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C6H5+


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   a


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 CH stretch 2790 ± 100 gas PE Butcher, Costa, et al., 1987

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 CH stretch 3117 A gas PF Patzer, Chakraborty, et al., 2010
1 CH stretch 3115 A gas PF Patzer, Chakraborty, et al., 2010
2 CH stretch 3090 A gas PF Patzer, Chakraborty, et al., 2010
2 CH stretch 3089 A gas PF Patzer, Chakraborty, et al., 2010
3 CH stretch 3055 A gas PF Patzer, Chakraborty, et al., 2010
3 CH stretch 3057 A gas PF Patzer, Chakraborty, et al., 2010
b1 CH deform. 713 Ar IR Winkler and Sander, 2000
b2 19 CH stretch 3111 A gas PF Patzer, Chakraborty, et al., 2010
19 CH stretch 3109 A gas PF Patzer, Chakraborty, et al., 2010
19 CH stretch 3110 Ar IR Winkler and Sander, 2000
Winkler and Sander, 2006
20 CH stretch 3063 A gas PF Patzer, Chakraborty, et al., 2010
20 CH stretch 3063 A gas PF Patzer, Chakraborty, et al., 2010

Additional references: Jacox, 1994, page 387; Jacox, 2003, page 367

Notes

A0~1 cm-1 uncertainty

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Butcher, Costa, et al., 1987
Butcher, V.; Costa, M.L.; Dyke, J.M.; Ellis, A.R.; Morris, A., A study of the phenyl radical by vacuum ultraviolet photoelectron spectroscopy, Chem. Phys., 1987, 115, 261. [all data]

Patzer, Chakraborty, et al., 2010
Patzer, A.; Chakraborty, S.; Solca, N.; Dopfer, O., IR Spectrum and Structure of the Phenyl Cation, Angew. Chem. Int. Ed., 2010, 49, 52, 10145, https://doi.org/10.1002/anie.201006357 . [all data]

Winkler and Sander, 2000
Winkler, M.; Sander, W., Isolation of the Phenyl Cation in a Solid Argon Matrix, Angew. Chem. Int. Ed., 2000, 39, 11, 2014, https://doi.org/10.1002/1521-3773(20000602)39:11<2014::AID-ANIE2014>3.0.CO;2-E . [all data]

Winkler and Sander, 2006
Winkler, M.; Sander, W., Generation and Reactivity of the Phenyl Cation in Cryogenic Argon Matrices: Monitoring the Reactions with Nitrogen and Carbon Monoxide Directly by IR Spectroscopy, J. Org. Chem., 2006, 71, 17, 6357, https://doi.org/10.1021/jo0603678 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

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