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Nitric acid, 1-methylethyl ester

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-230. ± 1.kJ/molCcbFairbrother, Skinner, et al., 1957ALS
Deltafliquid-226.0 ± 2.0kJ/molCcbTavernier and Lamouroux, 1957Reanalyzed by Cox and Pilcher, 1970, Original value = -222.0 kJ/mol; Author's hf298_condensed=-54.619 kcal/mol; ALS
Quantity Value Units Method Reference Comment
Deltacliquid-1951. ± 1.kJ/molCcbFairbrother, Skinner, et al., 1957ALS
Deltacliquid-1954.9 ± 2.0kJ/molCcbTavernier and Lamouroux, 1957Reanalyzed by Cox and Pilcher, 1970, Original value = -1958.97 kJ/mol; Author's hf298_condensed=-54.619 kcal/mol; ALS
Quantity Value Units Method Reference Comment
liquid263.2J/mol*KN/ALushnikov, Rubtsov, et al., 1988DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
200.7350.Bunyan, 1988DH
191.1298.15Lushnikov, Rubtsov, et al., 1988T = 14 to 300 K.; DH

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Isopropyl Alcohol + Nitric acid = Nitric acid, 1-methylethyl ester + Water

By formula: C3H8O + HNO3 = C3H7NO3 + H2O

Quantity Value Units Method Reference Comment
Deltar-23.4kJ/molEqkRubtsov, 1986liquid phase

References

Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Fairbrother, Skinner, et al., 1957
Fairbrother, D.M.; Skinner, H.A.; Evans, F.W., The heats of combustion of organic compounds of nitrogen, Trans. Faraday Soc., 1957, 53, 779-783. [all data]

Tavernier and Lamouroux, 1957
Tavernier, P.; Lamouroux, M., Determinations calorimetriques relatives a vingt et une substances organiques, Mem. Poudres, 1957, 39, 335-356. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Lushnikov, Rubtsov, et al., 1988
Lushnikov, V.N.; Rubtsov, Yu.I.; Eremenko, L.T.; Korolev, A.M., Specific heat and standard entropy of isopropyl nitrate, Zhur. Fiz. Khim., 1988, 62, 1209-1214. [all data]

Bunyan, 1988
Bunyan, P.F., A technique to measure the specific heat of reactive materials by heat flow calorimetry, Thermochim. Acta, 1988, 130, 335-344. [all data]

Rubtsov, 1986
Rubtsov, Yu.I., Thermodynamic calculation of equilibrium in nitration of alcohols, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1986, 19-22. [all data]


Notes

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