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Lithium ion (1+)


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RCD - Robert C. Dunbar
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 51 to 100

(Lithium ion (1+) bullet 2Carbon monoxide) + Carbon monoxide = (Lithium ion (1+) bullet 3Carbon monoxide)

By formula: (Li+ bullet 2CO) + CO = (Li+ bullet 3CO)

Quantity Value Units Method Reference Comment
Deltar35. ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD
Deltar35. ± 4.2kJ/molCIDTWalter, Sievers, et al., 1998RCD

(Lithium ion (1+) bullet Carbon monoxide) + Carbon monoxide = (Lithium ion (1+) bullet 2Carbon monoxide)

By formula: (Li+ bullet CO) + CO = (Li+ bullet 2CO)

Quantity Value Units Method Reference Comment
Deltar36. ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD
Deltar36. ± 4.2kJ/molCIDTWalter, Sievers, et al., 1998RCD

Lithium ion (1+) + Carbon monoxide = (Lithium ion (1+) bullet Carbon monoxide)

By formula: Li+ + CO = (Li+ bullet CO)

Quantity Value Units Method Reference Comment
Deltar55. ± 13.kJ/molCIDTRodgers and Armentrout, 2000RCD
Deltar55. ± 12.kJ/molCIDTWalter, Sievers, et al., 1998RCD

(Lithium ion (1+) bullet Nitrogen) + Nitrogen = (Lithium ion (1+) bullet 2Nitrogen)

By formula: (Li+ bullet N2) + N2 = (Li+ bullet 2N2)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
18.318.DTGatland, Colonna-Romano, et al., 1975gas phase; low E/N; M

Lithium ion (1+) + Nitrogen = (Lithium ion (1+) bullet Nitrogen)

By formula: Li+ + N2 = (Li+ bullet N2)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
23.318.DTGatland, Colonna-Romano, et al., 1975gas phase; low E/N; M

Lithium ion (1+) + Oxygen = (Lithium ion (1+) bullet Oxygen)

By formula: Li+ + O2 = (Li+ bullet O2)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
18.319.DTColonna-Romano and Keller, 1976gas phase; low E/N; M

(Lithium ion (1+) bullet Toluene) + Toluene = (Lithium ion (1+) bullet 2Toluene)

By formula: (Li+ bullet C7H8) + C7H8 = (Li+ bullet 2C7H8)

Quantity Value Units Method Reference Comment
Deltar116. ± 3.kJ/molCIDTAmunugama and Rodgers, 2002RCD

(Lithium ion (1+) bullet Phenol) + Phenol = (Lithium ion (1+) bullet 2Phenol)

By formula: (Li+ bullet C6H6O) + C6H6O = (Li+ bullet 2C6H6O)

Quantity Value Units Method Reference Comment
Deltar115. ± 3.kJ/molCIDTAmunugama and Rodgers, 2002, 2RCD

(Lithium ion (1+) bullet Benzene, fluoro-) + Benzene, fluoro- = (Lithium ion (1+) bullet 2Benzene, fluoro-)

By formula: (Li+ bullet C6H5F) + C6H5F = (Li+ bullet 2C6H5F)

Quantity Value Units Method Reference Comment
Deltar95. ± 3.kJ/molCIDTAmunugama and Rodgers, 2002, 3RCD

(Lithium ion (1+) bullet Anisole) + Anisole = (Lithium ion (1+) bullet 2Anisole)

By formula: (Li+ bullet C7H8O) + C7H8O = (Li+ bullet 2C7H8O)

Quantity Value Units Method Reference Comment
Deltar121. ± 4.kJ/molCIDTAmunugama and Rodgers, 2003RCD

(Lithium ion (1+) bullet Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (Lithium ion (1+) bullet 2Ethane, 1,2-dimethoxy-)

By formula: (Li+ bullet C4H10O2) + C4H10O2 = (Li+ bullet 2C4H10O2)

Quantity Value Units Method Reference Comment
Deltar139. ± 12.kJ/molCIDTRodgers and Armentrout, 2000RCD

(Lithium ion (1+) bullet Benzene) + Benzene = (Lithium ion (1+) bullet 2Benzene)

By formula: (Li+ bullet C6H6) + C6H6 = (Li+ bullet 2C6H6)

Quantity Value Units Method Reference Comment
Deltar104. ± 7.1kJ/molCIDTAmicangelo and Armentrout, 2000RCD

Lithium ion (1+) + 2H-Tetrazole = (Lithium ion (1+) bullet 2H-Tetrazole)

By formula: Li+ + CH2N4 = (Li+ bullet CH2N4)

Quantity Value Units Method Reference Comment
Deltar151. ± 7.1kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + Hydrogen = (Lithium ion (1+) bullet Hydrogen)

By formula: Li+ + H2 = (Li+ bullet H2)

Quantity Value Units Method Reference Comment
Deltar27. ± 19.kJ/molEIWu, 1979gas phase; M

Lithium ion (1+) + Acetamide, N-methyl- = (Lithium ion (1+) bullet Acetamide, N-methyl-)

By formula: Li+ + C3H7NO = (Li+ bullet C3H7NO)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
173.373.CIDT,ICRHerreros, Gal, et al., 1999RCD

Lithium ion (1+) + Toluene = (Lithium ion (1+) bullet Toluene)

By formula: Li+ + C7H8 = (Li+ bullet C7H8)

Quantity Value Units Method Reference Comment
Deltar183. ± 17.kJ/molCIDTAmunugama and Rodgers, 2002RCD

Lithium ion (1+) + Phenol = (Lithium ion (1+) bullet Phenol)

By formula: Li+ + C6H6O = (Li+ bullet C6H6O)

Quantity Value Units Method Reference Comment
Deltar178. ± 17.kJ/molCIDTAmunugama and Rodgers, 2002, 2RCD

Lithium ion (1+) + Pyrrole = (Lithium ion (1+) bullet Pyrrole)

By formula: Li+ + C4H5N = (Li+ bullet C4H5N)

Quantity Value Units Method Reference Comment
Deltar177. ± 17.kJ/molCIDTHuang and Rodgers, 2002RCD

Lithium ion (1+) + Formamide, N-methyl- = (Lithium ion (1+) bullet Formamide, N-methyl-)

By formula: Li+ + C2H5NO = (Li+ bullet C2H5NO)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
166.373.CIDCHerreros, Gal, et al., 1999RCD

Lithium ion (1+) + 1H-Pyrazole = (Lithium ion (1+) bullet 1H-Pyrazole)

By formula: Li+ + C3H4N2 = (Li+ bullet C3H4N2)

Quantity Value Units Method Reference Comment
Deltar187. ± 17.kJ/molCIDTHuang and Rodgers, 2002RCD

Lithium ion (1+) + 1H-Imidazole = (Lithium ion (1+) bullet 1H-Imidazole)

By formula: Li+ + C3H4N2 = (Li+ bullet C3H4N2)

Quantity Value Units Method Reference Comment
Deltar211. ± 9.6kJ/molCIDTHuang and Rodgers, 2002RCD

Lithium ion (1+) + Benzene, fluoro- = (Lithium ion (1+) bullet Benzene, fluoro-)

By formula: Li+ + C6H5F = (Li+ bullet C6H5F)

Quantity Value Units Method Reference Comment
Deltar147. ± 21.kJ/molCIDTAmunugama and Rodgers, 2002, 3RCD

Lithium ion (1+) + 1H-Imidazole, 1-methyl- = (Lithium ion (1+) bullet 1H-Imidazole, 1-methyl-)

By formula: Li+ + C4H6N2 = (Li+ bullet C4H6N2)

Quantity Value Units Method Reference Comment
Deltar242. ± 21.kJ/molCIDTHuang and Rodgers, 2002RCD

Lithium ion (1+) + 1H-Pyrazole, 1-methyl- = (Lithium ion (1+) bullet 1H-Pyrazole, 1-methyl-)

By formula: Li+ + C4H6N2 = (Li+ bullet C4H6N2)

Quantity Value Units Method Reference Comment
Deltar207. ± 19.kJ/molCIDTHuang and Rodgers, 2002RCD

Lithium ion (1+) + Anisole = (Lithium ion (1+) bullet Anisole)

By formula: Li+ + C7H8O = (Li+ bullet C7H8O)

Quantity Value Units Method Reference Comment
Deltar185. ± 19.kJ/molCIDTAmunugama and Rodgers, 2003RCD

Lithium ion (1+) + Ethane, 1,2-dimethoxy- = (Lithium ion (1+) bullet Ethane, 1,2-dimethoxy-)

By formula: Li+ + C4H10O2 = (Li+ bullet C4H10O2)

Quantity Value Units Method Reference Comment
Deltar158. ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + C2H3N3 = (Lithium ion (1+) bullet C2H3N3)

By formula: Li+ + C2H3N3 = (Li+ bullet C2H3N3)

Quantity Value Units Method Reference Comment
Deltar136. ± 7.1kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + 1H-1,2,4-Triazole = (Lithium ion (1+) bullet 1H-1,2,4-Triazole)

By formula: Li+ + C2H3N3 = (Li+ bullet C2H3N3)

Quantity Value Units Method Reference Comment
Deltar191. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + Pyrazine = (Lithium ion (1+) bullet Pyrazine)

By formula: Li+ + C4H4N2 = (Li+ bullet C4H4N2)

Quantity Value Units Method Reference Comment
Deltar149. ± 14.kJ/molCIDTAmunugama and Rodgers, 2000RCD

Lithium ion (1+) + 1,3,5-Triazine = (Lithium ion (1+) bullet 1,3,5-Triazine)

By formula: Li+ + C3H3N3 = (Li+ bullet C3H3N3)

Quantity Value Units Method Reference Comment
Deltar127. ± 13.kJ/molCIDTAmunugama and Rodgers, 2000RCD

Lithium ion (1+) + 12-Crown-4 = (Lithium ion (1+) bullet 12-Crown-4)

By formula: Li+ + C8H16O4 = (Li+ bullet C8H16O4)

Quantity Value Units Method Reference Comment
Deltar252. ± 13.kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + Formamide = (Lithium ion (1+) bullet Formamide)

By formula: Li+ + CH3NO = (Li+ bullet CH3NO)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
157.373.CIDCHerreros, Gal, et al., 1999RCD

Lithium ion (1+) + 1H-Pyrrole, 1-methyl- = (Lithium ion (1+) bullet 1H-Pyrrole, 1-methyl-)

By formula: Li+ + C5H7N = (Li+ bullet C5H7N)

Quantity Value Units Method Reference Comment
Deltar186. ± 17.kJ/molCIDTHuang and Rodgers, 2002RCD

Lithium ion (1+) + C7H8O3S = (Lithium ion (1+) bullet C7H8O3S)

By formula: Li+ + C7H8O3S = (Li+ bullet C7H8O3S)

Quantity Value Units Method Reference Comment
Deltar206.kJ/molCIDCBuncel, Decouzon, et al., 1997RCD

Lithium ion (1+) + Ethanol = (Lithium ion (1+) bullet Ethanol)

By formula: Li+ + C2H6O = (Li+ bullet C2H6O)

Quantity Value Units Method Reference Comment
Deltar164. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + Isopropyl Alcohol = (Lithium ion (1+) bullet Isopropyl Alcohol)

By formula: Li+ + C3H8O = (Li+ bullet C3H8O)

Quantity Value Units Method Reference Comment
Deltar173. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + 1-Propanol = (Lithium ion (1+) bullet 1-Propanol)

By formula: Li+ + C3H8O = (Li+ bullet C3H8O)

Quantity Value Units Method Reference Comment
Deltar171. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + 1-Butanol = (Lithium ion (1+) bullet 1-Butanol)

By formula: Li+ + C4H10O = (Li+ bullet C4H10O)

Quantity Value Units Method Reference Comment
Deltar178. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + 2-Propanol, 2-methyl- = (Lithium ion (1+) bullet 2-Propanol, 2-methyl-)

By formula: Li+ + C4H10O = (Li+ bullet C4H10O)

Quantity Value Units Method Reference Comment
Deltar178. ± 10.kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + 1-Propanol, 2-methyl- = (Lithium ion (1+) bullet 1-Propanol, 2-methyl-)

By formula: Li+ + C4H10O = (Li+ bullet C4H10O)

Quantity Value Units Method Reference Comment
Deltar169. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + 2-Butanol = (Lithium ion (1+) bullet 2-Butanol)

By formula: Li+ + C4H10O = (Li+ bullet C4H10O)

Quantity Value Units Method Reference Comment
Deltar174. ± 9.2kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + Pyridine, 4-methyl- = (Lithium ion (1+) bullet Pyridine, 4-methyl-)

By formula: Li+ + C6H7N = (Li+ bullet C6H7N)

Quantity Value Units Method Reference Comment
Deltar196. ± 14.kJ/molCIDTRodgers, 2001RCD

Lithium ion (1+) + Pyridine, 3-methyl- = (Lithium ion (1+) bullet Pyridine, 3-methyl-)

By formula: Li+ + C6H7N = (Li+ bullet C6H7N)

Quantity Value Units Method Reference Comment
Deltar197. ± 15.kJ/molCIDTRodgers, 2001RCD

Lithium ion (1+) + Pyridine, 2-methyl- = (Lithium ion (1+) bullet Pyridine, 2-methyl-)

By formula: Li+ + C6H7N = (Li+ bullet C6H7N)

Quantity Value Units Method Reference Comment
Deltar194. ± 6.7kJ/molCIDTRodgers, 2001RCD

Lithium ion (1+) + 3-Aminopyridine = (Lithium ion (1+) bullet 3-Aminopyridine)

By formula: Li+ + C5H6N2 = (Li+ bullet C5H6N2)

Quantity Value Units Method Reference Comment
Deltar202. ± 10.kJ/molCIDTRodgers, 2001, 2RCD

Lithium ion (1+) + 4-Aminopyridine = (Lithium ion (1+) bullet 4-Aminopyridine)

By formula: Li+ + C5H6N2 = (Li+ bullet C5H6N2)

Quantity Value Units Method Reference Comment
Deltar217. ± 21.kJ/molCIDTRodgers, 2001, 2RCD

Lithium ion (1+) + 2-Aminopyridine = (Lithium ion (1+) bullet 2-Aminopyridine)

By formula: Li+ + C5H6N2 = (Li+ bullet C5H6N2)

Quantity Value Units Method Reference Comment
Deltar238. ± 21.kJ/molCIDTRodgers, 2001, 2RCD

Lithium ion (1+) + Benzene, (methylsulfinyl)- = (Lithium ion (1+) bullet Benzene, (methylsulfinyl)-)

By formula: Li+ + C7H8OS = (Li+ bullet C7H8OS)

Quantity Value Units Method Reference Comment
Deltar230.kJ/molCIDCBuncel, Decouzon, et al., 1997RCD

Lithium ion (1+) + Methyl 4-nitrophenyl sulfone = (Lithium ion (1+) bullet Methyl 4-nitrophenyl sulfone)

By formula: Li+ + C7H8NO4S = (Li+ bullet C7H8NO4S)

Quantity Value Units Method Reference Comment
Deltar198.kJ/molCIDCBuncel, Decouzon, et al., 1997RCD

Lithium ion (1+) + Sulfone, methyl phenyl = (Lithium ion (1+) bullet Sulfone, methyl phenyl)

By formula: Li+ + C7H8O2S = (Li+ bullet C7H8O2S)

Quantity Value Units Method Reference Comment
Deltar213.kJ/molCIDCBuncel, Decouzon, et al., 1997RCD

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Walter, Sievers, et al., 1998
Walter, D.; Sievers, M.R.; Armentrout, P.B., Alkali Ion Carbonyls: Sequential Bond Energies of Li+(CO)x (x=1-3), Na+(CO)x (x=1, 2), and K+(CO), Int. J. Mass Spectrom., 1998, 175, 1-2, 93, https://doi.org/10.1016/S0168-1176(98)00109-8 . [all data]

Gatland, Colonna-Romano, et al., 1975
Gatland, I.R.; Colonna-Romano, L.M.; Keller, G.E., Single and Double Clustering of Nitrogen to Li+, Phys. Rev. A, 1975, 12, 5, 1885, https://doi.org/10.1103/PhysRevA.12.1885 . [all data]

Colonna-Romano and Keller, 1976
Colonna-Romano, L.M.; Keller, G.E., The Clustering of O2 and He to Li+, J. Chem. Phys., 1976, 64, 6, 2684, https://doi.org/10.1063/1.432522 . [all data]

Amunugama and Rodgers, 2002
Amunugama, R.; Rodgers, M.T., Influence of substituents on cation-pi interactions. 1. Absolute binding energies of alkali metal cation-toluene complexes determined by threshold collision-induced dissociation and theoretical studies, J. Phys. Chem. A, 2002, 106, 22, 5529, https://doi.org/10.1021/jp014307b . [all data]

Amunugama and Rodgers, 2002, 2
Amunugama, R.; Rodgers, M.T., The influence of substituents on cation-pi interactions. 4. Absolute binding energies of alkali metal cation - Phenol complexes determined by threshold collision-induced dissociation and theoretical studies, J. Phys. Chem. A, 2002, 106, 42, 9718, https://doi.org/10.1021/jp0211584 . [all data]

Amunugama and Rodgers, 2002, 3
Amunugama, R.; Rodgers, M.T., Influence of substituents on cation-pi interactions. 2. Absolute binding energies of alkali metal cation-fluorobenzene complexes determined by threshold collision-induced dissociation and theoretical studies, J. Phys. Chem. A, 2002, 106, 39, 9092, https://doi.org/10.1021/jp020459a . [all data]

Amunugama and Rodgers, 2003
Amunugama, R.; Rodgers, M.T., Influence of substituents on cation-pi interactions - 5. Absolute binding energies of alkali metal cation-anisole complexes determined by threshold collision-induced dissociation and theoretical studies, Int. J. Mass Spectrom., 2003, 222, 1-3, 431, https://doi.org/10.1016/S1387-3806(02)00945-4 . [all data]

Amicangelo and Armentrout, 2000
Amicangelo, J.C.; Armentrout, P.B., Absolute Binding Energies of Alkali-Metal Cation Complexes with Benzene Determined by Threshold Collision-Induced Dissociation Experiments and Ab Initio Theory, J. Phys. Chem. A, 2000, 104, 48, 11420, https://doi.org/10.1021/jp002652f . [all data]

Wu, 1979
Wu, C.H., Binding Energies of LiH2 and LiH2+ and the Ionization Potential of LiH2, J. Chem. Phys., 1979, 71, 2, 783, https://doi.org/10.1063/1.438367 . [all data]

Herreros, Gal, et al., 1999
Herreros, M.; Gal, J.-F.; Maria, P.-C.; Decouzon, M., Gas-Phase Basicity of Simple Amides Toward Proton and Lithium Cation: An Experimental and Theoretical Study, Eur. J. Mass Spectrom., 1999, 5, 1, 259, https://doi.org/10.1255/ejms.282 . [all data]

Huang and Rodgers, 2002
Huang, H.; Rodgers, M.T., Sigma versus Pi interactions in alkali metal ion binding to azoles: Threshold collision-induced dissociation and ab initio theory studies, J. Phys. Chem. A, 2002, 106, 16, 4277, https://doi.org/10.1021/jp013630b . [all data]

Amunugama and Rodgers, 2000
Amunugama, R.; Rodgers, M.T., Absolute Alkali Metal Ion Binding Affinities of Several Azines Determined by Threshold Collision-Induced Dissociation and Ab Initio Theory, Int. J. Mass Spectrom., 2000, 195/196, 439, https://doi.org/10.1016/S1387-3806(99)00145-1 . [all data]

Buncel, Decouzon, et al., 1997
Buncel, E.; Decouzon, M.; Formento, A.; Gal, J.-F.; Herreros, M.; Li, L.; Maria, P.-C., Lithium-Cation and Proton Affinities of Sulfoxides and Sulfones: A Fourier Transform Ion Cyclotron Resonance Study, J. Am. Soc. Mass Spectrom., 1997, 8, 3, 262, https://doi.org/10.1016/S1044-0305(96)00255-3 . [all data]

Rodgers, 2001
Rodgers, M.T., Substituent Effects in the Binding of Alkali Metal Ions to Pyridines, Studied by Threshold Collision-Induced Dissociation and ab Initio Theory: The Methylpyridines, J. Phys. Chem. A, 2001, 105, 11, 2374, https://doi.org/10.1021/jp004055z . [all data]

Rodgers, 2001, 2
Rodgers, M.T., Substituent Effects in the Binding of Alkali Metal Ions to Pyridines, Studied by Threshold Collision-Induced Dissociation and ab Initio Theory: The Aminopyridines, J. Phys. Chem. A, 2001, 105, 35, 8145, https://doi.org/10.1021/jp011555z . [all data]


Notes

Go To: Top, Reaction thermochemistry data, References