon, et al., 2004Kalemba and Thiem, 2004Marongiu, Piras, et al., 2004Orav, Stulova, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase NB-30NB-30DB-1DB-1HP-5MS
Column length (m) 50.50.60.60.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.20.200.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 50.50.50.50.60.
Tend (C) 250.250.250.250.280.
Heat rate (K/min) 2.2.4.4.4.
Initial hold (min)      
Final hold (min)      
I 1058.1058.1036.1096.1065.
ReferenceOrav, Stulova, et al., 2004Raal, Paaver, et al., 2004Rasooli and Razzaghi Abyaneh, 2004Rasooli and Razzaghi Abyaneh, 2004Sadeghpour, Asghari, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSDB-5HP-1HP-5HP-5MS
Column length (m) 30.30.30.25.30.
Carrier gas He HeN2He
Substrate      
Column diameter (mm) 0.250.250.250.20.25
Phase thickness (μm) 0.250.250.330.50.25
Tstart (C) 60.50.40.30.60.
Tend (C) 280.250.260.280.275.
Heat rate (K/min) 4.3.2.3.4.
Initial hold (min)  5.5.  
Final hold (min)   20.  
I 1067.1096.1118.1072.1068.
ReferenceSajjadi and Shahpiri, 2004Sefidkon, Jamzad, et al., 2004Senatore, Napolitano, et al., 2004Shafi, Nambiar, et al., 2004Afsharypuor and Jahromy, 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-1DB-1DB-5DB-5
Column length (m) 30.60.60.60.60.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.320.32
Phase thickness (μm) 0.25 0.25  
Tstart (C) 60.50.50.50.50.
Tend (C) 240.250.250.220.220.
Heat rate (K/min) 4.4.4.3.3.
Initial hold (min)      
Final hold (min)      
I 1067.1092.1054.1110.1074.
ReferenceCabanillas, Lopez, et al., 2003Dabiri and Sefidkon, 2003Ebrahimzadeh, Yamini, et al., 2003Edris and Farrag, 2003Edris and Farrag, 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-5HP-5MSHP-5MSRSL-200
Column length (m) 60.60.30.30.30.
Carrier gas HeHeHeHeH2
Substrate      
Column diameter (mm) 0.320.320.250.250.32
Phase thickness (μm)   0.250.250.25
Tstart (C) 50.50.60.60.40.
Tend (C) 200.200.220.275.280.
Heat rate (K/min) 3.3.5.4.6.
Initial hold (min)   20. 5.
Final hold (min)   20. 5.
I 1110.1074.1072.1065.1092.
ReferenceEdris, Shalaby, et al., 2003Edris, Shalaby, et al., 2003Feizbaksh, Saber Tehrani, et al., 2003Ghannadi, Aghazari, et al., 2003Jirovetz, Buchbauer, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase RSL-200DB-5DB-1DB-5MSDB-5
Column length (m) 30.30.30.30.50.
Carrier gas H2HeN2HeHe
Substrate      
Column diameter (mm) 0.320.250.250.250.2
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 40.60.80.60.50.
Tend (C) 280.240.250.240.220.
Heat rate (K/min) 6.3.4.3.3.
Initial hold (min) 5.   2.
Final hold (min) 5.    
I 1060.1070.1044.1097.1067.
ReferenceJirovetz, Buchbauer, et al., 2003Machado, Zoghbi, et al., 2003Mahalwal and Ali, 2003Maia, Taveira, et al., 2003Masotti, Juteau, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5ZB-1ZB-1HP-5HP-5
Column length (m) 50.30.30.30.30.
Carrier gas HeN2N2HeliumHelium
Substrate      
Column diameter (mm) 0.20.250.250.320.32
Phase thickness (μm) 0.250.250.25  
Tstart (C) 50.45.45.70.70.
Tend (C) 220.230.230.210.210.
Heat rate (K/min) 3.3.3.2.2.
Initial hold (min) 2.    
Final hold (min)    60.60.
I 1098.1075.1046.1068.1097.
ReferenceMasotti, Juteau, et al., 2003Mierendorff, Stahl-Biskup, et al., 2003Mierendorff, Stahl-Biskup, et al., 2003Mookdasanit, Tamura, et al., 2003Mookdasanit, Tamura, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1DB-1DB-5DB-5HP-5
Column length (m) 50.50.30.30.30.
Carrier gas N2N2H2H2He
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 95.95.60.60.60.
Tend (C) 240.240.280.280.280.
Heat rate (K/min) 4.4.4.4.3.
Initial hold (min)   10.10. 
Final hold (min)   40.40. 
I 1085.1062.1068.1096.1051.
ReferencePerez-Alonso, Velasco-Negueruela, et al., 2003Perez-Alonso, Velasco-Negueruela, et al., 2003Pino, Marbot, et al., 2003Pino, Marbot, et al., 2003Pitarokili, Tzakou, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5DB-1DB-1HP-5DB-1
Column length (m) 30.60.60.30.60.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.40.40.60.50.
Tend (C) 280.220.220.280.280.
Heat rate (K/min) 3.4.4.4.4.
Initial hold (min)      
Final hold (min)      
I 1086.1052.1058.1067.1087.
ReferencePitarokili, Tzakou, et al., 2003Rasooli and Mirmostafa, 2003Rasooli and Mirmostafa, 2003Sajjadi and Mehregan, 2003Shahmir, Ahmadi, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1DB-5DB-55 % Phenyl methyl siloxaneRSL-200
Column length (m) 60.30.30.30.30.
Carrier gas HeHeHeHeH2
Substrate      
Column diameter (mm) 0.250.2490.2490.250.32
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 50.60.60.75.40.
Tend (C) 280.300.300.200.280.
Heat rate (K/min) 4.3.3.3.6.
Initial hold (min)    4.5.
Final hold (min)  5.5.8.5.
I 1060.1068.1097.1070.1073.
ReferenceShahmir, Ahmadi, et al., 2003Bos, Koulman, et al., 2002Bos, Koulman, et al., 2002Cicció and Gómez-Laurito, 2002Jirovetz, Buchbauer, et al., 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase RSL-200DB-5DB-5MSDB-5MSHP-5
Column length (m) 30.30.30.30.30.
Carrier gas H2HeHeHe 
Substrate      
Column diameter (mm) 0.320.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 40.60.60.60.60.
Tend (C) 280.240.240.240.240.
Heat rate (K/min) 6.3.3.3.3.
Initial hold (min) 5.    
Final hold (min) 5.    
I 1110.1098.1066.1096.1099.
ReferenceJirovetz, Buchbauer, et al., 2002Kobaisy, Tellez, et al., 2002Maia, Zoghbi, et al., 2002Maia, Zoghbi, et al., 2002Novak, Langbehn, et al., 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-5HP-5DB-1DB-1
Column length (m) 30.30.30.50.60.
Carrier gas    N2He
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.60.80.40.
Tend (C) 240.240.240.225.280.
Heat rate (K/min) 3.3.3.4.4.
Initial hold (min)     5.
Final hold (min)      
I 1101.1070.1074.1051.1053.
ReferenceNovak, Langbehn, et al., 2002Novak, Langbehn, et al., 2002Novak, Langbehn, et al., 2002Palá-Paúl, Pérez-Alonso, et al., 2002Sefidkon, Jalili, et al., 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1DB-5MSDB-5MSDB-5DB-5MS
Column length (m) 60.30.30.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 40.60.60.60.60.
Tend (C) 280.270.270.240.240.
Heat rate (K/min) 4.3.3.3.3.
Initial hold (min) 5.    
Final hold (min)      
I 1053.1069.1097.1065.1061.
ReferenceSefidkon, 2002Zoghbi, Andrade, et al., 2002Zoghbi, Andrade, et al., 2002Zoghbi, Andrade, et al., 2002, 2Cherchi, Deidda, et al., 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5MSDB-1DB-1DB-5MSHP-5
Column length (m) 30.60.60.60.30.
Carrier gas HeHeHeHeN2
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.40.40.35.60.
Tend (C) 240.280.280.250.220.
Heat rate (K/min) 3.4.4.3.5.
Initial hold (min)  5.5.5.10.
Final hold (min)      
I 1089.1044.1054.1106.1070.
ReferenceCherchi, Deidda, et al., 2001Dabiri and Sefidkon, 2001Dabiri and Sefidkon, 2001Fernando and Grün, 2001Gallori, Flamini, et al., 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BP-1DB-5MSDB-1OV-101OV-101
Column length (m) 50.30.60.50.50.
Carrier gas HeHeHeHeN2
Substrate      
Column diameter (mm) 0.220.250.250.20.25
Phase thickness (μm) 0.250.250.25  
Tstart (C) 60.60.50.50.80.
Tend (C) 230.240.270.250.200.
Heat rate (K/min) 2.3.4.2.2.
Initial hold (min)      
Final hold (min) 35.30.   
I 1053.1044.1061.1055.1059.
ReferenceLota, de Rocca Serra, et al., 2001Marongiu, Porcedda, et al., 2001Mirza, Ahmadi, et al., 2001Orav and Kann, 2001Yang, 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CP Sil 5 CBDB-1DB-1BP-1HP-5
Column length (m) 25.25.25.25.30.
Carrier gas  NitrogenNitrogenN2He
Substrate      
Column diameter (mm) 0.250.500.500.330.25
Phase thickness (μm) 0.150.250.251.00.25
Tstart (C) 50.60.60.60.60.
Tend (C) 230.220.220.275.275.
Heat rate (K/min) 3.5.5.4.4.
Initial hold (min)      
Final hold (min)      
I 1052.1101.1058.1070.1068.
ReferenceAsekun and Ekundayo, 2000Mallavarapu, Rao, et al., 2000Mallavarapu, Rao, et al., 2000Mohagheghzadeh, Shams-Ardakani, et al., 2000Mohagheghzadeh, Shams-Ardakani, et al., 2000, 2
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase RTX-1RTX-1DB-1DB-1CBP-1
Column length (m) 30.30.25.25.25.
Carrier gas N2N2HeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.3
Phase thickness (μm) 0.250.250.250.25 
Tstart (C) 60.60.50.50.60.
Tend (C) 300.300.290.290.240.
Heat rate (K/min) 4.4.4.4.4.
Initial hold (min)      
Final hold (min)      
I 1087.1059.1068.1097.1067.
ReferenceKalemba, 1999Kalemba, 1999Koulman, 1999Koulman, 1999Labuckas, Zygadlo, et al., 1999
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-1SE-30BP-1CP Sil 5 CBCP Sil 5 CB
Column length (m) 25.30.25.25.25.
Carrier gas H2HeliumN2N2N2
Substrate      
Column diameter (mm) 0.250.250.50.250.25
Phase thickness (μm) 0.250.20 0.390.39
Tstart (C) 40.60.60.60.60.
Tend (C) 220.200.220.220.220.
Heat rate (K/min) 3.3.5.5.5.
Initial hold (min) 5.4.   
Final hold (min) 5. 10.  
I 1062.1057.1059.1088.1059.
ReferenceOberhofer, Nikiforov, et al., 1999Prikhod'ko, Klyuev, et al., 1999Rao, Bhattacharya, et al., 1999Rustaiyan and Nadji, 1999Rustaiyan and Nadji, 1999
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1DB-1DB-1DB-5DB-5
Column length (m) 60.60.60.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 40.40.50.60.60.
Tend (C) 280.280.220.240.240.
Heat rate (K/min) 4.4.4.3.3.
Initial hold (min) 5.5.   
Final hold (min)      
I 1085.1055.1064.1069.1097.
ReferenceSefidkon, Dabiri, et al., 1999Sefidkon, Dabiri, et al., 1999Sefidkon and Mirza, 1999Tellez, Canel, et al., 1999Tellez, Canel, et al., 1999
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-101DB-5DB-5DB-5MSDB-5
Column length (m) 25.30.30.30.30.
Carrier gas NitrogenHeHeHeHe
Substrate      
Column diameter (mm) 0.200.250.250.250.25
Phase thickness (μm)  0.250.250.250.25
Tstart (C) 60.60.60.60.60.
Tend (C) 220.240.240.240.240.
Heat rate (K/min) 4.3.3.3.3.
Initial hold (min) 0.    
Final hold (min) 0.    
I 1059.1066.1095.1072.1066.
ReferenceTropnikova, Zenkevich, et al., 1999Zoghbi, Andrade, et al., 1999Zoghbi, Andrade, et al., 1999Zoghbi, Andrade, et al., 1999, 2Maia, Zohhbi, et al., 1998
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-1SPB-SulfurSPB-SulfurDB-1
Column length (m) 25.60.30.30. 
Carrier gas HeHeHeHe 
Substrate      
Column diameter (mm) 0.20.250.320.32 
Phase thickness (μm) 0.330.254.4. 
Tstart (C) 70.50.45.45.80.
Tend (C) 290.280.240.240.220.
Heat rate (K/min) 3.4.5.5.6.
Initial hold (min) 8.5.13.13. 
Final hold (min) 20. 5.5. 
I 1067.1076.1073.1073.1066.
ReferencePoiana, Sicari, et al., 1998Stashenko, Cervantes, et al., 1998Mariaca, Berger, et al., 1997Mariaca, Berger, et al., 1997Salgueiro, Vila, et al., 1997
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1HP-1HP-1DB-1SPB-1
Column length (m)  23.23.60.50.
Carrier gas  HeHeHeHe
Substrate      
Column diameter (mm)  0.320.320.320.2
Phase thickness (μm)  0.170.170.500.33
Tstart (C) 80.60.60.50.40.
Tend (C) 220.250.250.250.200.
Heat rate (K/min) 6.5.5.8.3.
Initial hold (min)  3.3.1.3.
Final hold (min)  30.30.6.30.
I 1037.1080.1050.1102.1054.
ReferenceSalgueiro, Vila, et al., 1997Ayedoun, Adeoti, et al., 1996Ayedoun, Adeoti, et al., 1996Sagrero-Nieves and Bartley, 1996Wong and Lai, 1996
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SPB-1DB-1DB-1DB-1DB-1
Column length (m) 50.60.60.60.60.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.20.250.250.250.25
Phase thickness (μm) 0.330.250.250.250.25
Tstart (C) 40.70.70.70.70.
Tend (C) 200.270.270.270.270.
Heat rate (K/min) 3.2.52.52.52.5
Initial hold (min) 3.5.5.5.5.
Final hold (min) 30.    
I 1085.1088.1088.1054.1054.
ReferenceWong and Lai, 1996Tirado, Stashenko, et al., 1995Tirado, Stashenko, et al., 1995Tirado, Stashenko, et al., 1995Tirado, Stashenko, et al., 1995
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Methyl SiliconeMethyl SiliconeCP Sil 5 CBOV-101OV-101
Column length (m) 50.50.25.50.50.
Carrier gas N2N2   
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.170.17   
Tstart (C) 80.80.60.80.80.
Tend (C) 200.200.280.200.200.
Heat rate (K/min) 2.3.5.2.2.
Initial hold (min)      
Final hold (min)      
I 1060.1057.1058.1059.1059.
ReferenceGopalakrishnan, Menon, et al., 1993Gopalakrishnan, Menon, et al., 1993Kaul, Singh, et al., 1993Tamura, Yang, et al., 1993Tamura, Yang, et al., 1993
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SE-54SE-54BP-1BP-1SE-30
Column length (m) 30.30.50.50.40.
Carrier gas HydrogenHydrogenH2H2He
Substrate      
Column diameter (mm) 0.250.250.300.300.50
Phase thickness (μm) 0.250.25  0.75
Tstart (C) 60.60.40.40.30.
Tend (C) 250.250.250.250.220.
Heat rate (K/min) 2.2.10.10.3.
Initial hold (min) 5.5.1.1. 
Final hold (min) 2.2.   
I 1093.1066.1089.1058.1053.
ReferenceKollmannsberger, Nitz, et al., 1992Kollmannsberger, Nitz, et al., 1992Brophy, Davies, et al., 1989Brophy, Davies, et al., 1989de Pooter, de Buyck, et al., 1989
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SE-30OV-101OV-101OV-101OV-1
Column length (m) 40.50.50.50.50.
Carrier gas HeN2N2N2He
Substrate      
Column diameter (mm) 0.500.250.250.250.20
Phase thickness (μm) 0.75   0.20
Tstart (C) 30.80.80.80.30.
Tend (C) 220.200.200.200.220.
Heat rate (K/min) 3.2.2.2.2.
Initial hold (min)      
Final hold (min)      
I 1088.1069.1059.1060.1053.
Referencede Pooter, de Buyck, et al., 1989Sugisawa, Yamamoto, et al., 1989Sugisawa, Yang, et al., 1989Sugisawa, Yang, et al., 1989de Pooter, Nicolai, et al., 1988
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-1OV-101OV-101OV-101OV-101
Column length (m) 50.50.50.50.50.
Carrier gas He    
Substrate      
Column diameter (mm) 0.200.300.300.300.30
Phase thickness (μm) 0.20    
Tstart (C) 30.40.40.40.40.
Tend (C) 220.230.230.230.230.
Heat rate (K/min) 2.3.53.53.53.5
Initial hold (min)  5.5.5.5.
Final hold (min)      
I 1096.1080.1088.1101.1053.
Referencede Pooter, Nicolai, et al., 1988Nykanen, 1986Nykanen, 1986Nykanen, 1986Nykanen, 1986
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-101OV-101OV-1OV-1OV-1
Column length (m) 50.50.40.40. 
Carrier gas   HeHeHe
Substrate      
Column diameter (mm) 0.300.300.50.5 
Phase thickness (μm)   0.750.75 
Tstart (C) 40.40.30.30.40.
Tend (C) 230.230.220.220.220.
Heat rate (K/min) 3.53.53.3.2.
Initial hold (min) 5.5.   
Final hold (min)      
I 1060.1071.1086.1054.1089.
ReferenceNykanen, 1986Nykanen, 1986de Pooter, de Buyck, et al., 1986de Pooter, de Buyck, et al., 1986De Pooter, De Buyck, et al., 1986
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type Capillary
Active phase OV-1
Column length (m)  
Carrier gas He
Substrate  
Column diameter (mm)  
Phase thickness (μm)  
Tstart (C) 40.
Tend (C) 220.
Heat rate (K/min) 2.
Initial hold (min)  
Final hold (min)  
I 1056.
ReferenceDe Pooter, De Buyck, et al., 1986
Comment MSDC-RI

References

Go To: Top, Normal alkane RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

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Notes

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