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Hydrazine, trimethyl-

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
7.9 ± 0.1EIDibeler, Franklin, et al., 1959RDSH
8.74PERademacher, 1975Vertical value; LLK
8.67PENelsen and Buschek, 1974Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
N2?+13.2 ± 0.2?EIDibeler, Franklin, et al., 1959RDSH
C2H4N?+11.7 ± 0.2?EIDibeler, Franklin, et al., 1959RDSH
N2H2?+11.9 ± 1.0?EIDibeler, Franklin, et al., 1959RDSH
N2H3?+11.7 ± 1.0?EIDibeler, Franklin, et al., 1959RDSH
CH3+14.0 ± 0.5?EIDibeler, Franklin, et al., 1959RDSH
C2H5N2+11.1 ± 0.4?EIDibeler, Franklin, et al., 1959RDSH
C2H6N+11.1 ± 0.2?EIDibeler, Franklin, et al., 1959RDSH
C2H7N2+9.4 ± 0.1CH3EIDibeler, Franklin, et al., 1959RDSH
C3H7+10.7 ± 0.3?EIDibeler, Franklin, et al., 1959RDSH
C3H7N2+10.7 ± 0.1H2+HEIDibeler, Franklin, et al., 1959RDSH
C3H8N2+8.2 ± 0.1H2EIDibeler, Franklin, et al., 1959RDSH
C3H9N2+8.9 ± 0.1HEIDibeler, Franklin, et al., 1959RDSH
N2H4+11.9 ± 0.2?EIDibeler, Franklin, et al., 1959RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dibeler, Franklin, et al., 1959
Dibeler, V.H.; Franklin, J.L.; Reese, R.M., Electron impact studies of hydrazine and the methyl-substituted hydrazines, J. Am. Chem. Soc., 1959, 81, 68. [all data]

Rademacher, 1975
Rademacher, P., Acyclische Hydrazine, Chem. Ber., 1975, 108, 1548. [all data]

Nelsen and Buschek, 1974
Nelsen, S.F.; Buschek, J.M., Photoelectron spectra of hydrazines. III. Evidence for similar lone pair-lone pair dihedral angles for acyclic hydrazines, J. Am. Chem. Soc., 1974, 96, 2392. [all data]


Notes

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