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Oxacyclotetradecan-2-one

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-644. ± 2.kJ/molCmWiberg and Waldron, 1991Heat of reduction, Hfusion=1.72 kcal/mol; ALS
Quantity Value Units Method Reference Comment
Deltafsolid-648.1 ± 2.9kJ/molCcbLebedev, Yevstropov, et al., 1981ALS
Quantity Value Units Method Reference Comment
Deltacsolid-7895.3 ± 2.9kJ/molCcbLebedev, Yevstropov, et al., 1981Corresponding «DELTA»fsolid = -650.3 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
solid,1 bar401.8J/mol*KN/ALebedev, Evstropov, et al., 1981DH
solid,1 bar401.9J/mol*KN/ALebedev, Yevstropov, et al., 1981, 2DH

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
398.3298.15Lebedev, Evstropov, et al., 1981T = 5 to 400 K.; DH
398.3298.15Lebedev, Yevstropov, et al., 1981, 2T = 10.3 to 330 K.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wiberg and Waldron, 1991
Wiberg, K.B.; Waldron, R.F., Lactones. 2. Enthalpies of hydrolysis, reduction, and formation of the C4-C13 monocyclic lactones. strain energies and conformations, J. Am. Chem. Soc., 1991, 113, 7697-7705. [all data]

Lebedev, Yevstropov, et al., 1981
Lebedev, B.V.; Yevstropov, A.A.; Kiparisova, Ye.G., Thermodynamics of undecanolactone, tridecanolactone, and pentadecanolactone from 0 to 340 K, J. Chem. Thermodyn., 1981, 13, 1185-1204. [all data]

Lebedev, Evstropov, et al., 1981
Lebedev, B.V.; Evstropov, A.A.; Kiparisova, Y.G.; Sheveleva, N.P., Thermodynamics of tridecanolactone, its polymerization process, and the resultant poly(tridecanolactone) in the 0-430 K range, Vysokomol. Soedin., 1981, B23, 551-554. [all data]

Lebedev, Yevstropov, et al., 1981, 2
Lebedev, B.V.; Yevstropov, A.A.; Kiparisova, Y.G., Thermodynamic properties of undecanolactone over the range, 1981, Termodin. [all data]


Notes

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