Sodium ion (1+)
- Formula: Na+
- Molecular weight: 22.98922070
- IUPAC Standard InChIKey: FKNQFGJONOIPTF-UHFFFAOYSA-N
- CAS Registry Number: 17341-25-2
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Sodium cation
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Reaction thermochemistry data: reactions 51 to 100, reactions 101 to 150, reactions 151 to 200, reactions 201 to 248
- Ion clustering data
- Options:
Gas phase thermochemistry data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
S°gas,1 bar | 147.95 | J/mol*K | Review | Chase, 1998 | Data last reviewed in December, 1983 |
Reaction thermochemistry data
Go To: Top, Gas phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Reactions 1 to 50
By formula: (Na+ 3H2O) + H2O = (Na+
4H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 55. ± 4. | kJ/mol | AVG | N/A | Average of 7 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 99. ± 10. | J/mol*K | AVG | N/A | Average of 6 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 26. | kJ/mol | ES/HPMS | Blades, Klassen, et al., 1996 | gas phase; M |
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
54.8 (+5.9,-0.) | CID | Dalleska, Tjelta, et al., 1994 | gas phase; guided ion beam CID, Na+ (3s0); M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
28. | 293. | ES/HPMS | Klassen, Blades, et al., 1995 | gas phase; M |
27. | 300. | HPMS | Blades, Jayaweera, et al., 1990 | gas phase; electrospray, Entropy change calculated or estimated; M |
By formula: (Na+ H2O) + H2O = (Na+
2H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 79. ± 8. | kJ/mol | AVG | N/A | Average of 8 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92.9 | J/mol*K | HPMS | Dzidic and Kebarle, 1970 | gas phase; M |
![]() | 96. | J/mol*K | N/A | Blades, Jayaweera, et al., 1990 | gas phase; electrospray, Entropy change calculated or estimated; M |
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
82.0 (+5.9,-0.) | CID | Dalleska, Tjelta, et al., 1994 | gas phase; guided ion beam CID, Na+ (3s0); M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
41.8 | 300. | HPMS | Blades, Jayaweera, et al., 1990 | gas phase; electrospray, Entropy change calculated or estimated; M |
By formula: (Na+ 2H2O) + H2O = (Na+
3H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 62.3 | kJ/mol | HPMS | Tang, Lian, et al., 1976 | gas phase; M |
![]() | 66.1 | kJ/mol | HPMS | Dzidic and Kebarle, 1970 | gas phase; M |
![]() | 69.9 ± 5.9 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
![]() | 67.4 | kJ/mol | ES/HPMS | Blades, Klassen, et al., 1996 | gas phase; M |
![]() | 70. ± 10. | kJ/mol | HPMS | Blades, Jayaweera, et al., 1990 | gas phase; electrospray, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 87.0 | J/mol*K | HPMS | Tang, Lian, et al., 1976 | gas phase; M |
![]() | 91.6 | J/mol*K | HPMS | Dzidic and Kebarle, 1970 | gas phase; M |
![]() | 92.0 | J/mol*K | ES/HPMS | Blades, Klassen, et al., 1996 | gas phase; M |
![]() | 96. | J/mol*K | N/A | Blades, Jayaweera, et al., 1990 | gas phase; electrospray, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 40. | kJ/mol | ES/HPMS | Blades, Klassen, et al., 1996 | gas phase; M |
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
70.3 (+5.9,-0.) | CID | Dalleska, Tjelta, et al., 1994 | gas phase; guided ion beam CID, Na+ (3s0); M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
39. | 300. | HPMS | Blades, Jayaweera, et al., 1990 | gas phase; electrospray, Entropy change calculated or estimated; M |
By formula: Na+ + H2O = (Na+ H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 100. | kJ/mol | HPMS | Dzidic and Kebarle, 1970 | gas phase; M |
![]() | 87.9 ± 5.9 | kJ/mol | CIDC | Amicangelo and Armentrout, 2001 | Anchor NH3=24.41; RCD |
![]() | 82.0 ± 5.9 | kJ/mol | CIDC | Amicangelo and Armentrout, 2001 | Anchor NH3=24.41; RCD |
![]() | 95.0 ± 7.9 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
![]() | 111. | kJ/mol | MS | Burdett and Hayhurst, 1982 | gas phase; flame source, 1600 K; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 90.0 | J/mol*K | HPMS | Dzidic and Kebarle, 1970 | gas phase; M |
![]() | 92. | J/mol*K | MS | Burdett and Hayhurst, 1982 | gas phase; flame source, 1600 K; M |
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
94.6 (+7.5,-0.) | CID | Dalleska, Tjelta, et al., 1994 | gas phase; guided ion beam CID, Na+ (3s0); M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
65.7 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: (Na+ 4H2O) + H2O = (Na+
5H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 44.8 | kJ/mol | HPMS | Tang, Lian, et al., 1976 | gas phase; M |
![]() | 48.5 | kJ/mol | HPMS | Tang and Castleman, 1972 | gas phase; M |
![]() | 51.5 | kJ/mol | HPMS | Dzidic and Kebarle, 1970 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 104. | J/mol*K | HPMS | Tang, Lian, et al., 1976 | gas phase; M |
![]() | 111. | J/mol*K | HPMS | Tang and Castleman, 1972 | gas phase; M |
![]() | 118. | J/mol*K | HPMS | Dzidic and Kebarle, 1970 | gas phase; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
20. | 293. | ES/HPMS | Klassen, Blades, et al., 1995 | gas phase; M |
By formula: (Na+ CO2) + H2O = (Na+
H2O
CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 86.6 | kJ/mol | HPMS | Peterson, Mark, et al., 1984 | gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M |
![]() | 95.8 | kJ/mol | FA | Perry, Rowe, et al., 1980 | gas phase; From thermochemical cycle(Na+) 2H2O; Dzidic and Kebarle, 1970, Peterson, Mark, et al., 1984; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 106. | J/mol*K | HPMS | Peterson, Mark, et al., 1984 | gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M |
![]() | 107. | J/mol*K | FA | Perry, Rowe, et al., 1980 | gas phase; From thermochemical cycle(Na+) 2H2O; Dzidic and Kebarle, 1970, Peterson, Mark, et al., 1984; M |
By formula: (Na+ H3N) + H3N = (Na+
2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 93. ± 5. | kJ/mol | AVG | N/A | Average of 6 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 105. | J/mol*K | HPMS | Castleman, Holland, et al., 1978 | gas phase; M |
By formula: (Na+ C6H6) + C6H6 = (Na+
2C6H6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 81. ± 5. | kJ/mol | AVG | N/A | Average of 7 values; Individual data points |
By formula: (Na+ C2H6O) + C2H6O = (Na+
2C2H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 85. ± 7. | kJ/mol | AVG | N/A | Average of 7 values; Individual data points |
By formula: Na+ + C3H6O = (Na+ C3H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 131. ± 4.2 | kJ/mol | CIDT | Armentrout and Rodgers, 2000 | RCD |
![]() | 129. ± 2. | kJ/mol | HPMS | Hoyau, Norrman, et al., 1999 | See 96KLA/AND?; RCD |
![]() | 102. | kJ/mol | CIDT | Klassen, Anderson, et al., 1996 | RCD |
![]() | 140. ± 0.8 | kJ/mol | HPMS | Guo, Conklin, et al., 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 87900. | J/mol*K | HPMS | Hoyau, Norrman, et al., 1999 | See 96KLA/AND?; RCD |
![]() | 109. | J/mol*K | HPMS | Guo, Conklin, et al., 1989 | gas phase; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
101. | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: Na+ + CH4O = (Na+ CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 97.1 ± 5.4 | kJ/mol | CIDC | Amicangelo and Armentrout, 2001 | Anchor NH3=24.41; RCD |
![]() | 91.6 ± 5.9 | kJ/mol | CIDT | Armentrout and Rodgers, 2000 | RCD |
![]() | 100. ± 0.8 | kJ/mol | HPMS | Hoyau, Norrman, et al., 1999 | RCD |
![]() | 111. ± 0.8 | kJ/mol | HPMS | Guo, Conklin, et al., 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 85800. | J/mol*K | HPMS | Hoyau, Norrman, et al., 1999 | RCD |
![]() | 102. | J/mol*K | HPMS | Guo, Conklin, et al., 1989 | gas phase; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
72.4 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: Na+ + H3N = (Na+ H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 102. ± 5.4 | kJ/mol | CIDC | Amicangelo and Armentrout, 2001 | Anchor NH3=24.41; RCD |
![]() | 102. ± 5.4 | kJ/mol | CIDT | Armentrout and Rodgers, 2000 | RCD |
![]() | 107. ± 0.8 | kJ/mol | HPMS | Hoyau, Norrman, et al., 1999 | RCD |
![]() | 122. | kJ/mol | HPMS | Castleman, Holland, et al., 1978 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 91200. | J/mol*K | HPMS | Hoyau, Norrman, et al., 1999 | RCD |
![]() | 108. | J/mol*K | HPMS | Castleman, Holland, et al., 1978 | gas phase; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
77.8 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: Na+ + C6H6 = (Na+ C6H6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 95.4 ± 5.9 | kJ/mol | CIDC | Amicangelo and Armentrout, 2001 | Anchor NH3=24.41; RCD |
![]() | 88.3 ± 5.0 | kJ/mol | CIDT | Amicangelo and Armentrout, 2000 | RCD |
![]() | 88.3 ± 4.6 | kJ/mol | CIDT | Armentrout and Rodgers, 2000 | RCD |
![]() | 117. | kJ/mol | HPMS | Guo, Purnell, et al., 1990 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 131. | J/mol*K | HPMS | Guo, Purnell, et al., 1990 | gas phase; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
65.7 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: Na+ + C4H10O2 = (Na+ C4H10O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 158. ± 4.2 | kJ/mol | CIDT | Armentrout and Rodgers, 2000 | glyme; RCD |
![]() | 241. ± 18. | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
![]() | 161. ± 4.2 | kJ/mol | CIDT | More, Ray, et al., 1997 | RCD |
![]() | 197. | kJ/mol | HPMS | Castleman, Peterson, et al., 1983 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 145. | J/mol*K | HPMS | Castleman, Peterson, et al., 1983 | gas phase; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
133. | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: Na+ + C2H6O = (Na+ C2H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 100. ± 5.4 | kJ/mol | CIDC | Amicangelo and Armentrout, 2001 | Anchor NH3=24.41; RCD |
![]() | 91.6 ± 4.6 | kJ/mol | CIDT | Armentrout and Rodgers, 2000 | RCD |
![]() | 92.0 ± 5.0 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
![]() | 92.9 ± 5.0 | kJ/mol | CIDT | More, Ray, et al., 1997 | RCD |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
73.6 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
73.6 | 298. | CIDC | McMahon and Ohanessian, 2000 | RCD |
By formula: (Na+ 2H2O
CO2) + H2O = (Na+
3H2O
CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 51.9 | kJ/mol | HPMS | Peterson, Mark, et al., 1984 | gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | HPMS | Peterson, Mark, et al., 1984 | gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 23. | kJ/mol | HPMS | Peterson, Mark, et al., 1984 | gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M |
By formula: (Na+ CH4O) + CH4O = (Na+
2CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 85.8 ± 5.9 | kJ/mol | CIDC | Amicangelo and Armentrout, 2001 | Anchor NH3=24.41; RCD |
![]() | 89.5 ± 6.7 | kJ/mol | CIDC | Amicangelo and Armentrout, 2001 | Anchor NH3=24.41; RCD |
![]() | 85.8 ± 6.7 | kJ/mol | CIDC | Amicangelo and Armentrout, 2001 | Anchor NH3=24.41; RCD |
![]() | 84.5 ± 0.8 | kJ/mol | HPMS | Guo, Conklin, et al., 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 90.8 | J/mol*K | HPMS | Guo, Conklin, et al., 1989 | gas phase; M |
By formula: (Na+ 3H2O) + CO2 = (Na+
CO2
3H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 30. | kJ/mol | HPMS | Peterson, Mark, et al., 1984 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 100. | J/mol*K | N/A | Peterson, Mark, et al., 1984 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | -1. | kJ/mol | HPMS | Peterson, Mark, et al., 1984 | gas phase; Entropy change calculated or estimated; M |
By formula: (Na+ 3O2S) + O2S = (Na+
4O2S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 51.5 | kJ/mol | HPMS | Castleman, Peterson, et al., 1983 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 110. | J/mol*K | N/A | Castleman, Peterson, et al., 1983 | gas phase; Entropy change calculated or estimated; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
13. | 328. | HPMS | Castleman, Peterson, et al., 1983 | gas phase; Entropy change calculated or estimated; M |
By formula: (Na+ 3CO2) + CO2 = (Na+
4CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 35. | kJ/mol | HPMS | Peterson, Mark, et al., 1984 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 100. | J/mol*K | N/A | Peterson, Mark, et al., 1984 | gas phase; Entropy change calculated or estimated; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
3. | 310. | HPMS | Peterson, Mark, et al., 1984 | gas phase; Entropy change calculated or estimated; M |
By formula: Na+ + CO2 = (Na+ CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 66.5 | kJ/mol | HPMS | Peterson, Mark, et al., 1984 | gas phase; M |
![]() | 57.3 | kJ/mol | FA | Perry, Rowe, et al., 1980 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84.1 | J/mol*K | HPMS | Peterson, Mark, et al., 1984 | gas phase; M |
![]() | 82.8 | J/mol*K | FA | Perry, Rowe, et al., 1980 | gas phase; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
28. | 310. | DT | Keller and Beyer, 1971 | gas phase; low E/N; M |
By formula: Na+ + C2H6O = (Na+ C2H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 110. ± 5.4 | kJ/mol | CIDC | Amicangelo and Armentrout, 2001 | Anchor NH3=24.41; RCD |
![]() | 102. ± 4. | kJ/mol | CIDT | Armentrout and Rodgers, 2000 | RCD |
![]() | 102. ± 4. | kJ/mol | CIDT | Rodgers and Armentrout, 1999 | RCD |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
79.5 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
0.0 | 0. | CIDT | Rodgers and Armentrout, 1999 | RCD |
By formula: Na+ + CH5N = (Na+ CH5N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 110. ± 0.8 | kJ/mol | HPMS | Hoyau, Norrman, et al., 1999 | RCD |
![]() | 134. | kJ/mol | HPMS | Guo and Castleman, 1990 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 94600. | J/mol*K | HPMS | Hoyau, Norrman, et al., 1999 | RCD |
![]() | 127. | J/mol*K | HPMS | Guo and Castleman, 1990 | gas phase; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
81.6 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: Na+ + O2S = (Na+ O2S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 79.1 | kJ/mol | FA | Perry, Rowe, et al., 1980 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84.9 | J/mol*K | N/A | Perry, Rowe, et al., 1980 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 53.6 | kJ/mol | FA | Perry, Rowe, et al., 1980 | gas phase; Entropy change calculated or estimated; M |
By formula: Na+ + Kr = (Na+ Kr)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 20.3 | kJ/mol | SCATTERING | Gislason, 1984 | gas phase; M |
![]() | 21.3 | kJ/mol | IMob | Viehland, 1984 | gas phase; M |
![]() | 24. | kJ/mol | DT | McKnight and Sawina, 1973 | gas phase; M |
![]() | 27.5 | kJ/mol | IMob | Takebe, 1983 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 77.4 | J/mol*K | DT | McKnight and Sawina, 1973 | gas phase; M |
By formula: (Na+ C2H6O) + C2H6O = (Na+
2C2H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 99.2 ± 6.7 | kJ/mol | CIDC | Amicangelo and Armentrout, 2001 | Anchor NH3=24.41; RCD |
![]() | 96.7 ± 4.6 | kJ/mol | CIDC | Amicangelo and Armentrout, 2001 | Anchor NH3=24.41; RCD |
![]() | 99.2 ± 6.7 | kJ/mol | CIDC | Amicangelo and Armentrout, 2001 | Anchor NH3=24.41; RCD |
![]() | 97.5 ± 5.9 | kJ/mol | CIDC | Amicangelo and Armentrout, 2001 | Anchor NH3=24.41; RCD |
By formula: Na+ + Ar = (Na+ Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 15. ± 8.8 | kJ/mol | CIDT | Armentrout and Rodgers, 2000 | RCD |
![]() | 15.5 | kJ/mol | SCATTERING | Gislason, 1984 | gas phase; M |
![]() | 18.4 | kJ/mol | IMob | Viehland, 1984 | gas phase; M |
![]() | 18. | kJ/mol | DT | McKnight and Sawina, 1973 | gas phase; M |
![]() | 20.4 | kJ/mol | IMob | Takebe, 1983 | gas phase; M |
By formula: (Na+ 4C2H3N) + C2H3N = (Na+
5C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 53. ± 3. | kJ/mol | CIDT | Valina, 2001 | CH3CN is fifth ligand; RCD |
![]() | 53.1 | kJ/mol | HPMS | Davidson and Kebarle, 1976 | gas phase; Entropy change is questionable; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 172. | J/mol*K | HPMS | Davidson and Kebarle, 1976 | gas phase; Entropy change is questionable; M |
By formula: Na+ + N2 = (Na+ N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 33. | kJ/mol | FA | Perry, Rowe, et al., 1980 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 77.8 | J/mol*K | FA | Perry, Rowe, et al., 1980 | gas phase; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
9.2 | 310. | FA | Perry, Rowe, et al., 1980 | gas phase; M |
8.4 | 310. | DT | Beyer and Keller, 1971 | gas phase; low E/N; M |
By formula: (Na+ H2O
CO2) + H2O = (Na+
2H2O
CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 72.8 | kJ/mol | HPMS | Peterson, Mark, et al., 1984 | gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 98.7 | J/mol*K | HPMS | Peterson, Mark, et al., 1984 | gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M |
By formula: Na+ + C3H8O = (Na+ C3H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 113. ± 4.2 | kJ/mol | CIDT | Armentrout and Rodgers, 2000 | RCD |
![]() | 113. ± 4.6 | kJ/mol | CIDT | Rodgers and Armentrout, 1999 | RCD |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
85.4 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
0.0 | 0. | CIDT | Rodgers and Armentrout, 1999 | RCD |
By formula: (Na+ C4H10O2) + C4H10O2 = (Na+
2C4H10O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 116. ± 7.9 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
![]() | 114. ± 8.4 | kJ/mol | CIDT | More, Ray, et al., 1997 | RCD |
![]() | 147. | kJ/mol | HPMS | Castleman, Peterson, et al., 1983 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 169. | J/mol*K | HPMS | Castleman, Peterson, et al., 1983 | gas phase; M |
By formula: (Na+ CO) + CO = (Na+
2CO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 24. ± 3. | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
![]() | 24. ± 3. | kJ/mol | CIDT | Walter, Sievers, et al., 1998 | RCD |
![]() | 31. | kJ/mol | HPMS | Castleman, Peterson, et al., 1983 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 63.2 | J/mol*K | HPMS | Castleman, Peterson, et al., 1983 | gas phase; M |
By formula: Na+ + He = (Na+ He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 4.98 | kJ/mol | SCATTERING | Gislason, 1984 | gas phase; M |
![]() | 3.3 | kJ/mol | IMob | Viehland, 1984 | gas phase; M |
![]() | 3.9 | kJ/mol | IMob | Mason and Sharp, 1958 | gas phase; M |
![]() | 5.77 | kJ/mol | IMob | Takebe, 1983 | gas phase; M |
By formula: Na+ + CO = (Na+ CO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 32. ± 7.9 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
![]() | 32. ± 7.9 | kJ/mol | CIDT | Walter, Sievers, et al., 1998 | RCD |
![]() | 52.7 | kJ/mol | HPMS | Castleman, Peterson, et al., 1983 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 85.4 | J/mol*K | HPMS | Castleman, Peterson, et al., 1983 | gas phase; M |
By formula: Na+ + C12H24O6 = (Na+ C12H24O6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 296. ± 19. | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
![]() | 300. ± 19. | kJ/mol | CIDT | More, Ray, et al., 1999 | RCD |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
0.0 | 0. | CIDT | Rodgers and Armentrout, 2000 | RCD |
0.0 | 298. | CIDT | More, Ray, et al., 1999 | RCD |
By formula: (Na+ CO2) + CO2 = (Na+
2CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 46.0 | kJ/mol | HPMS | Peterson, Mark, et al., 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 90.8 | J/mol*K | HPMS | Peterson, Mark, et al., 1984 | gas phase; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
20. | 310. | DT | Keller and Beyer, 1971 | gas phase; low E/N; M |
By formula: Na+ + C4H10O = (Na+ C4H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 130. ± 1. | kJ/mol | HPMS | Guo, Conklin, et al., 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 118. | J/mol*K | HPMS | Guo, Conklin, et al., 1989 | gas phase; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
89.1 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: (Na+ H2) + H2 = (Na+
2H2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 10.1 | kJ/mol | SIDT | Bushnell, Kemper, et al., 1994 | gas phase; «DELTA»rH(0K) = 9.41 kJ/mol; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 51.9 | J/mol*K | SIDT | Bushnell, Kemper, et al., 1994 | gas phase; «DELTA»rH(0K) = 9.41 kJ/mol; M |
By formula: (Na+ N2) + N2 = (Na+
2N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 22. | kJ/mol | FA | Perry, Rowe, et al., 1980 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 70.3 | J/mol*K | FA | Perry, Rowe, et al., 1980 | gas phase; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
-1. | 310. | FA | Perry, Rowe, et al., 1980 | gas phase; M |
By formula: Na+ + H2 = (Na+ H2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 12.3 | kJ/mol | SIDT | Bushnell, Kemper, et al., 1994 | gas phase; «DELTA»rH(0K) = 10.3 kJ/mol; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 55.2 | J/mol*K | SIDT | Bushnell, Kemper, et al., 1994 | gas phase; «DELTA»rH(0K) = 10.3 kJ/mol; M |
By formula: Na+ + C6H6O = (Na+ C6H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 102. ± 3. | kJ/mol | CIDT | Amunugama and Rodgers, 2002 | RCD |
![]() | 98. ± 3. | kJ/mol | CIDT | Armentrout and Rodgers, 2000 | RCD |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
69.9 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: Na+ + C4H10O = (Na+ C4H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 117. ± 4.2 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
![]() | 116. ± 4.2 | kJ/mol | CIDT | Rodgers and Armentrout, 1999 | RCD |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
89.5 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: (Na+ 2C2H3N) + C2H3N = (Na+
3C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 89. ± 3. | kJ/mol | CIDT | Valina, 2001 | RCD |
![]() | 86.2 | kJ/mol | HPMS | Davidson and Kebarle, 1976 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 115. | J/mol*K | HPMS | Davidson and Kebarle, 1976 | gas phase; M |
By formula: (Na+ 3C2H3N) + C2H3N = (Na+
4C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 64. ± 3. | kJ/mol | CIDT | Valina, 2001 | RCD |
![]() | 62.3 | kJ/mol | HPMS | Davidson and Kebarle, 1976 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 117. | J/mol*K | HPMS | Davidson and Kebarle, 1976 | gas phase; M |
By formula: (Na+ C2H3N) + C2H3N = (Na+
2C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 109. ± 7.9 | kJ/mol | CIDT | Valina, 2001 | RCD |
![]() | 102. | kJ/mol | HPMS | Davidson and Kebarle, 1976 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 95.0 | J/mol*K | HPMS | Davidson and Kebarle, 1976 | gas phase; M |
By formula: Na+ + C2H5NO2 = (Na+ C2H5NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 161. ± 7.9 | kJ/mol | CIDC | Kish, Ohanessian, et al., 2003 | Anchor alanine=39.89; RCD |
![]() | 164. ± 5.9 | kJ/mol | CIDT | Moision and Armentrout, 2002 | RCD |
![]() | 153. | kJ/mol | CIDT | Klassen, Anderson, et al., 1996 | RCD |
By formula: Na+ + Xe = (Na+ Xe)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 25.0 | kJ/mol | SCATTERING | Gislason, 1984 | gas phase; M |
![]() | 24.9 | kJ/mol | IMob | Viehland, 1984 | gas phase; M |
![]() | 39.8 | kJ/mol | IMob | Takebe, 1983 | gas phase; M |
By formula: Na+ + C4H8N2O3 = (Na+ C4H8N2O3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 177. ± 7.1 | kJ/mol | CIDC | Cerda, Hoyau, et al., 1998 | See amide; RCD |
![]() | 179. | kJ/mol | CIDT | Klassen, Anderson, et al., 1996 | RCD |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
143. | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
By formula: Na+ + Ne = (Na+ Ne)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 7.36 | kJ/mol | SCATTERING | Gislason, 1984 | gas phase; M |
![]() | 6.36 | kJ/mol | IMob | Viehland, 1984 | gas phase; M |
![]() | 6.07 | kJ/mol | IMob | Takebe, 1983 | gas phase; M |
References
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chase, 1998
Chase, M.W., Jr.,
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Blades, A.T.; Klassen, J.S.; Kebarle, P.,
Determination of Ion-Solvent Equilibria in the Gas Phase. Hydration of Diprotonated Diamines and Bis(trimethylammonium) Alkanes,
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Dalleska, Tjelta, et al., 1994
Dalleska, N.F.; Tjelta, B.L.; Armentrout, P.B.,
Sequential Bond Energies of Water to Na+ (3s0), Mg+ (3s1), and Al+ (3s2),
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Klassen, Blades, et al., 1995
Klassen, J.S.; Blades, A.T.; Kebarle, P.,
Determinations of Ion-Molecule Equilibria Involving Ions Produced by Electrospray. Hydration of Protonated Amines, Diamines, and Some Small Peptides,
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Blades, Jayaweera, et al., 1990
Blades, A.T.; Jayaweera, P.; Ikonomou, M.G.; Kebarle, P.,
Studies of Alkaline - Earth and Transition - Metal M++ Gas - Phase Ion Chemistry,
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Dzidic and Kebarle, 1970
Dzidic, I.; Kebarle, P.,
Hydration of the Alkali Ions in the Gas Phase. Enthalpies and Entropies of Reactions M+(H2O)n-1 + H2O = M+(H2O)n,
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Tang, Lian, et al., 1976
Tang, I.N.; Lian, M.S.; Castleman, A.W.,
Mass Spectrometric Study of Gas - Phase Clustering Reactions: Hydration of the Monovalent Strontium Ion,
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Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation,
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Burdett and Hayhurst, 1982
Burdett, N.A.; Hayhurst, A.N.,
Hydration of gas phase ions and the measurement of boundary layer cooling during flame sampling into a mass spectrometer.,
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McMahon and Ohanessian, 2000
McMahon, T.B.; Ohanessian, G.,
An Experimental and Ab Initio Study of the Nature of the Binding in Gas-Phase Complexes of Sodium Ions,
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Tang and Castleman, 1972
Tang, I.N.; Castleman, A.W.,
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Peterson, Mark, et al., 1984
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Perry, Rowe, et al., 1980
Perry, R.A.; Rowe, B.R.; Viggiano, A.A.; Albritton, D.L.; Ferguson, E.E.; Fehsenfeld, F.C.,
Laboratory Measurements of Stratospheric Sodium Ion Measurements,
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Castleman, Holland, et al., 1978
Castleman, A.W.; Holland, P.M.; Lindsay, D.M.; Peterson, K.I.,
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Klassen, Anderson, et al., 1996
Klassen, J.S.; Anderson, S.G.; Blades, A.T.; Kebarle, P.,
Reaction Enthalpies for M+L = M+ + L, Where M+ = Na+ and K+ and L = Acetamide, N-Methylacetamide, N,N-Dimethylacetamide, Glycine, and Glycylglycine, from Determinations of the Collision-Induced Dissociation Thresholds,
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Guo, Conklin, et al., 1989
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Castleman, Peterson, et al., 1983
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Keller and Beyer, 1971
Keller, G.E.; Beyer, R.A.,
CO2 and O2 Clustering to Sodium Ions,
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The Association Reactions of Pb+ Ion with CH3OH and CH3NH2 in the Gas Phase,
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Gislason, 1984
Gislason, E.A.,
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Viehland, 1984
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Takebe, 1983
Takebe, M.,
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Davidson and Kebarle, 1976
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Beyer and Keller, 1971
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Mason and Sharp, 1958
Mason, E.A.; Sharp, H.W.,
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More, Ray, et al., 1999
More, M.B.; Ray, D.; Armentrout, P.B.,
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Bushnell, Kemper, et al., 1994
Bushnell, J.E.; Kemper, P.R.; Bowers, M.T.,
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Amunugama and Rodgers, 2002
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The influence of substituents on cation-pi interactions. 4. Absolute binding energies of alkali metal cation - Phenol complexes determined by threshold collision-induced dissociation and theoretical studies,
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Kish, Ohanessian, et al., 2003
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Moision and Armentrout, 2002
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Experimental and Theoretical Dissection of Sodium Cation/Glycine Interactions,
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Cerda, Hoyau, et al., 1998
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PAs of Peptides,
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Feng, Gronert, et al., 1999
Feng, W.Y.; Gronert, S.; Lebrilla, C.B.,
Lithium and sodium ion binding energies of N-acetyl and N-glycyl amino acids,
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Notes
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References
- Symbols used in this document:
S°gas,1 bar Entropy of gas at standard conditions (1 bar) T Temperature rG°
Free energy of reaction at standard conditions rH°
Enthalpy of reaction at standard conditions rS°
Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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