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barium hydroxide


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Deltafgas-149.75kcal/molReviewChase, 1998Data last reviewed in December, 1975
Quantity Value Units Method Reference Comment
gas,1 bar75.301cal/mol*KReviewChase, 1998Data last reviewed in December, 1975

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 2000. - 6000.
A 19.56914
B 3.426793
C -0.686078
D 0.047222
E -0.177017
F -156.3239
G 96.99594
H -149.7519
ReferenceChase, 1998
Comment Data last reviewed in December, 1975

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Deltafliquid-223.26kcal/molReviewChase, 1998Data last reviewed in December, 1975
Quantity Value Units Method Reference Comment
liquid,1 bar29.481cal/mol*KReviewChase, 1998Data last reviewed in December, 1975
Quantity Value Units Method Reference Comment
Deltafsolid-226.17kcal/molReviewChase, 1998«alpha» phase; Data last reviewed in December, 1975

Liquid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 681.15 - 2000.
A 33.70005
B -0.000001
C 0.000001
D -3.103299×10-7
E 1.385588×10-8
F -234.4367
G 67.15846
H -223.2608
ReferenceChase, 1998
Comment Data last reviewed in December, 1975

Solid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. - 681.
A 11.38009
B 79.44885
C -124.8635
D 72.34704
E -0.142910
F -232.6133
G 19.79089
H -226.1699
ReferenceChase, 1998
Comment «alpha» phase; Data last reviewed in December, 1975

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference
8. ± 1.EIFarber and Srivastava, 1981

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

OH stretch 3723 Ne IR Wang and Andrews, 2005
OH stretch 3724.2 Ar IR Andrews and Wang, 2005
Wang and Andrews, 2005
OH stretch 3718 H2 IR Wang and Andrews, 2005
BaO a-stretch 422.8 Ar IR Kauffman, Hauge, et al., 1984
Andrews and Wang, 2005
Wang and Andrews, 2005
BaO a-stretch 410 H2 IR Wang and Andrews, 2005

Additional references: Jacox, 1994, page 251


References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Farber and Srivastava, 1981
Farber, M.; Srivastava, R.D., Electron impact ionization of Ba(OH)2 (g), J. Chem. Phys., 1981, 74, 2160. [all data]

Wang and Andrews, 2005
Wang, X.; Andrews, L., Infrared Spectra and Electronic Structure Calculations for the Group 2 Metal M(OH), J. Phys. Chem. A, 2005, 109, 12, 2782, https://doi.org/10.1021/jp044660s . [all data]

Andrews and Wang, 2005
Andrews, L.; Wang, X., Infrared Spectra of the Group 2 Metal Dihydroxide Molecules, Inorg. Chem., 2005, 44, 1, 11, https://doi.org/10.1021/ic0483794 . [all data]

Kauffman, Hauge, et al., 1984
Kauffman, J.W.; Hauge, R.H.; Margrave, J.L., High Temp. Sci., 1984, 18, 97. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

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