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Lithium ion (1+)


Gas phase thermochemistry data

Go To: Top, Reaction thermochemistry data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
gas,1 bar133.02J/mol*KReviewChase, 1998Data last reviewed in December, 1983

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RCD - Robert C. Dunbar
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 1 to 50

Lithium ion (1+) + Dimethyl ether = (Lithium ion (1+) bullet Dimethyl ether)

By formula: Li+ + C2H6O = (Li+ bullet C2H6O)

Quantity Value Units Method Reference Comment
Deltar165. ± 11.kJ/molCIDTRodgers and Armentrout, 2000RCD
Deltar165.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Deltar160.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Deltar131.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
165. (+10.,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

Lithium ion (1+) + Argon = (Lithium ion (1+) bullet Argon)

By formula: Li+ + Ar = (Li+ bullet Ar)

Quantity Value Units Method Reference Comment
Deltar30. ± 4.kJ/molAVGN/AAverage of 4 out of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Deltar30.J/mol*KDTMcKnight and Sawina, 1973gas phase; «DELTA»rS approximate; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
5.9294.IMobCassidy and Elford, 1985gas phase; M
7.9319.DTKeller, Beyer, et al., 1973gas phase; LOW E/N; M
11.215.DTMcKnight and Sawina, 1973gas phase; «DELTA»rS approximate; M

Lithium ion (1+) + Benzene = (Lithium ion (1+) bullet Benzene)

By formula: Li+ + C6H6 = (Li+ bullet C6H6)

Quantity Value Units Method Reference Comment
Deltar161. ± 13.kJ/molCIDTAmicangelo and Armentrout, 2000RCD
Deltar159.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Deltar153.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Deltar115.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Deltar124.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Methyl Alcohol = (Lithium ion (1+) bullet Methyl Alcohol)

By formula: Li+ + CH4O = (Li+ bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar154. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD
Deltar159.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Deltar160.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
Deltar127.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Ammonia = (Lithium ion (1+) bullet Ammonia)

By formula: Li+ + H3N = (Li+ bullet H3N)

Quantity Value Units Method Reference Comment
Deltar164.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Deltar161.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Deltar96.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
Deltar134.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Formaldehyde = (Lithium ion (1+) bullet Formaldehyde)

By formula: Li+ + CH2O = (Li+ bullet CH2O)

Quantity Value Units Method Reference Comment
Deltar151.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Deltar150.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
Deltar118.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Hydrogen cyanide = (Lithium ion (1+) bullet Hydrogen cyanide)

By formula: Li+ + CHN = (Li+ bullet CHN)

Quantity Value Units Method Reference Comment
Deltar152.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Deltar150.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
Deltar120.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Methylamine, N,N-dimethyl- = (Lithium ion (1+) bullet Methylamine, N,N-dimethyl-)

By formula: Li+ + C3H9N = (Li+ bullet C3H9N)

Quantity Value Units Method Reference Comment
Deltar176.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Deltar170.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970; M
Quantity Value Units Method Reference Comment
Deltar120.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Deltar140.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M

(Lithium ion (1+) bullet 3Water) + Water = (Lithium ion (1+) bullet 4Water)

By formula: (Li+ bullet 3H2O) + H2O = (Li+ bullet 4H2O)

Quantity Value Units Method Reference Comment
Deltar69.9 ± 5.0kJ/molCIDTRodgers and Armentrout, 2000RCD
Deltar68.6kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Deltar60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar125.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
Deltar96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
33.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

(Lithium ion (1+) bullet 4Water) + Water = (Lithium ion (1+) bullet 5Water)

By formula: (Li+ bullet 4H2O) + H2O = (Li+ bullet 5H2O)

Quantity Value Units Method Reference Comment
Deltar56.9 ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD
Deltar58.2kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Deltar50. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar131.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
Deltar96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
23.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

Lithium ion (1+) + Dimethylamine = (Lithium ion (1+) bullet Dimethylamine)

By formula: Li+ + C2H7N = (Li+ bullet C2H7N)

Quantity Value Units Method Reference Comment
Deltar177.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Deltar143.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Methylamine = (Lithium ion (1+) bullet Methylamine)

By formula: Li+ + CH5N = (Li+ bullet CH5N)

Quantity Value Units Method Reference Comment
Deltar172.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
Deltar139.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

(Lithium ion (1+) bullet 2Water) + Water = (Lithium ion (1+) bullet 3Water)

By formula: (Li+ bullet 2H2O) + H2O = (Li+ bullet 3H2O)

Quantity Value Units Method Reference Comment
Deltar94.1 ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD
Deltar70. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray; M
Deltar86.6kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
Deltar96.J/mol*KHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray; M
Deltar104.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
41.8300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray; M

Lithium ion (1+) + helium = (Lithium ion (1+) bullet helium)

By formula: Li+ + He = (Li+ bullet He)

Quantity Value Units Method Reference Comment
Deltar7.15kJ/molIMobGatland, 1984gas phase; M
Deltar6.86kJ/molSCATTERINGGislason, 1984gas phase; M
Deltar7.07kJ/molIMobViehland, 1984gas phase; M
Deltar4.56kJ/molIMobMason and Sharp, 1958gas phase; M
Deltar13.2kJ/molIMobTakebe, 1983gas phase; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
-15.309.DTColonna-Romano and Keller, 1976gas phase; low E/N; M

Lithium ion (1+) + Water = (Lithium ion (1+) bullet Water)

By formula: Li+ + H2O = (Li+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar135. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD
Deltar140.kJ/molHPMSDzidic and Kebarle, 1970gas phase; interpolated; M
Quantity Value Units Method Reference Comment
Deltar96.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; interpolated; M

(Lithium ion (1+) bullet 5Water) + Water = (Lithium ion (1+) bullet 6Water)

By formula: (Li+ bullet 5H2O) + H2O = (Li+ bullet 6H2O)

Quantity Value Units Method Reference Comment
Deltar59.8 ± 5.0kJ/molCIDTRodgers and Armentrout, 2000RCD
Deltar50.6kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
Deltar134.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

(Lithium ion (1+) bullet Water) + Water = (Lithium ion (1+) bullet 2Water)

By formula: (Li+ bullet H2O) + H2O = (Li+ bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar113. ± 10.kJ/molCIDTRodgers and Armentrout, 2000RCD
Deltar108.kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
Deltar88.3J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

Lithium ion (1+) + Pyridine = (Lithium ion (1+) bullet Pyridine)

By formula: Li+ + C5H5N = (Li+ bullet C5H5N)

Quantity Value Units Method Reference Comment
Deltar181. ± 15.kJ/molCIDTAmunugama and Rodgers, 2000RCD
Deltar180.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + neon = (Lithium ion (1+) bullet neon)

By formula: Li+ + Ne = (Li+ bullet Ne)

Quantity Value Units Method Reference Comment
Deltar11.0kJ/molSCATTERINGGislason, 1984gas phase; M
Deltar11.9kJ/molIMobViehland, 1984gas phase; M
Deltar14.0kJ/molIMobTakebe, 1983gas phase; M

Lithium ion (1+) + Xenon = (Lithium ion (1+) bullet Xenon)

By formula: Li+ + Xe = (Li+ bullet Xe)

Quantity Value Units Method Reference Comment
Deltar51.5kJ/molSCATTERINGGislason, 1984gas phase; M
Deltar52.7kJ/molIMobViehland, 1984gas phase; M
Deltar87.0kJ/molIMobTakebe, 1983gas phase; M

Lithium ion (1+) + Krypton = (Lithium ion (1+) bullet Krypton)

By formula: Li+ + Kr = (Li+ bullet Kr)

Quantity Value Units Method Reference Comment
Deltar44.4kJ/molSCATTERINGGislason, 1984gas phase; M
Deltar38.kJ/molIMobViehland, 1984gas phase; M
Deltar68.6kJ/molIMobTakebe, 1983gas phase; M

(Lithium ion (1+) bullet 2Dimethyl ether) + Dimethyl ether = (Lithium ion (1+) bullet 3Dimethyl ether)

By formula: (Li+ bullet 2C2H6O) + C2H6O = (Li+ bullet 3C2H6O)

Quantity Value Units Method Reference Comment
Deltar89.1 ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
110. (+5.9,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

(Lithium ion (1+) bullet 3Dimethyl ether) + Dimethyl ether = (Lithium ion (1+) bullet 4Dimethyl ether)

By formula: (Li+ bullet 3C2H6O) + C2H6O = (Li+ bullet 4C2H6O)

Quantity Value Units Method Reference Comment
Deltar68. ± 10.kJ/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
95.4 (+6.7,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

(Lithium ion (1+) bullet Dimethyl ether) + Dimethyl ether = (Lithium ion (1+) bullet 2Dimethyl ether)

By formula: (Li+ bullet C2H6O) + C2H6O = (Li+ bullet 2C2H6O)

Quantity Value Units Method Reference Comment
Deltar121. ± 5.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
130. (+4.,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

Lithium ion (1+) + Acetaldehyde = (Lithium ion (1+) bullet Acetaldehyde)

By formula: Li+ + C2H4O = (Li+ bullet C2H4O)

Quantity Value Units Method Reference Comment
Deltar173.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, Keesee and Castleman, 1986 from Berman and Beauchamp, 1986; Dzidic and Kebarle, 1970 interpolated; M

(Lithium ion (1+) bullet 2Ammonia) + Ammonia = (Lithium ion (1+) bullet 3Ammonia)

By formula: (Li+ bullet 2H3N) + H3N = (Li+ bullet 3H3N)

Quantity Value Units Method Reference Comment
Deltar87.9kJ/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
Deltar106.J/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

(Lithium ion (1+) bullet 3Ammonia) + Ammonia = (Lithium ion (1+) bullet 4Ammonia)

By formula: (Li+ bullet 3H3N) + H3N = (Li+ bullet 4H3N)

Quantity Value Units Method Reference Comment
Deltar69.0kJ/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
Deltar136.J/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

(Lithium ion (1+) bullet 4Ammonia) + Ammonia = (Lithium ion (1+) bullet 5Ammonia)

By formula: (Li+ bullet 4H3N) + H3N = (Li+ bullet 5H3N)

Quantity Value Units Method Reference Comment
Deltar46.4kJ/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
Deltar117.J/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

(Lithium ion (1+) bullet 5Ammonia) + Ammonia = (Lithium ion (1+) bullet 6Ammonia)

By formula: (Li+ bullet 5H3N) + H3N = (Li+ bullet 6H3N)

Quantity Value Units Method Reference Comment
Deltar39.kJ/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
Deltar106.J/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

(Lithium ion (1+) bullet Ammonia) + Ammonia = (Lithium ion (1+) bullet 2Ammonia)

By formula: (Li+ bullet H3N) + H3N = (Li+ bullet 2H3N)

Quantity Value Units Method Reference Comment
Deltar138.kJ/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
Deltar124.J/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

Lithium ion (1+) + Propane, 2-fluoro- = (Lithium ion (1+) bullet Propane, 2-fluoro-)

By formula: Li+ + C3H7F = (Li+ bullet C3H7F)

Quantity Value Units Method Reference Comment
Deltar149.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Cyclohexane = (Lithium ion (1+) bullet Cyclohexane)

By formula: Li+ + C6H12 = (Li+ bullet C6H12)

Quantity Value Units Method Reference Comment
Deltar100.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Propene = (Lithium ion (1+) bullet Propene)

By formula: Li+ + C3H6 = (Li+ bullet C3H6)

Quantity Value Units Method Reference Comment
Deltar96.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + 1-Propene, 2-methyl- = (Lithium ion (1+) bullet 1-Propene, 2-methyl-)

By formula: Li+ + C4H8 = (Li+ bullet C4H8)

Quantity Value Units Method Reference Comment
Deltar120.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Ethane, fluoro- = (Lithium ion (1+) bullet Ethane, fluoro-)

By formula: Li+ + C2H5F = (Li+ bullet C2H5F)

Quantity Value Units Method Reference Comment
Deltar140.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Methyl fluoride = (Lithium ion (1+) bullet Methyl fluoride)

By formula: Li+ + CH3F = (Li+ bullet CH3F)

Quantity Value Units Method Reference Comment
Deltar130.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Acetic acid = (Lithium ion (1+) bullet Acetic acid)

By formula: Li+ + C2H4O2 = (Li+ bullet C2H4O2)

Quantity Value Units Method Reference Comment
Deltar174.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Acetone = (Lithium ion (1+) bullet Acetone)

By formula: Li+ + C3H6O = (Li+ bullet C3H6O)

Quantity Value Units Method Reference Comment
Deltar186.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Propyne = (Lithium ion (1+) bullet Propyne)

By formula: Li+ + C3H4 = (Li+ bullet C3H4)

Quantity Value Units Method Reference Comment
Deltar119.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Difluoromethane = (Lithium ion (1+) bullet Difluoromethane)

By formula: Li+ + CH2F2 = (Li+ bullet CH2F2)

Quantity Value Units Method Reference Comment
Deltar111.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Dimethyl sulfide = (Lithium ion (1+) bullet Dimethyl sulfide)

By formula: Li+ + C2H6S = (Li+ bullet C2H6S)

Quantity Value Units Method Reference Comment
Deltar137.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Propane, 2-bromo- = (Lithium ion (1+) bullet Propane, 2-bromo-)

By formula: Li+ + C3H7Br = (Li+ bullet C3H7Br)

Quantity Value Units Method Reference Comment
Deltar128.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Propane, 2-iodo- = (Lithium ion (1+) bullet Propane, 2-iodo-)

By formula: Li+ + C3H7I = (Li+ bullet C3H7I)

Quantity Value Units Method Reference Comment
Deltar123.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Formamide, N,N-dimethyl- = (Lithium ion (1+) bullet Formamide, N,N-dimethyl-)

By formula: Li+ + C3H7NO = (Li+ bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar210.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Chloromethane = (Lithium ion (1+) bullet Chloromethane)

By formula: Li+ + CH3Cl = (Li+ bullet CH3Cl)

Quantity Value Units Method Reference Comment
Deltar100.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Acetonitrile = (Lithium ion (1+) bullet Acetonitrile)

By formula: Li+ + C2H3N = (Li+ bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar180.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Methylene chloride = (Lithium ion (1+) bullet Methylene chloride)

By formula: Li+ + CH2Cl2 = (Li+ bullet CH2Cl2)

Quantity Value Units Method Reference Comment
Deltar120.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Propane, 2-chloro- = (Lithium ion (1+) bullet Propane, 2-chloro-)

By formula: Li+ + C3H7Cl = (Li+ bullet C3H7Cl)

Quantity Value Units Method Reference Comment
Deltar130.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Acetic acid, methyl ester = (Lithium ion (1+) bullet Acetic acid, methyl ester)

By formula: Li+ + C3H6O2 = (Li+ bullet C3H6O2)

Quantity Value Units Method Reference Comment
Deltar180.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Methane, nitro- = (Lithium ion (1+) bullet Methane, nitro-)

By formula: Li+ + CH3NO2 = (Li+ bullet CH3NO2)

Quantity Value Units Method Reference Comment
Deltar165.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970; M

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RCD - Robert C. Dunbar
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Lithium ion (1+) + Argon = (Lithium ion (1+) bullet Argon)

By formula: Li+ + Ar = (Li+ bullet Ar)

Quantity Value Units Method Reference Comment
Deltar30. ± 4.kJ/molAVGN/AAverage of 4 out of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Deltar30.J/mol*KDTMcKnight and Sawina, 1973gas phase; «DELTA»rS approximate; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
5.9294.IMobCassidy and Elford, 1985gas phase; M
7.9319.DTKeller, Beyer, et al., 1973gas phase; LOW E/N; M
11.215.DTMcKnight and Sawina, 1973gas phase; «DELTA»rS approximate; M

Lithium ion (1+) + Hydrogen cyanide = (Lithium ion (1+) bullet Hydrogen cyanide)

By formula: Li+ + CHN = (Li+ bullet CHN)

Quantity Value Units Method Reference Comment
Deltar152.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Deltar150.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
Deltar120.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Methylene chloride = (Lithium ion (1+) bullet Methylene chloride)

By formula: Li+ + CH2Cl2 = (Li+ bullet CH2Cl2)

Quantity Value Units Method Reference Comment
Deltar120.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Difluoromethane = (Lithium ion (1+) bullet Difluoromethane)

By formula: Li+ + CH2F2 = (Li+ bullet CH2F2)

Quantity Value Units Method Reference Comment
Deltar111.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + 2H-Tetrazole = (Lithium ion (1+) bullet 2H-Tetrazole)

By formula: Li+ + CH2N4 = (Li+ bullet CH2N4)

Quantity Value Units Method Reference Comment
Deltar151. ± 7.1kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + Formaldehyde = (Lithium ion (1+) bullet Formaldehyde)

By formula: Li+ + CH2O = (Li+ bullet CH2O)

Quantity Value Units Method Reference Comment
Deltar151.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Deltar150.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
Deltar118.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Chloromethane = (Lithium ion (1+) bullet Chloromethane)

By formula: Li+ + CH3Cl = (Li+ bullet CH3Cl)

Quantity Value Units Method Reference Comment
Deltar100.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Methyl fluoride = (Lithium ion (1+) bullet Methyl fluoride)

By formula: Li+ + CH3F = (Li+ bullet CH3F)

Quantity Value Units Method Reference Comment
Deltar130.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Formamide = (Lithium ion (1+) bullet Formamide)

By formula: Li+ + CH3NO = (Li+ bullet CH3NO)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
157.373.CIDCHerreros, Gal, et al., 1999RCD

Lithium ion (1+) + Methane, nitro- = (Lithium ion (1+) bullet Methane, nitro-)

By formula: Li+ + CH3NO2 = (Li+ bullet CH3NO2)

Quantity Value Units Method Reference Comment
Deltar165.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970; M

Lithium ion (1+) + Methyl Alcohol = (Lithium ion (1+) bullet Methyl Alcohol)

By formula: Li+ + CH4O = (Li+ bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar154. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD
Deltar159.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Deltar160.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
Deltar127.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Methylamine = (Lithium ion (1+) bullet Methylamine)

By formula: Li+ + CH5N = (Li+ bullet CH5N)

Quantity Value Units Method Reference Comment
Deltar172.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
Deltar139.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Carbon monoxide = (Lithium ion (1+) bullet Carbon monoxide)

By formula: Li+ + CO = (Li+ bullet CO)

Quantity Value Units Method Reference Comment
Deltar55. ± 13.kJ/molCIDTRodgers and Armentrout, 2000RCD
Deltar55. ± 12.kJ/molCIDTWalter, Sievers, et al., 1998RCD

(Lithium ion (1+) bullet Carbon monoxide) + Carbon monoxide = (Lithium ion (1+) bullet 2Carbon monoxide)

By formula: (Li+ bullet CO) + CO = (Li+ bullet 2CO)

Quantity Value Units Method Reference Comment
Deltar36. ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD
Deltar36. ± 4.2kJ/molCIDTWalter, Sievers, et al., 1998RCD

(Lithium ion (1+) bullet 2Carbon monoxide) + Carbon monoxide = (Lithium ion (1+) bullet 3Carbon monoxide)

By formula: (Li+ bullet 2CO) + CO = (Li+ bullet 3CO)

Quantity Value Units Method Reference Comment
Deltar35. ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD
Deltar35. ± 4.2kJ/molCIDTWalter, Sievers, et al., 1998RCD

Lithium ion (1+) + Acetonitrile = (Lithium ion (1+) bullet Acetonitrile)

By formula: Li+ + C2H3N = (Li+ bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar180.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + C2H3N3 = (Lithium ion (1+) bullet C2H3N3)

By formula: Li+ + C2H3N3 = (Li+ bullet C2H3N3)

Quantity Value Units Method Reference Comment
Deltar136. ± 7.1kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + 1H-1,2,4-Triazole = (Lithium ion (1+) bullet 1H-1,2,4-Triazole)

By formula: Li+ + C2H3N3 = (Li+ bullet C2H3N3)

Quantity Value Units Method Reference Comment
Deltar191. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + Acetaldehyde = (Lithium ion (1+) bullet Acetaldehyde)

By formula: Li+ + C2H4O = (Li+ bullet C2H4O)

Quantity Value Units Method Reference Comment
Deltar173.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, Keesee and Castleman, 1986 from Berman and Beauchamp, 1986; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Acetic acid = (Lithium ion (1+) bullet Acetic acid)

By formula: Li+ + C2H4O2 = (Li+ bullet C2H4O2)

Quantity Value Units Method Reference Comment
Deltar174.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + 1,3,2-Dioxathiolane, 2-oxide = (Lithium ion (1+) bullet 1,3,2-Dioxathiolane, 2-oxide)

By formula: Li+ + C2H4O3S = (Li+ bullet C2H4O3S)

Quantity Value Units Method Reference Comment
Deltar199.kJ/molCIDCBuncel, Decouzon, et al., 1997RCD

Lithium ion (1+) + Ethane, fluoro- = (Lithium ion (1+) bullet Ethane, fluoro-)

By formula: Li+ + C2H5F = (Li+ bullet C2H5F)

Quantity Value Units Method Reference Comment
Deltar140.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Formamide, N-methyl- = (Lithium ion (1+) bullet Formamide, N-methyl-)

By formula: Li+ + C2H5NO = (Li+ bullet C2H5NO)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
166.373.CIDCHerreros, Gal, et al., 1999RCD

Lithium ion (1+) + Ethanol = (Lithium ion (1+) bullet Ethanol)

By formula: Li+ + C2H6O = (Li+ bullet C2H6O)

Quantity Value Units Method Reference Comment
Deltar164. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + Dimethyl ether = (Lithium ion (1+) bullet Dimethyl ether)

By formula: Li+ + C2H6O = (Li+ bullet C2H6O)

Quantity Value Units Method Reference Comment
Deltar165. ± 11.kJ/molCIDTRodgers and Armentrout, 2000RCD
Deltar165.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Deltar160.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Deltar131.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
165. (+10.,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

(Lithium ion (1+) bullet Dimethyl ether) + Dimethyl ether = (Lithium ion (1+) bullet 2Dimethyl ether)

By formula: (Li+ bullet C2H6O) + C2H6O = (Li+ bullet 2C2H6O)

Quantity Value Units Method Reference Comment
Deltar121. ± 5.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
130. (+4.,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

(Lithium ion (1+) bullet 2Dimethyl ether) + Dimethyl ether = (Lithium ion (1+) bullet 3Dimethyl ether)

By formula: (Li+ bullet 2C2H6O) + C2H6O = (Li+ bullet 3C2H6O)

Quantity Value Units Method Reference Comment
Deltar89.1 ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
110. (+5.9,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

(Lithium ion (1+) bullet 3Dimethyl ether) + Dimethyl ether = (Lithium ion (1+) bullet 4Dimethyl ether)

By formula: (Li+ bullet 3C2H6O) + C2H6O = (Li+ bullet 4C2H6O)

Quantity Value Units Method Reference Comment
Deltar68. ± 10.kJ/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
95.4 (+6.7,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

Lithium ion (1+) + Dimethyl sulfone = (Lithium ion (1+) bullet Dimethyl sulfone)

By formula: Li+ + C2H6O2S = (Li+ bullet C2H6O2S)

Quantity Value Units Method Reference Comment
Deltar203.kJ/molCIDCBuncel, Decouzon, et al., 1997RCD

Lithium ion (1+) + Dimethyl sulfide = (Lithium ion (1+) bullet Dimethyl sulfide)

By formula: Li+ + C2H6S = (Li+ bullet C2H6S)

Quantity Value Units Method Reference Comment
Deltar137.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Dimethylamine = (Lithium ion (1+) bullet Dimethylamine)

By formula: Li+ + C2H7N = (Li+ bullet C2H7N)

Quantity Value Units Method Reference Comment
Deltar177.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Deltar143.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + 1,3,5-Triazine = (Lithium ion (1+) bullet 1,3,5-Triazine)

By formula: Li+ + C3H3N3 = (Li+ bullet C3H3N3)

Quantity Value Units Method Reference Comment
Deltar127. ± 13.kJ/molCIDTAmunugama and Rodgers, 2000RCD

Lithium ion (1+) + 1H-Pyrazole = (Lithium ion (1+) bullet 1H-Pyrazole)

By formula: Li+ + C3H4N2 = (Li+ bullet C3H4N2)

Quantity Value Units Method Reference Comment
Deltar187. ± 17.kJ/molCIDTHuang and Rodgers, 2002RCD

Lithium ion (1+) + 1H-Imidazole = (Lithium ion (1+) bullet 1H-Imidazole)

By formula: Li+ + C3H4N2 = (Li+ bullet C3H4N2)

Quantity Value Units Method Reference Comment
Deltar211. ± 9.6kJ/molCIDTHuang and Rodgers, 2002RCD

Lithium ion (1+) + Propyne = (Lithium ion (1+) bullet Propyne)

By formula: Li+ + C3H4 = (Li+ bullet C3H4)

Quantity Value Units Method Reference Comment
Deltar119.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Acetone = (Lithium ion (1+) bullet Acetone)

By formula: Li+ + C3H6O = (Li+ bullet C3H6O)

Quantity Value Units Method Reference Comment
Deltar186.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Acetic acid, methyl ester = (Lithium ion (1+) bullet Acetic acid, methyl ester)

By formula: Li+ + C3H6O2 = (Li+ bullet C3H6O2)

Quantity Value Units Method Reference Comment
Deltar180.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Propene = (Lithium ion (1+) bullet Propene)

By formula: Li+ + C3H6 = (Li+ bullet C3H6)

Quantity Value Units Method Reference Comment
Deltar96.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Propane, 2-bromo- = (Lithium ion (1+) bullet Propane, 2-bromo-)

By formula: Li+ + C3H7Br = (Li+ bullet C3H7Br)

Quantity Value Units Method Reference Comment
Deltar128.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Propane, 2-chloro- = (Lithium ion (1+) bullet Propane, 2-chloro-)

By formula: Li+ + C3H7Cl = (Li+ bullet C3H7Cl)

Quantity Value Units Method Reference Comment
Deltar130.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Propane, 2-fluoro- = (Lithium ion (1+) bullet Propane, 2-fluoro-)

By formula: Li+ + C3H7F = (Li+ bullet C3H7F)

Quantity Value Units Method Reference Comment
Deltar149.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Propane, 2-iodo- = (Lithium ion (1+) bullet Propane, 2-iodo-)

By formula: Li+ + C3H7I = (Li+ bullet C3H7I)

Quantity Value Units Method Reference Comment
Deltar123.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Formamide, N,N-dimethyl- = (Lithium ion (1+) bullet Formamide, N,N-dimethyl-)

By formula: Li+ + C3H7NO = (Li+ bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar210.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Acetamide, N-methyl- = (Lithium ion (1+) bullet Acetamide, N-methyl-)

By formula: Li+ + C3H7NO = (Li+ bullet C3H7NO)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
173.373.CIDT,ICRHerreros, Gal, et al., 1999RCD

Lithium ion (1+) + Isopropyl Alcohol = (Lithium ion (1+) bullet Isopropyl Alcohol)

By formula: Li+ + C3H8O = (Li+ bullet C3H8O)

Quantity Value Units Method Reference Comment
Deltar173. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + 1-Propanol = (Lithium ion (1+) bullet 1-Propanol)

By formula: Li+ + C3H8O = (Li+ bullet C3H8O)

Quantity Value Units Method Reference Comment
Deltar171. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + Methylamine, N,N-dimethyl- = (Lithium ion (1+) bullet Methylamine, N,N-dimethyl-)

By formula: Li+ + C3H9N = (Li+ bullet C3H9N)

Quantity Value Units Method Reference Comment
Deltar176.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Deltar170.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970; M
Quantity Value Units Method Reference Comment
Deltar120.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Deltar140.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Pyrazine = (Lithium ion (1+) bullet Pyrazine)

By formula: Li+ + C4H4N2 = (Li+ bullet C4H4N2)

Quantity Value Units Method Reference Comment
Deltar149. ± 14.kJ/molCIDTAmunugama and Rodgers, 2000RCD

Lithium ion (1+) + Pyrrole = (Lithium ion (1+) bullet Pyrrole)

By formula: Li+ + C4H5N = (Li+ bullet C4H5N)

Quantity Value Units Method Reference Comment
Deltar177. ± 17.kJ/molCIDTHuang and Rodgers, 2002RCD

Lithium ion (1+) + 1H-Imidazole, 1-methyl- = (Lithium ion (1+) bullet 1H-Imidazole, 1-methyl-)

By formula: Li+ + C4H6N2 = (Li+ bullet C4H6N2)

Quantity Value Units Method Reference Comment
Deltar242. ± 21.kJ/molCIDTHuang and Rodgers, 2002RCD

Lithium ion (1+) + 1H-Pyrazole, 1-methyl- = (Lithium ion (1+) bullet 1H-Pyrazole, 1-methyl-)

By formula: Li+ + C4H6N2 = (Li+ bullet C4H6N2)

Quantity Value Units Method Reference Comment
Deltar207. ± 19.kJ/molCIDTHuang and Rodgers, 2002RCD

Lithium ion (1+) + 1-Propene, 2-methyl- = (Lithium ion (1+) bullet 1-Propene, 2-methyl-)

By formula: Li+ + C4H8 = (Li+ bullet C4H8)

Quantity Value Units Method Reference Comment
Deltar120.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + 1-Butanol = (Lithium ion (1+) bullet 1-Butanol)

By formula: Li+ + C4H10O = (Li+ bullet C4H10O)

Quantity Value Units Method Reference Comment
Deltar178. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + 2-Propanol, 2-methyl- = (Lithium ion (1+) bullet 2-Propanol, 2-methyl-)

By formula: Li+ + C4H10O = (Li+ bullet C4H10O)

Quantity Value Units Method Reference Comment
Deltar178. ± 10.kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + 1-Propanol, 2-methyl- = (Lithium ion (1+) bullet 1-Propanol, 2-methyl-)

By formula: Li+ + C4H10O = (Li+ bullet C4H10O)

Quantity Value Units Method Reference Comment
Deltar169. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + 2-Butanol = (Lithium ion (1+) bullet 2-Butanol)

By formula: Li+ + C4H10O = (Li+ bullet C4H10O)

Quantity Value Units Method Reference Comment
Deltar174. ± 9.2kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + Ethane, 1,2-dimethoxy- = (Lithium ion (1+) bullet Ethane, 1,2-dimethoxy-)

By formula: Li+ + C4H10O2 = (Li+ bullet C4H10O2)

Quantity Value Units Method Reference Comment
Deltar158. ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD

(Lithium ion (1+) bullet Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (Lithium ion (1+) bullet 2Ethane, 1,2-dimethoxy-)

By formula: (Li+ bullet C4H10O2) + C4H10O2 = (Li+ bullet 2C4H10O2)

Quantity Value Units Method Reference Comment
Deltar139. ± 12.kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + Pyridine = (Lithium ion (1+) bullet Pyridine)

By formula: Li+ + C5H5N = (Li+ bullet C5H5N)

Quantity Value Units Method Reference Comment
Deltar181. ± 15.kJ/molCIDTAmunugama and Rodgers, 2000RCD
Deltar180.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + 3-Aminopyridine = (Lithium ion (1+) bullet 3-Aminopyridine)

By formula: Li+ + C5H6N2 = (Li+ bullet C5H6N2)

Quantity Value Units Method Reference Comment
Deltar202. ± 10.kJ/molCIDTRodgers, 2001RCD

Lithium ion (1+) + 4-Aminopyridine = (Lithium ion (1+) bullet 4-Aminopyridine)

By formula: Li+ + C5H6N2 = (Li+ bullet C5H6N2)

Quantity Value Units Method Reference Comment
Deltar217. ± 21.kJ/molCIDTRodgers, 2001RCD

Lithium ion (1+) + 2-Aminopyridine = (Lithium ion (1+) bullet 2-Aminopyridine)

By formula: Li+ + C5H6N2 = (Li+ bullet C5H6N2)

Quantity Value Units Method Reference Comment
Deltar238. ± 21.kJ/molCIDTRodgers, 2001RCD

Lithium ion (1+) + 1H-Pyrrole, 1-methyl- = (Lithium ion (1+) bullet 1H-Pyrrole, 1-methyl-)

By formula: Li+ + C5H7N = (Li+ bullet C5H7N)

Quantity Value Units Method Reference Comment
Deltar186. ± 17.kJ/molCIDTHuang and Rodgers, 2002RCD

Lithium ion (1+) + Benzene, fluoro- = (Lithium ion (1+) bullet Benzene, fluoro-)

By formula: Li+ + C6H5F = (Li+ bullet C6H5F)

Quantity Value Units Method Reference Comment
Deltar147. ± 21.kJ/molCIDTAmunugama and Rodgers, 2002RCD

(Lithium ion (1+) bullet Benzene, fluoro-) + Benzene, fluoro- = (Lithium ion (1+) bullet 2Benzene, fluoro-)

By formula: (Li+ bullet C6H5F) + C6H5F = (Li+ bullet 2C6H5F)

Quantity Value Units Method Reference Comment
Deltar95. ± 3.kJ/molCIDTAmunugama and Rodgers, 2002RCD

Lithium ion (1+) + Phenol = (Lithium ion (1+) bullet Phenol)

By formula: Li+ + C6H6O = (Li+ bullet C6H6O)

Quantity Value Units Method Reference Comment
Deltar178. ± 17.kJ/molCIDTAmunugama and Rodgers, 2002, 2RCD

(Lithium ion (1+) bullet Phenol) + Phenol = (Lithium ion (1+) bullet 2Phenol)

By formula: (Li+ bullet C6H6O) + C6H6O = (Li+ bullet 2C6H6O)

Quantity Value Units Method Reference Comment
Deltar115. ± 3.kJ/molCIDTAmunugama and Rodgers, 2002, 2RCD

Lithium ion (1+) + Benzene = (Lithium ion (1+) bullet Benzene)

By formula: Li+ + C6H6 = (Li+ bullet C6H6)

Quantity Value Units Method Reference Comment
Deltar161. ± 13.kJ/molCIDTAmicangelo and Armentrout, 2000RCD
Deltar159.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Deltar153.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Deltar115.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Deltar124.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M

(Lithium ion (1+) bullet Benzene) + Benzene = (Lithium ion (1+) bullet 2Benzene)

By formula: (Li+ bullet C6H6) + C6H6 = (Li+ bullet 2C6H6)

Quantity Value Units Method Reference Comment
Deltar104. ± 7.1kJ/molCIDTAmicangelo and Armentrout, 2000RCD

Lithium ion (1+) + Pyridine, 4-methyl- = (Lithium ion (1+) bullet Pyridine, 4-methyl-)

By formula: Li+ + C6H7N = (Li+ bullet C6H7N)

Quantity Value Units Method Reference Comment
Deltar196. ± 14.kJ/molCIDTRodgers, 2001, 2RCD

Lithium ion (1+) + Pyridine, 3-methyl- = (Lithium ion (1+) bullet Pyridine, 3-methyl-)

By formula: Li+ + C6H7N = (Li+ bullet C6H7N)

Quantity Value Units Method Reference Comment
Deltar197. ± 15.kJ/molCIDTRodgers, 2001, 2RCD

Lithium ion (1+) + Pyridine, 2-methyl- = (Lithium ion (1+) bullet Pyridine, 2-methyl-)

By formula: Li+ + C6H7N = (Li+ bullet C6H7N)

Quantity Value Units Method Reference Comment
Deltar194. ± 6.7kJ/molCIDTRodgers, 2001, 2RCD

Lithium ion (1+) + Cyclohexane = (Lithium ion (1+) bullet Cyclohexane)

By formula: Li+ + C6H12 = (Li+ bullet C6H12)

Quantity Value Units Method Reference Comment
Deltar100.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Methyl 4-nitrophenyl sulfone = (Lithium ion (1+) bullet Methyl 4-nitrophenyl sulfone)

By formula: Li+ + C7H8NO4S = (Li+ bullet C7H8NO4S)

Quantity Value Units Method Reference Comment
Deltar198.kJ/molCIDCBuncel, Decouzon, et al., 1997RCD

Lithium ion (1+) + Benzene, (methylsulfinyl)- = (Lithium ion (1+) bullet Benzene, (methylsulfinyl)-)

By formula: Li+ + C7H8OS = (Li+ bullet C7H8OS)

Quantity Value Units Method Reference Comment
Deltar230.kJ/molCIDCBuncel, Decouzon, et al., 1997RCD

Lithium ion (1+) + Anisole = (Lithium ion (1+) bullet Anisole)

By formula: Li+ + C7H8O = (Li+ bullet C7H8O)

Quantity Value Units Method Reference Comment
Deltar185. ± 19.kJ/molCIDTAmunugama and Rodgers, 2003RCD

(Lithium ion (1+) bullet Anisole) + Anisole = (Lithium ion (1+) bullet 2Anisole)

By formula: (Li+ bullet C7H8O) + C7H8O = (Li+ bullet 2C7H8O)

Quantity Value Units Method Reference Comment
Deltar121. ± 4.kJ/molCIDTAmunugama and Rodgers, 2003RCD

Lithium ion (1+) + Sulfone, methyl phenyl = (Lithium ion (1+) bullet Sulfone, methyl phenyl)

By formula: Li+ + C7H8O2S = (Li+ bullet C7H8O2S)

Quantity Value Units Method Reference Comment
Deltar213.kJ/molCIDCBuncel, Decouzon, et al., 1997RCD

Lithium ion (1+) + C7H8O3S = (Lithium ion (1+) bullet C7H8O3S)

By formula: Li+ + C7H8O3S = (Li+ bullet C7H8O3S)

Quantity Value Units Method Reference Comment
Deltar206.kJ/molCIDCBuncel, Decouzon, et al., 1997RCD

Lithium ion (1+) + Toluene = (Lithium ion (1+) bullet Toluene)

By formula: Li+ + C7H8 = (Li+ bullet C7H8)

Quantity Value Units Method Reference Comment
Deltar183. ± 17.kJ/molCIDTAmunugama and Rodgers, 2002, 3RCD

(Lithium ion (1+) bullet Toluene) + Toluene = (Lithium ion (1+) bullet 2Toluene)

By formula: (Li+ bullet C7H8) + C7H8 = (Li+ bullet 2C7H8)

Quantity Value Units Method Reference Comment
Deltar116. ± 3.kJ/molCIDTAmunugama and Rodgers, 2002, 3RCD

Lithium ion (1+) + Benzene, 1-methyl-4-(methylsulfonyl)- = (Lithium ion (1+) bullet Benzene, 1-methyl-4-(methylsulfonyl)-)

By formula: Li+ + C8H10O2S = (Li+ bullet C8H10O2S)

Quantity Value Units Method Reference Comment
Deltar216.kJ/molCIDCBuncel, Decouzon, et al., 1997RCD

Lithium ion (1+) + 12-Crown-4 = (Lithium ion (1+) bullet 12-Crown-4)

By formula: Li+ + C8H16O4 = (Li+ bullet C8H16O4)

Quantity Value Units Method Reference Comment
Deltar252. ± 13.kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + Diphenyl sulfoxide = (Lithium ion (1+) bullet Diphenyl sulfoxide)

By formula: Li+ + C12H10OS = (Li+ bullet C12H10OS)

Quantity Value Units Method Reference Comment
Deltar234.kJ/molCIDCBuncel, Decouzon, et al., 1997RCD

Lithium ion (1+) + Diphenyl sulfone = (Lithium ion (1+) bullet Diphenyl sulfone)

By formula: Li+ + C12H10O2S = (Li+ bullet C12H10O2S)

Quantity Value Units Method Reference Comment
Deltar218.kJ/molCIDCBuncel, Decouzon, et al., 1997RCD

Lithium ion (1+) + Water = (Lithium ion (1+) bullet Water)

By formula: Li+ + H2O = (Li+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar135. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD
Deltar140.kJ/molHPMSDzidic and Kebarle, 1970gas phase; interpolated; M
Quantity Value Units Method Reference Comment
Deltar96.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; interpolated; M

(Lithium ion (1+) bullet Water) + Water = (Lithium ion (1+) bullet 2Water)

By formula: (Li+ bullet H2O) + H2O = (Li+ bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar113. ± 10.kJ/molCIDTRodgers and Armentrout, 2000RCD
Deltar108.kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
Deltar88.3J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

(Lithium ion (1+) bullet 2Water) + Water = (Lithium ion (1+) bullet 3Water)

By formula: (Li+ bullet 2H2O) + H2O = (Li+ bullet 3H2O)

Quantity Value Units Method Reference Comment
Deltar94.1 ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD
Deltar70. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray; M
Deltar86.6kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
Deltar96.J/mol*KHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray; M
Deltar104.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
41.8300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray; M

(Lithium ion (1+) bullet 3Water) + Water = (Lithium ion (1+) bullet 4Water)

By formula: (Li+ bullet 3H2O) + H2O = (Li+ bullet 4H2O)

Quantity Value Units Method Reference Comment
Deltar69.9 ± 5.0kJ/molCIDTRodgers and Armentrout, 2000RCD
Deltar68.6kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Deltar60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar125.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
Deltar96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
33.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

(Lithium ion (1+) bullet 4Water) + Water = (Lithium ion (1+) bullet 5Water)

By formula: (Li+ bullet 4H2O) + H2O = (Li+ bullet 5H2O)

Quantity Value Units Method Reference Comment
Deltar56.9 ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD
Deltar58.2kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Deltar50. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar131.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
Deltar96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
23.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

(Lithium ion (1+) bullet 5Water) + Water = (Lithium ion (1+) bullet 6Water)

By formula: (Li+ bullet 5H2O) + H2O = (Li+ bullet 6H2O)

Quantity Value Units Method Reference Comment
Deltar59.8 ± 5.0kJ/molCIDTRodgers and Armentrout, 2000RCD
Deltar50.6kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
Deltar134.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

Lithium ion (1+) + Hydrogen = (Lithium ion (1+) bullet Hydrogen)

By formula: Li+ + H2 = (Li+ bullet H2)

Quantity Value Units Method Reference Comment
Deltar27. ± 19.kJ/molEIWu, 1979gas phase; M

Lithium ion (1+) + Ammonia = (Lithium ion (1+) bullet Ammonia)

By formula: Li+ + H3N = (Li+ bullet H3N)

Quantity Value Units Method Reference Comment
Deltar164.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Deltar161.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Deltar96.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
Deltar134.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

(Lithium ion (1+) bullet Ammonia) + Ammonia = (Lithium ion (1+) bullet 2Ammonia)

By formula: (Li+ bullet H3N) + H3N = (Li+ bullet 2H3N)

Quantity Value Units Method Reference Comment
Deltar138.kJ/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
Deltar124.J/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

(Lithium ion (1+) bullet 2Ammonia) + Ammonia = (Lithium ion (1+) bullet 3Ammonia)

By formula: (Li+ bullet 2H3N) + H3N = (Li+ bullet 3H3N)

Quantity Value Units Method Reference Comment
Deltar87.9kJ/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
Deltar106.J/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

(Lithium ion (1+) bullet 3Ammonia) + Ammonia = (Lithium ion (1+) bullet 4Ammonia)

By formula: (Li+ bullet 3H3N) + H3N = (Li+ bullet 4H3N)

Quantity Value Units Method Reference Comment
Deltar69.0kJ/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
Deltar136.J/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

(Lithium ion (1+) bullet 4Ammonia) + Ammonia = (Lithium ion (1+) bullet 5Ammonia)

By formula: (Li+ bullet 4H3N) + H3N = (Li+ bullet 5H3N)

Quantity Value Units Method Reference Comment
Deltar46.4kJ/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
Deltar117.J/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

(Lithium ion (1+) bullet 5Ammonia) + Ammonia = (Lithium ion (1+) bullet 6Ammonia)

By formula: (Li+ bullet 5H3N) + H3N = (Li+ bullet 6H3N)

Quantity Value Units Method Reference Comment
Deltar39.kJ/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
Deltar106.J/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

Lithium ion (1+) + helium = (Lithium ion (1+) bullet helium)

By formula: Li+ + He = (Li+ bullet He)

Quantity Value Units Method Reference Comment
Deltar7.15kJ/molIMobGatland, 1984gas phase; M
Deltar6.86kJ/molSCATTERINGGislason, 1984gas phase; M
Deltar7.07kJ/molIMobViehland, 1984gas phase; M
Deltar4.56kJ/molIMobMason and Sharp, 1958gas phase; M
Deltar13.2kJ/molIMobTakebe, 1983gas phase; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
-15.309.DTColonna-Romano and Keller, 1976gas phase; low E/N; M

Lithium ion (1+) + Krypton = (Lithium ion (1+) bullet Krypton)

By formula: Li+ + Kr = (Li+ bullet Kr)

Quantity Value Units Method Reference Comment
Deltar44.4kJ/molSCATTERINGGislason, 1984gas phase; M
Deltar38.kJ/molIMobViehland, 1984gas phase; M
Deltar68.6kJ/molIMobTakebe, 1983gas phase; M

Lithium ion (1+) + Nitrogen = (Lithium ion (1+) bullet Nitrogen)

By formula: Li+ + N2 = (Li+ bullet N2)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
23.318.DTGatland, Colonna-Romano, et al., 1975gas phase; low E/N; M

(Lithium ion (1+) bullet Nitrogen) + Nitrogen = (Lithium ion (1+) bullet 2Nitrogen)

By formula: (Li+ bullet N2) + N2 = (Li+ bullet 2N2)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
18.318.DTGatland, Colonna-Romano, et al., 1975gas phase; low E/N; M

Lithium ion (1+) + neon = (Lithium ion (1+) bullet neon)

By formula: Li+ + Ne = (Li+ bullet Ne)

Quantity Value Units Method Reference Comment
Deltar11.0kJ/molSCATTERINGGislason, 1984gas phase; M
Deltar11.9kJ/molIMobViehland, 1984gas phase; M
Deltar14.0kJ/molIMobTakebe, 1983gas phase; M

Lithium ion (1+) + Oxygen = (Lithium ion (1+) bullet Oxygen)

By formula: Li+ + O2 = (Li+ bullet O2)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
18.319.DTColonna-Romano and Keller, 1976gas phase; low E/N; M

Lithium ion (1+) + Xenon = (Lithium ion (1+) bullet Xenon)

By formula: Li+ + Xe = (Li+ bullet Xe)

Quantity Value Units Method Reference Comment
Deltar51.5kJ/molSCATTERINGGislason, 1984gas phase; M
Deltar52.7kJ/molIMobViehland, 1984gas phase; M
Deltar87.0kJ/molIMobTakebe, 1983gas phase; M

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Woodin and Beauchamp, 1978
Woodin, R.L.; Beauchamp, J.L., Bonding of Li+ to Lewis Bases in the Gas Phase. Reversals in Methyl Substituent Effects for Different Reference Acids, J. Am. Chem. Soc., 1978, 100, 2, 501, https://doi.org/10.1021/ja00470a024 . [all data]

Dzidic and Kebarle, 1970
Dzidic, I.; Kebarle, P., Hydration of the Alkali Ions in the Gas Phase. Enthalpies and Entropies of Reactions M+(H2O)n-1 + H2O = M+(H2O)n, J. Phys. Chem., 1970, 74, 7, 1466, https://doi.org/10.1021/j100702a013 . [all data]

Staley and Beauchamp, 1975
Staley, R.H.; Beauchamp, J.L., Intrinsic Acid - Base Properties of Molecules. Binding Energies of Li+ to pi - and n - Donor Bases, J. Am. Chem. Soc., 1975, 97, 20, 5920, https://doi.org/10.1021/ja00853a050 . [all data]

More, Gledening, et al., 1996
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Notes

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