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Propane, 1,3-dimethoxy-


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

CH6N+ + Propane, 1,3-dimethoxy- = (CH6N+ bullet Propane, 1,3-dimethoxy-)

By formula: CH6N+ + C5H12O2 = (CH6N+ bullet C5H12O2)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar31.2kcal/molPHPMSMeot-Ner, 1984gas phase
Deltar31.2kcal/molPHPMSMeot-Ner (Mautner), 1983gas phase
Quantity Value Units Method Reference Comment
Deltar32.0cal/mol*KPHPMSMeot-Ner, 1984gas phase
Deltar32.0cal/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase

C3H10N+ + Propane, 1,3-dimethoxy- = (C3H10N+ bullet Propane, 1,3-dimethoxy-)

By formula: C3H10N+ + C5H12O2 = (C3H10N+ bullet C5H12O2)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar25.5kcal/molPHPMSMeot-Ner (Mautner), 1983gas phase
Quantity Value Units Method Reference Comment
Deltar33.1cal/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase

C5H5FN+ + Propane, 1,3-dimethoxy- = (C5H5FN+ bullet Propane, 1,3-dimethoxy-)

By formula: C5H5FN+ + C5H12O2 = (C5H5FN+ bullet C5H12O2)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar26.2kcal/molPHPMSMeot-Ner (Mautner), 1983gas phase
Quantity Value Units Method Reference Comment
Deltar31.6cal/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase

C5H6N+ + Propane, 1,3-dimethoxy- = (C5H6N+ bullet Propane, 1,3-dimethoxy-)

By formula: C5H6N+ + C5H12O2 = (C5H6N+ bullet C5H12O2)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar26.5kcal/molPHPMSMeot-Ner (Mautner), 1983gas phase
Quantity Value Units Method Reference Comment
Deltar35.8cal/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase

C6H14N+ + Propane, 1,3-dimethoxy- = (C6H14N+ bullet Propane, 1,3-dimethoxy-)

By formula: C6H14N+ + C5H12O2 = (C6H14N+ bullet C5H12O2)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar28.4kcal/molPHPMSMeot-Ner (Mautner), 1983gas phase
Quantity Value Units Method Reference Comment
Deltar35.0cal/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, Ion clustering data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard

Quantity Value Units Method Reference Comment
Proton affinity (review)214.4kcal/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity205.2kcal/molN/AHunter and Lias, 1998HL

Ionization energy determinations

IE (eV) Method Reference Comment
9.3PEBiermann and Morton, 1983LBLHLM
9.68PEBiermann and Morton, 1983Vertical value; LBLHLM

Ion clustering data

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

CH6N+ + Propane, 1,3-dimethoxy- = (CH6N+ bullet Propane, 1,3-dimethoxy-)

By formula: CH6N+ + C5H12O2 = (CH6N+ bullet C5H12O2)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar31.2kcal/molPHPMSMeot-Ner, 1984gas phase
Deltar31.2kcal/molPHPMSMeot-Ner (Mautner), 1983gas phase
Quantity Value Units Method Reference Comment
Deltar32.0cal/mol*KPHPMSMeot-Ner, 1984gas phase
Deltar32.0cal/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase

C3H10N+ + Propane, 1,3-dimethoxy- = (C3H10N+ bullet Propane, 1,3-dimethoxy-)

By formula: C3H10N+ + C5H12O2 = (C3H10N+ bullet C5H12O2)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar25.5kcal/molPHPMSMeot-Ner (Mautner), 1983gas phase
Quantity Value Units Method Reference Comment
Deltar33.1cal/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase

C5H5FN+ + Propane, 1,3-dimethoxy- = (C5H5FN+ bullet Propane, 1,3-dimethoxy-)

By formula: C5H5FN+ + C5H12O2 = (C5H5FN+ bullet C5H12O2)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar26.2kcal/molPHPMSMeot-Ner (Mautner), 1983gas phase
Quantity Value Units Method Reference Comment
Deltar31.6cal/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase

C5H6N+ + Propane, 1,3-dimethoxy- = (C5H6N+ bullet Propane, 1,3-dimethoxy-)

By formula: C5H6N+ + C5H12O2 = (C5H6N+ bullet C5H12O2)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar26.5kcal/molPHPMSMeot-Ner (Mautner), 1983gas phase
Quantity Value Units Method Reference Comment
Deltar35.8cal/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase

C6H14N+ + Propane, 1,3-dimethoxy- = (C6H14N+ bullet Propane, 1,3-dimethoxy-)

By formula: C6H14N+ + C5H12O2 = (C6H14N+ bullet C5H12O2)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar28.4kcal/molPHPMSMeot-Ner (Mautner), 1983gas phase
Quantity Value Units Method Reference Comment
Deltar35.0cal/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase

Mass spectrum (electron ionization)

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Chemical Concepts
NIST MS number 150331

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References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meot-Ner, 1984
Meot-Ner, (Mautner)M., The Ionic Hydrogen Bond and Ion Solvation. 1. -NH+ O-, -NH+ N- and -OH+ O- Bonds. Correlations with Proton Affinity. Deviations Due to Structural Effects, J. Am. Chem. Soc., 1984, 106, 5, 1257, https://doi.org/10.1021/ja00317a015 . [all data]

Meot-Ner (Mautner), 1983
Meot-Ner (Mautner), M., The Ionic Hydrogen Bond. 3. Multiple and -CH+...O- Bonds. Complexes of Ammonium Ions with Polyethers and Crown Ethers, J. Am. Chem. Soc., 1983, 105, 15, 4912, https://doi.org/10.1021/ja00353a012 . [all data]

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Biermann and Morton, 1983
Biermann, H.W.; Morton, T.H., Reversible tautomerization of radical cations. Photoionization of 2-methoxyethanol and 3-methoxy-1-propanol, J. Am. Chem. Soc., 1983, 105, 5025. [all data]


Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Mass spectrum (electron ionization), References