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Cl2O3


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 37450 gas 220 320 Hayman and Cox, 1989
Burkholder, Orlando, et al., 1990
Burkholder, Mauldin, et al., 1993
Harwood, Rowley, et al., 1995

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

1225 vs gas IR Schell-Sorokin, Bethune, et al., 1982
Burkholder, Orlando, et al., 1990
1216.0 Ne IR Muller and Willner, 1993
1226.1 Ar IR Cheng and Lee, 1989
1213.5 Ar IR Muller and Willner, 1993
1203.1 Ne IR Muller and Willner, 1993
1200.7 Ar IR Muller and Willner, 1993
1057 s gas IR Burkholder, Orlando, et al., 1990
1060 Ne IR Muller and Willner, 1993
1058.4 Ar IR Cheng and Lee, 1989
Muller and Willner, 1993
740 w gas IR Burkholder, Orlando, et al., 1990
560 w m gas IR Burkholder, Orlando, et al., 1990

Additional references: Jacox, 1994, page 302; Jacox, 1998, page 307; Friedl, Birk, et al., 1995

Notes

wWeak
mMedium
sStrong
vsVery strong
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hayman and Cox, 1989
Hayman, G.D.; Cox, R.A., UV absorption spectrum and thermochemistry of Cl2O3 formed in the photolysis of OClO-containing mixtures at low temperatures, Chem. Phys. Lett., 1989, 155, 1, 1, https://doi.org/10.1016/S0009-2614(89)87350-6 . [all data]

Burkholder, Orlando, et al., 1990
Burkholder, J.B.; Orlando, J.J.; Howard, C.J., Ultraviolet absorption cross sections of chlorine oxide (Cl2O2) between 210 and 410 nm, J. Phys. Chem., 1990, 94, 2, 687, https://doi.org/10.1021/j100365a033 . [all data]

Burkholder, Mauldin, et al., 1993
Burkholder, J.B.; Mauldin, R.L., III; Yokelson, R.J.; Solomon, S.; Ravishankara, A.R., Kinetic, thermochemical, and spectroscopic study of chlorine oxide (Cl2O3), J. Phys. Chem., 1993, 97, 29, 7597, https://doi.org/10.1021/j100131a032 . [all data]

Harwood, Rowley, et al., 1995
Harwood, M.H.; Rowley, D.M.; Freshwater, R.A.; Cox, R.A.; Jones, R.L., J. Chem. Soc., 1995, Faraday Trans. 91, 3027. [all data]

Schell-Sorokin, Bethune, et al., 1982
Schell-Sorokin, A.J.; Bethune, D.S.; Lankard, J.R.; Loy, M.M.T.; Sorokin, P.P., Chlorine perchlorate a major photolysis product of chlorine dioxide, J. Phys. Chem., 1982, 86, 24, 4653, https://doi.org/10.1021/j100221a001 . [all data]

Muller and Willner, 1993
Muller, H.S.P.; Willner, H., Vibrational and electronic spectra of chlorine dioxide, OClO, and chlorine superoxide ClOO, isolated in cryogenic matrixes, J. Phys. Chem., 1993, 97, 41, 10589, https://doi.org/10.1021/j100143a013 . [all data]

Cheng and Lee, 1989
Cheng, B.-M.; Lee, Y.-P., Production and trapping of gaseous dimeric ClO: The infrared spectrum of chlorine peroxide (ClOOCl) in solid argon, J. Chem. Phys., 1989, 90, 11, 5930, https://doi.org/10.1063/1.456359 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Friedl, Birk, et al., 1995
Friedl, R.R.; Birk, M.; Oh, J.J.; Cohen, E.A., The Rotational Spectrum and Molecular Structure of Chlorine Chlorate, J. Mol. Spectrosc., 1995, 170, 2, 383, https://doi.org/10.1006/jmsp.1995.1079 . [all data]


Notes

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