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di-«mu»-carbonyldecacarbonyl-triangulo-triiron


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafgas-1746. ± 24.kJ/molReviewMartinho Simões 
Deltafgas-1756. ± 25.kJ/molReviewMartinho Simões 
Deltafgas-1751. ± 23.kJ/molReviewMartinho SimõesSelected data. Average of the values from Connor, Skinner, et al., 1973

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafsolid-1842. ± 12.kJ/molReviewMartinho Simões 
Deltafsolid-1852. ± 13.kJ/molReviewMartinho Simões 
Deltafsolid-1847.1 ± 8.8kJ/molReviewMartinho SimõesSelected data. Average of the values from Connor, Skinner, et al., 1973

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltasub96. ± 21.kJ/molN/APilcher and Skinner, 1983See also Connor, Skinner, et al., 1972.; AC
Deltasub96. ± 21.kJ/molTD-HFCConnor, Skinner, et al., 1973MS

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C12Fe3O12 (cr) = 12Carbon monoxide (g) + 3iron (cr)

By formula: C12Fe3O12 (cr) = 12CO (g) + 3Fe (cr)

Quantity Value Units Method Reference Comment
Deltar516. ± 12.kJ/molTD-HFCConnor, Skinner, et al., 1973 
Deltar526. ± 13.kJ/molHAL-HFCConnor, Skinner, et al., 1973 

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
7.44PEDeKock, Wong, et al., 1982LBLHLM
7.8PEWong, Dutta, et al., 1981LLK

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Connor, Skinner, et al., 1973
Connor, J.A.; Skinner, H.A.; Virmani, Y., High temperature microcalorimetric studies of the thermal decomposition and iodination of polynuclear carbonyls of Fe, Co, Ru, Rh, Re, Os and Ir, Faraday Symp. Chem. Soc., 1973, 8, 18, https://doi.org/10.1039/fs9730800018 . [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Connor, Skinner, et al., 1972
Connor, J.A.; Skinner, H.A.; Virmani, Y., Microcalorimetric studies. Thermal decomposition and iodination of metal carbonyls, J. Chem. Soc., Faraday Trans. 1, 1972, 68, 0, 1754, https://doi.org/10.1039/f19726801754 . [all data]

DeKock, Wong, et al., 1982
DeKock, R.L.; Wong, K.S.; Fehlner, T.P., Effects of bridging hydrogens on metal-netal bonds. 2. UV photoelectron and UV-visible spectra and quantum chemical calculations for Fe3(«mu»-H)3(CO)9(«mu»3-CCH3) and Co3(CO)9(«mu»3-CCH3), Inorg. Chem., 1982, 21, 3203. [all data]

Wong, Dutta, et al., 1981
Wong, K.S.; Dutta, T.L.; Fehlner, T.P., The proton as a probe of cluster bonding. The UV photoelectron spectra of two hydrido transition metal clusters, J. Organomet. Chem., 1981, 215, 48. [all data]


Notes

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