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Nitric acid, 1-methylethyl ester

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil373.7KN/AWeast and Grasselli, 1989BS
Quantity Value Units Method Reference Comment
Ttriple190.81KN/ALushnikov, Rubstov, et al., 1988Uncertainty assigned by TRC = 0.02 K; TRC
Quantity Value Units Method Reference Comment
Deltavap38.79kJ/molVGray and Pratt, 1957ALS

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
39.7288.AStephenson and Malanowski, 1987Based on data from 273. - 343. K. See also Gray and Pratt, 1957, 2 and Dykyj, 1970.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
273. - 343.3.544961018.568-89.622Gray and Pratt, 1957, 3Coefficents calculated by NIST from author's data.

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
10.010190.81Lushnikov, Rubtsov, et al., 1988DH
10.1190.9Lushnikov, Rubstov, et al., 1988AC

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
52.43190.81Lushnikov, Rubtsov, et al., 1988DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Lushnikov, Rubstov, et al., 1988
Lushnikov, V.N.; Rubstov, Y.I.; Dremenko, L.T.; Korolev, A.M., Zh. Fiz. Khim., 1988, 62, 1209. [all data]

Gray and Pratt, 1957
Gray, P.; Pratt, M.W.T., The latent heats of vaporization of the alkyl nitrates, J. Chem. Soc., 1957, 2163-21. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Gray and Pratt, 1957, 2
Gray, Peter; Pratt, M.W.T., 414. The latent heats of vaporization of the alkyl nitrates, J. Chem. Soc., 1957, 2163, https://doi.org/10.1039/jr9570002163 . [all data]

Dykyj, 1970
Dykyj, J., Petrochemica, 1970, 10, 2, 51. [all data]

Gray and Pratt, 1957, 3
Gray, P.; Pratt, M.W.T., The Latent Heats of Vaporization of the Alkyl Nitrates, J. Chem. Soc., 1957, 2163-2168, https://doi.org/10.1039/jr9570002163 . [all data]

Lushnikov, Rubtsov, et al., 1988
Lushnikov, V.N.; Rubtsov, Yu.I.; Eremenko, L.T.; Korolev, A.M., Specific heat and standard entropy of isopropyl nitrate, Zhur. Fiz. Khim., 1988, 62, 1209-1214. [all data]


Notes

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