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Propane, 2-methyl-2-(1-methylethoxy)-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Tboil360.8KN/AWeast and Grasselli, 1989BS
Tboil360.7KN/AMajer and Svoboda, 1985 
Tboil360.8KN/AOlson, Hipsher, et al., 1947Uncertainty assigned by TRC = 0.5 K; TRC
Tboil360.8KN/ANorris and Rigby, 1932Uncertainty assigned by TRC = 0.4 K; TRC
Quantity Value Units Method Reference Comment
Tfus185.08KN/AOlson, Hipsher, et al., 1947Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Deltavap34.67kJ/molN/AMajer and Svoboda, 1985 
Deltavap36.2kJ/molCGCVerevkin, Krasnykh, et al., 2003See also Verevkin, 2002 and Verevkin, Krasnykh, et al., 2003.; AC
Deltavap34.4 ± 0.6kJ/molEBVarushchenko, Pashchenko, et al., 2002Based on data from 305. - 360. K.; AC
Deltavap34.5 ± 0.2kJ/molCVarushchenko, Pashchenko, et al., 2002See also Dorofeeva, Yungman, et al., 2004.; AC
Deltavap35.1kJ/molVSmutny and Bondi, 1961Heat of combustion corrected for pressure; ALS

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
30.5360.7N/AMajer and Svoboda, 1985 
34.0322.EBKraehenbuehl and Gmehling, 1994Based on data from 307. - 360. K.; AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
8.46184.8Varushchenko, Druzhinina, et al., 2001See also Dorofeeva, Yungman, et al., 2004.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Olson, Hipsher, et al., 1947
Olson, W.T.; Hipsher, H.F.; Buess, C.M.; Goodman, I.A.; Hart, I.; Lamneck, J.H.; Gibbons, L.C., The Synthesis and Purification of Ethers, J. Am. Chem. Soc., 1947, 69, 2451-4. [all data]

Norris and Rigby, 1932
Norris, J.F.; Rigby, G.W., Reactivity of Atoms and Groups in Organic Compounds XII. The Preparation and Properties of Mixed Aliphatic Ethers with Special Reference to those Containing the Tert-Butyl Radical, J. Am. Chem. Soc., 1932, 54, 2088. [all data]

Verevkin, Krasnykh, et al., 2003
Verevkin, Sergey P.; Krasnykh, Eugen L.; Vasiltsova, Tatiana V.; Heintz, Andreas, Determination of Ambient Temperature Vapor Pressures and Vaporization Enthalpies of Branched Ethers, J. Chem. Eng. Data, 2003, 48, 3, 591-599, https://doi.org/10.1021/je0255980 . [all data]

Verevkin, 2002
Verevkin, Sergey P., Improved Benson Increments for the Estimation of Standard Enthalpies of Formation and Enthalpies of Vaporization of Alkyl Ethers, Acetals, Ketals, and Ortho Esters, J. Chem. Eng. Data, 2002, 47, 5, 1071-1097, https://doi.org/10.1021/je020023o . [all data]

Varushchenko, Pashchenko, et al., 2002
Varushchenko, R.M.; Pashchenko, L.L.; Druzhinina, A.I.; Churkina, A.Yu.; Vorob'ev, I.I.; Kravchun, S.N., Zh. Fiz. Khim., 2002, 76, 4, 632. [all data]

Dorofeeva, Yungman, et al., 2004
Dorofeeva, O.V.; Yungman, V.S.; Varushchenko, R.M.; Druzhinina, A.I., Ideal Gas Thermodynamic Properties of Propyl tert-Butyl Ethers from Density Functional Theory Results Combined with Experimental Data, International Journal of Thermophysics, 2004, 25, 4, 1097-1113, https://doi.org/10.1023/B:IJOT.0000038503.77644.a4 . [all data]

Smutny and Bondi, 1961
Smutny, E.J.; Bondi, A., Di-t-butyl ether: Strain energy and physical properties, J. Phys. Chem., 1961, 65, 546-550. [all data]

Kraehenbuehl and Gmehling, 1994
Kraehenbuehl, M.A.; Gmehling, J., Vapor Pressures of Methyl tert-Butyl Ether, Ethyl tert-Butyl Ether, Isopropyl tert-Butyl Ether, tert-Amyl Methyl Ether, and tert-Amyl Ethyl Ether, J. Chem. Eng. Data, 1994, 39, 4, 759-762, https://doi.org/10.1021/je00016a026 . [all data]

Varushchenko, Druzhinina, et al., 2001
Varushchenko, R.M.; Druzhinina, A.I.; Churkina, A.Yu.; Zhi, C.-T., Zh. Fiz. Khim., 2001, 75, 8, 1351. [all data]


Notes

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