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Lithium ion (1+)


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RCD - Robert C. Dunbar
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 1 to 50

Lithium ion (1+) + Dimethyl ether = (Lithium ion (1+) bullet Dimethyl ether)

By formula: Li+ + C2H6O = (Li+ bullet C2H6O)

Quantity Value Units Method Reference Comment
Deltar39.4 ± 2.6kcal/molCIDTRodgers and Armentrout, 2000RCD
Deltar39.5kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Deltar39.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Deltar27.cal/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Deltar31.3kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
39.4 (+2.5,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

Lithium ion (1+) + Argon = (Lithium ion (1+) bullet Argon)

By formula: Li+ + Ar = (Li+ bullet Ar)

Quantity Value Units Method Reference Comment
Deltar7. ± 1.kcal/molAVGN/AAverage of 4 out of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Deltar7.cal/mol*KDTMcKnight and Sawina, 1973gas phase; «DELTA»rS approximate; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
1.4294.IMobCassidy and Elford, 1985gas phase; M
1.9319.DTKeller, Beyer, et al., 1973gas phase; LOW E/N; M
2.6215.DTMcKnight and Sawina, 1973gas phase; «DELTA»rS approximate; M

Lithium ion (1+) + Benzene = (Lithium ion (1+) bullet Benzene)

By formula: Li+ + C6H6 = (Li+ bullet C6H6)

Quantity Value Units Method Reference Comment
Deltar38.5 ± 3.2kcal/molCIDTAmicangelo and Armentrout, 2000RCD
Deltar37.9kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Deltar36.5kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Deltar27.5cal/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Deltar29.7kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Methyl Alcohol = (Lithium ion (1+) bullet Methyl Alcohol)

By formula: Li+ + CH4O = (Li+ bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar36.8 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000RCD
Deltar38.1kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Deltar38.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Deltar26.cal/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
Deltar30.3kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Ammonia = (Lithium ion (1+) bullet Ammonia)

By formula: Li+ + H3N = (Li+ bullet H3N)

Quantity Value Units Method Reference Comment
Deltar39.1kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Deltar38.5kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
Deltar32.1kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Formaldehyde = (Lithium ion (1+) bullet Formaldehyde)

By formula: Li+ + CH2O = (Li+ bullet CH2O)

Quantity Value Units Method Reference Comment
Deltar36.0kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Deltar36.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Deltar26.cal/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
Deltar28.2kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Hydrogen cyanide = (Lithium ion (1+) bullet Hydrogen cyanide)

By formula: Li+ + CHN = (Li+ bullet CHN)

Quantity Value Units Method Reference Comment
Deltar36.4kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Deltar36.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Deltar25.cal/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
Deltar28.kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Methylamine, N,N-dimethyl- = (Lithium ion (1+) bullet Methylamine, N,N-dimethyl-)

By formula: Li+ + C3H9N = (Li+ bullet C3H9N)

Quantity Value Units Method Reference Comment
Deltar42.1kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Deltar40.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970; M
Quantity Value Units Method Reference Comment
Deltar28.cal/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Deltar33.kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M

(Lithium ion (1+) bullet 3Water) + Water = (Lithium ion (1+) bullet 4Water)

By formula: (Li+ bullet 3H2O) + H2O = (Li+ bullet 4H2O)

Quantity Value Units Method Reference Comment
Deltar16.7 ± 1.2kcal/molCIDTRodgers and Armentrout, 2000RCD
Deltar16.4kcal/molHPMSDzidic and Kebarle, 1970gas phase; M
Deltar15. ± 3.kcal/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar29.9cal/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
Deltar23.cal/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
7.8300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

(Lithium ion (1+) bullet 4Water) + Water = (Lithium ion (1+) bullet 5Water)

By formula: (Li+ bullet 4H2O) + H2O = (Li+ bullet 5H2O)

Quantity Value Units Method Reference Comment
Deltar13.6 ± 1.0kcal/molCIDTRodgers and Armentrout, 2000RCD
Deltar13.9kcal/molHPMSDzidic and Kebarle, 1970gas phase; M
Deltar12. ± 3.kcal/molHPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar31.4cal/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
Deltar23.cal/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
5.5300.HPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

Lithium ion (1+) + Dimethylamine = (Lithium ion (1+) bullet Dimethylamine)

By formula: Li+ + C2H7N = (Li+ bullet C2H7N)

Quantity Value Units Method Reference Comment
Deltar42.2kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Deltar27.cal/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Deltar34.1kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Methylamine = (Lithium ion (1+) bullet Methylamine)

By formula: Li+ + CH5N = (Li+ bullet CH5N)

Quantity Value Units Method Reference Comment
Deltar41.1kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
Deltar26.cal/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
Deltar33.3kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

(Lithium ion (1+) bullet 2Water) + Water = (Lithium ion (1+) bullet 3Water)

By formula: (Li+ bullet 2H2O) + H2O = (Li+ bullet 3H2O)

Quantity Value Units Method Reference Comment
Deltar22.5 ± 1.0kcal/molCIDTRodgers and Armentrout, 2000RCD
Deltar17. ± 3.kcal/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray; M
Deltar20.7kcal/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray; M
Deltar24.9cal/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
10.0300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray; M

Lithium ion (1+) + helium = (Lithium ion (1+) bullet helium)

By formula: Li+ + He = (Li+ bullet He)

Quantity Value Units Method Reference Comment
Deltar1.71kcal/molIMobGatland, 1984gas phase; M
Deltar1.64kcal/molSCATTERINGGislason, 1984gas phase; M
Deltar1.69kcal/molIMobViehland, 1984gas phase; M
Deltar1.09kcal/molIMobMason and Sharp, 1958gas phase; M
Deltar3.16kcal/molIMobTakebe, 1983gas phase; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
-3.7309.DTColonna-Romano and Keller, 1976gas phase; low E/N; M

Lithium ion (1+) + Water = (Lithium ion (1+) bullet Water)

By formula: Li+ + H2O = (Li+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar32.3 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000RCD
Deltar34.kcal/molHPMSDzidic and Kebarle, 1970gas phase; interpolated; M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KHPMSDzidic and Kebarle, 1970gas phase; interpolated; M

(Lithium ion (1+) bullet 5Water) + Water = (Lithium ion (1+) bullet 6Water)

By formula: (Li+ bullet 5H2O) + H2O = (Li+ bullet 6H2O)

Quantity Value Units Method Reference Comment
Deltar14.3 ± 1.2kcal/molCIDTRodgers and Armentrout, 2000RCD
Deltar12.1kcal/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
Deltar32.0cal/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

(Lithium ion (1+) bullet Water) + Water = (Lithium ion (1+) bullet 2Water)

By formula: (Li+ bullet H2O) + H2O = (Li+ bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar27.0 ± 2.4kcal/molCIDTRodgers and Armentrout, 2000RCD
Deltar25.8kcal/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
Deltar21.1cal/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

Lithium ion (1+) + Pyridine = (Lithium ion (1+) bullet Pyridine)

By formula: Li+ + C5H5N = (Li+ bullet C5H5N)

Quantity Value Units Method Reference Comment
Deltar43.2 ± 3.5kcal/molCIDTAmunugama and Rodgers, 2000RCD
Deltar44.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + neon = (Lithium ion (1+) bullet neon)

By formula: Li+ + Ne = (Li+ bullet Ne)

Quantity Value Units Method Reference Comment
Deltar2.63kcal/molSCATTERINGGislason, 1984gas phase; M
Deltar2.84kcal/molIMobViehland, 1984gas phase; M
Deltar3.34kcal/molIMobTakebe, 1983gas phase; M

Lithium ion (1+) + Xenon = (Lithium ion (1+) bullet Xenon)

By formula: Li+ + Xe = (Li+ bullet Xe)

Quantity Value Units Method Reference Comment
Deltar12.3kcal/molSCATTERINGGislason, 1984gas phase; M
Deltar12.6kcal/molIMobViehland, 1984gas phase; M
Deltar20.8kcal/molIMobTakebe, 1983gas phase; M

Lithium ion (1+) + Krypton = (Lithium ion (1+) bullet Krypton)

By formula: Li+ + Kr = (Li+ bullet Kr)

Quantity Value Units Method Reference Comment
Deltar10.6kcal/molSCATTERINGGislason, 1984gas phase; M
Deltar9.2kcal/molIMobViehland, 1984gas phase; M
Deltar16.4kcal/molIMobTakebe, 1983gas phase; M

(Lithium ion (1+) bullet 2Dimethyl ether) + Dimethyl ether = (Lithium ion (1+) bullet 3Dimethyl ether)

By formula: (Li+ bullet 2C2H6O) + C2H6O = (Li+ bullet 3C2H6O)

Quantity Value Units Method Reference Comment
Deltar21.3 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
26.3 (+1.4,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

(Lithium ion (1+) bullet 3Dimethyl ether) + Dimethyl ether = (Lithium ion (1+) bullet 4Dimethyl ether)

By formula: (Li+ bullet 3C2H6O) + C2H6O = (Li+ bullet 4C2H6O)

Quantity Value Units Method Reference Comment
Deltar16.3 ± 2.4kcal/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
22.8 (+1.6,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

(Lithium ion (1+) bullet Dimethyl ether) + Dimethyl ether = (Lithium ion (1+) bullet 2Dimethyl ether)

By formula: (Li+ bullet C2H6O) + C2H6O = (Li+ bullet 2C2H6O)

Quantity Value Units Method Reference Comment
Deltar28.9 ± 1.4kcal/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
31.1 (+0.9,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

Lithium ion (1+) + Acetaldehyde = (Lithium ion (1+) bullet Acetaldehyde)

By formula: Li+ + C2H4O = (Li+ bullet C2H4O)

Quantity Value Units Method Reference Comment
Deltar41.3kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, Keesee and Castleman, 1986 from Berman and Beauchamp, 1986; Dzidic and Kebarle, 1970 interpolated; M

(Lithium ion (1+) bullet 2Ammonia) + Ammonia = (Lithium ion (1+) bullet 3Ammonia)

By formula: (Li+ bullet 2H3N) + H3N = (Li+ bullet 3H3N)

Quantity Value Units Method Reference Comment
Deltar21.0kcal/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
Deltar25.3cal/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

(Lithium ion (1+) bullet 3Ammonia) + Ammonia = (Lithium ion (1+) bullet 4Ammonia)

By formula: (Li+ bullet 3H3N) + H3N = (Li+ bullet 4H3N)

Quantity Value Units Method Reference Comment
Deltar16.5kcal/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
Deltar32.6cal/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

(Lithium ion (1+) bullet 4Ammonia) + Ammonia = (Lithium ion (1+) bullet 5Ammonia)

By formula: (Li+ bullet 4H3N) + H3N = (Li+ bullet 5H3N)

Quantity Value Units Method Reference Comment
Deltar11.1kcal/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
Deltar28.0cal/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

(Lithium ion (1+) bullet 5Ammonia) + Ammonia = (Lithium ion (1+) bullet 6Ammonia)

By formula: (Li+ bullet 5H3N) + H3N = (Li+ bullet 6H3N)

Quantity Value Units Method Reference Comment
Deltar9.3kcal/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
Deltar25.3cal/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

(Lithium ion (1+) bullet Ammonia) + Ammonia = (Lithium ion (1+) bullet 2Ammonia)

By formula: (Li+ bullet H3N) + H3N = (Li+ bullet 2H3N)

Quantity Value Units Method Reference Comment
Deltar33.1kcal/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
Deltar29.7cal/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

Lithium ion (1+) + Propane, 2-fluoro- = (Lithium ion (1+) bullet Propane, 2-fluoro-)

By formula: Li+ + C3H7F = (Li+ bullet C3H7F)

Quantity Value Units Method Reference Comment
Deltar35.5kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Cyclohexane = (Lithium ion (1+) bullet Cyclohexane)

By formula: Li+ + C6H12 = (Li+ bullet C6H12)

Quantity Value Units Method Reference Comment
Deltar24.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Propene = (Lithium ion (1+) bullet Propene)

By formula: Li+ + C3H6 = (Li+ bullet C3H6)

Quantity Value Units Method Reference Comment
Deltar23.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + 1-Propene, 2-methyl- = (Lithium ion (1+) bullet 1-Propene, 2-methyl-)

By formula: Li+ + C4H8 = (Li+ bullet C4H8)

Quantity Value Units Method Reference Comment
Deltar28.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Ethane, fluoro- = (Lithium ion (1+) bullet Ethane, fluoro-)

By formula: Li+ + C2H5F = (Li+ bullet C2H5F)

Quantity Value Units Method Reference Comment
Deltar34.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Methyl fluoride = (Lithium ion (1+) bullet Methyl fluoride)

By formula: Li+ + CH3F = (Li+ bullet CH3F)

Quantity Value Units Method Reference Comment
Deltar31.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Acetic acid = (Lithium ion (1+) bullet Acetic acid)

By formula: Li+ + C2H4O2 = (Li+ bullet C2H4O2)

Quantity Value Units Method Reference Comment
Deltar41.5kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Acetone = (Lithium ion (1+) bullet Acetone)

By formula: Li+ + C3H6O = (Li+ bullet C3H6O)

Quantity Value Units Method Reference Comment
Deltar44.5kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Propyne = (Lithium ion (1+) bullet Propyne)

By formula: Li+ + C3H4 = (Li+ bullet C3H4)

Quantity Value Units Method Reference Comment
Deltar28.5kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Difluoromethane = (Lithium ion (1+) bullet Difluoromethane)

By formula: Li+ + CH2F2 = (Li+ bullet CH2F2)

Quantity Value Units Method Reference Comment
Deltar26.5kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Dimethyl sulfide = (Lithium ion (1+) bullet Dimethyl sulfide)

By formula: Li+ + C2H6S = (Li+ bullet C2H6S)

Quantity Value Units Method Reference Comment
Deltar32.8kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Propane, 2-bromo- = (Lithium ion (1+) bullet Propane, 2-bromo-)

By formula: Li+ + C3H7Br = (Li+ bullet C3H7Br)

Quantity Value Units Method Reference Comment
Deltar30.5kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Propane, 2-iodo- = (Lithium ion (1+) bullet Propane, 2-iodo-)

By formula: Li+ + C3H7I = (Li+ bullet C3H7I)

Quantity Value Units Method Reference Comment
Deltar29.5kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Formamide, N,N-dimethyl- = (Lithium ion (1+) bullet Formamide, N,N-dimethyl-)

By formula: Li+ + C3H7NO = (Li+ bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar50.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Chloromethane = (Lithium ion (1+) bullet Chloromethane)

By formula: Li+ + CH3Cl = (Li+ bullet CH3Cl)

Quantity Value Units Method Reference Comment
Deltar25.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Acetonitrile = (Lithium ion (1+) bullet Acetonitrile)

By formula: Li+ + C2H3N = (Li+ bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar43.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Methylene chloride = (Lithium ion (1+) bullet Methylene chloride)

By formula: Li+ + CH2Cl2 = (Li+ bullet CH2Cl2)

Quantity Value Units Method Reference Comment
Deltar29.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Propane, 2-chloro- = (Lithium ion (1+) bullet Propane, 2-chloro-)

By formula: Li+ + C3H7Cl = (Li+ bullet C3H7Cl)

Quantity Value Units Method Reference Comment
Deltar30.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Acetic acid, methyl ester = (Lithium ion (1+) bullet Acetic acid, methyl ester)

By formula: Li+ + C3H6O2 = (Li+ bullet C3H6O2)

Quantity Value Units Method Reference Comment
Deltar44.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Methane, nitro- = (Lithium ion (1+) bullet Methane, nitro-)

By formula: Li+ + CH3NO2 = (Li+ bullet CH3NO2)

Quantity Value Units Method Reference Comment
Deltar39.5kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970; M

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Woodin and Beauchamp, 1978
Woodin, R.L.; Beauchamp, J.L., Bonding of Li+ to Lewis Bases in the Gas Phase. Reversals in Methyl Substituent Effects for Different Reference Acids, J. Am. Chem. Soc., 1978, 100, 2, 501, https://doi.org/10.1021/ja00470a024 . [all data]

Dzidic and Kebarle, 1970
Dzidic, I.; Kebarle, P., Hydration of the Alkali Ions in the Gas Phase. Enthalpies and Entropies of Reactions M+(H2O)n-1 + H2O = M+(H2O)n, J. Phys. Chem., 1970, 74, 7, 1466, https://doi.org/10.1021/j100702a013 . [all data]

Staley and Beauchamp, 1975
Staley, R.H.; Beauchamp, J.L., Intrinsic Acid - Base Properties of Molecules. Binding Energies of Li+ to pi - and n - Donor Bases, J. Am. Chem. Soc., 1975, 97, 20, 5920, https://doi.org/10.1021/ja00853a050 . [all data]

More, Gledening, et al., 1996
More, M.B.; Gledening, E.D.; Ray, D.; Feller, D.; Armentrout, P.B., Cation-Ether Complexes in the Gas Phase: Bond Dissociation Energies and Equilibrium Structures of Li+[O(CH3)2]x, x=1-4, J. Phys. Chem., 1996, 100, 5, 1605, https://doi.org/10.1021/jp9523175 . [all data]

McKnight and Sawina, 1973
McKnight, L.G.; Sawina, J.M., Equilibrium Constants and Binding Energies of Alkali Metal Ions with Inert Gases, Bull. Am. Phys. Soc., 1973, 18, 804. [all data]

Cassidy and Elford, 1985
Cassidy, R.A.; Elford, M.T., The Mobility of Li+ Ions in Helium and Argon, Aust. J. Phys., 1985, 38, 4, 587, https://doi.org/10.1071/PH850587 . [all data]

Keller, Beyer, et al., 1973
Keller, C.E.; Beyer, R.A.; Colonna-Romano, L.M., Clustering of Ar to Li+ and a Comparison of Drift - Tube Models, Phys. Rev. A, 1973, 8, 3, 1446, https://doi.org/10.1103/PhysRevA.8.1446 . [all data]

Amicangelo and Armentrout, 2000
Amicangelo, J.C.; Armentrout, P.B., Absolute Binding Energies of Alkali-Metal Cation Complexes with Benzene Determined by Threshold Collision-Induced Dissociation Experiments and Ab Initio Theory, J. Phys. Chem. A, 2000, 104, 48, 11420, https://doi.org/10.1021/jp002652f . [all data]

Blades, Jayaweera, et al., 1990
Blades, A.T.; Jayaweera, P.; Ikonomou, M.G.; Kebarle, P., Studies of Alkaline - Earth and Transition - Metal M++ Gas - Phase Ion Chemistry, J. Chem. Phys., 1990, 92, 10, 5900, https://doi.org/10.1063/1.458360 . [all data]

Gatland, 1984
Gatland, I.R., Swarms of Ions and Electrons in Gases, W. Lindinger, T. D. Mark and F. Howorka, eds. (Springer, New York, 1984, 1984, 44. [all data]

Gislason, 1984
Gislason, E.A., Quoted in I. R. Gatland in Swarms of Ions and Electrons in Gases, W. Lindinger, T. D. Mark and F. Howorka, eds. (Springer, New York, 1984, 1984, 44. [all data]

Viehland, 1984
Viehland, L.A., Interaction Potentials for Li+ - Rare - Gas Systems, Chem. Phys., 1984, 78, 2, 279, https://doi.org/10.1016/0301-0104(83)85114-3 . [all data]

Mason and Sharp, 1958
Mason, E.A.; Sharp, H.W., Mobility of gaseous lons in weak electric fields, Ann. Phys., 1958, 4, 3, 233, https://doi.org/10.1016/0003-4916(58)90049-6 . [all data]

Takebe, 1983
Takebe, M., The Generalized Mobility Curve for Alkali Ions in Rare Gases: Clustering Reactions and Mobility Curves, J. Chem. Phys., 1983, 78, 12, 7223, https://doi.org/10.1063/1.444763 . [all data]

Colonna-Romano and Keller, 1976
Colonna-Romano, L.M.; Keller, G.E., The Clustering of O2 and He to Li+, J. Chem. Phys., 1976, 64, 6, 2684, https://doi.org/10.1063/1.432522 . [all data]

Amunugama and Rodgers, 2000
Amunugama, R.; Rodgers, M.T., Absolute Alkali Metal Ion Binding Affinities of Several Azines Determined by Threshold Collision-Induced Dissociation and Ab Initio Theory, Int. J. Mass Spectrom., 2000, 195/196, 439, https://doi.org/10.1016/S1387-3806(99)00145-1 . [all data]

Keesee and Castleman, 1986
Keesee, R.G.; Castleman, A.W., Jr., Thermochemical data on Ggs-phase ion-molecule association and clustering reactions, J. Phys. Chem. Ref. Data, 1986, 15, 1011. [all data]

Berman and Beauchamp, 1986
Berman, D.W.; Beauchamp, J.L., Quoted in Keesee and Castleman, 1986, 1986. [all data]

Castleman, Holland, et al., 1978
Castleman, A.W.; Holland, P.M.; Lindsay, D.M.; Peterson, K.I., The Properties of Clusters in the Gas Phase. 2. Ammonia about Metal Ions, J. Am. Chem. Soc., 1978, 100, 19, 6039, https://doi.org/10.1021/ja00487a011 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, References