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MeS anion


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

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Clustering reactions

(MeS anion bullet 4294967295Thioformaldehyde) + Thioformaldehyde = MeS anion

By formula: (CH3S- bullet 4294967295CH2S) + CH2S = CH3S-

Quantity Value Units Method Reference Comment
Deltar73.0 ± 3.8kcal/molN/ABartmess, Scott, et al., 1979gas phase; value altered from reference due to change in acidity scale; B

MeS anion + Isopropyl Alcohol = (MeS anion bullet Isopropyl Alcohol)

By formula: CH3S- + C3H8O = (CH3S- bullet C3H8O)

Quantity Value Units Method Reference Comment
Deltar17.10 ± 0.20kcal/molTDAsSieck and Meot-ner, 1989gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar23.1cal/mol*KPHPMSSieck and Meot-ner, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar10.20 ± 0.80kcal/molTDAsSieck and Meot-ner, 1989gas phase; B

MeS anion + Water = (MeS anion bullet Water)

By formula: CH3S- + H2O = (CH3S- bullet H2O)

Quantity Value Units Method Reference Comment
Deltar15.00 ± 0.20kcal/molTDAsSieck and Meot-ner, 1989gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar21.2cal/mol*KPHPMSSieck and Meot-ner, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar8.70 ± 0.70kcal/molTDAsSieck and Meot-ner, 1989gas phase; B

(MeS anion bullet Water) + Water = (MeS anion bullet 2Water)

By formula: (CH3S- bullet H2O) + H2O = (CH3S- bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar13.5kcal/molPHPMSSieck and Meot-ner, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar23.5cal/mol*KPHPMSSieck and Meot-ner, 1989gas phase; M

(MeS anion bullet 2Water) + Water = (MeS anion bullet 3Water)

By formula: (CH3S- bullet 2H2O) + H2O = (CH3S- bullet 3H2O)

Quantity Value Units Method Reference Comment
Deltar11.1kcal/molPHPMSSieck and Meot-ner, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar20.5cal/mol*KPHPMSSieck and Meot-ner, 1989gas phase; M

(MeS anion bullet 3Water) + Water = (MeS anion bullet 4Water)

By formula: (CH3S- bullet 3H2O) + H2O = (CH3S- bullet 4H2O)

Quantity Value Units Method Reference Comment
Deltar9.6kcal/molPHPMSSieck and Meot-ner, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar19.2cal/mol*KPHPMSSieck and Meot-ner, 1989gas phase; M

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bartmess, Scott, et al., 1979
Bartmess, J.E.; Scott, J.A.; McIver, R.T., Jr., The gas phase acidity scale from methanol to phenol, J. Am. Chem. Soc., 1979, 101, 6047. [all data]

Sieck and Meot-ner, 1989
Sieck, L.W.; Meot-ner, M., Ionic Hydrogen Bond and Ion Solvation. 8. RS-..HOR Bond Strengths. Correlation with Acidities., J. Phys. Chem., 1989, 93, 4, 1586, https://doi.org/10.1021/j100341a079 . [all data]


Notes

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