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C2H3D3O


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C2H2D5O- + Hydrogen cation = C2H3D3O

By formula: C2H2D5O- + H+ = C2H3D3O

Quantity Value Units Method Reference Comment
Deltar377.6 ± 2.3kcal/molG+TSDang, Motell, et al., 1993gas phase; CIDC in SIFT at 30 V: 0.20 ± 0.15 kcal/mol weaker than protio
Quantity Value Units Method Reference Comment
Deltar371.0 ± 2.2kcal/molCIDCDang, Motell, et al., 1993gas phase; CIDC in SIFT at 30 V: 0.20 ± 0.15 kcal/mol weaker than protio

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

De-protonation reactions

C2H2D5O- + Hydrogen cation = C2H3D3O

By formula: C2H2D5O- + H+ = C2H3D3O

Quantity Value Units Method Reference Comment
Deltar377.6 ± 2.3kcal/molG+TSDang, Motell, et al., 1993gas phase; CIDC in SIFT at 30 V: 0.20 ± 0.15 kcal/mol weaker than protio
Quantity Value Units Method Reference Comment
Deltar371.0 ± 2.2kcal/molCIDCDang, Motell, et al., 1993gas phase; CIDC in SIFT at 30 V: 0.20 ± 0.15 kcal/mol weaker than protio

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dang, Motell, et al., 1993
Dang, T.T.; Motell, E.L.; Travers, M.J.; Clifford, E.P.; Ellison, G.B.; Depuy, C.H.; Bierbaum, V.M., Experimental and Computational Studies of Deuterated Ethanols - Gas-Phase Acidities, Electron Affinities and Bond Dissociation Energies, Int. J. Mass Spectrom. Ion Proc., 1993, 123, 3, 171, https://doi.org/10.1016/0168-1176(93)87096-B . [all data]


Notes

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