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Formyl cation


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Formyl cation + Carbon monoxide = (Formyl cation bullet Carbon monoxide)

By formula: CHO+ + CO = (CHO+ bullet CO)

Quantity Value Units Method Reference Comment
Deltar45.2kJ/molPHPMSJennings, Headley, et al., 1982gas phase
Deltar53.6kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase
Deltar49.0kJ/molPHPMSMeot-Ner (Mautner) and Field, 1974gas phase
Quantity Value Units Method Reference Comment
Deltar94.1J/mol*KPHPMSJennings, Headley, et al., 1982gas phase
Deltar100.J/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase
Deltar87.4J/mol*KPHPMSMeot-Ner (Mautner) and Field, 1974gas phase

(Formyl cation bullet Carbon monoxide) + Carbon monoxide = (Formyl cation bullet 2Carbon monoxide)

By formula: (CHO+ bullet CO) + CO = (CHO+ bullet 2CO)

Quantity Value Units Method Reference Comment
Deltar20. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase
Deltar28.kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase
Quantity Value Units Method Reference Comment
Deltar62.8J/mol*KPHPMSHiraoka and Mori, 1989gas phase
Deltar100.J/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase

(Formyl cation bullet 2Carbon monoxide) + Carbon monoxide = (Formyl cation bullet 3Carbon monoxide)

By formula: (CHO+ bullet 2CO) + CO = (CHO+ bullet 3CO)

Quantity Value Units Method Reference Comment
Deltar19. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase
Deltar26.kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase
Quantity Value Units Method Reference Comment
Deltar66.1J/mol*KPHPMSHiraoka and Mori, 1989gas phase
Deltar110.J/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase

(Formyl cation bullet 3Carbon monoxide) + Carbon monoxide = (Formyl cation bullet 4Carbon monoxide)

By formula: (CHO+ bullet 3CO) + CO = (CHO+ bullet 4CO)

Quantity Value Units Method Reference Comment
Deltar19. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase
Deltar26.kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase
Quantity Value Units Method Reference Comment
Deltar76.1J/mol*KPHPMSHiraoka and Mori, 1989gas phase
Deltar120.J/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase

(Formyl cation bullet 4Carbon monoxide) + Carbon monoxide = (Formyl cation bullet 5Carbon monoxide)

By formula: (CHO+ bullet 4CO) + CO = (CHO+ bullet 5CO)

Quantity Value Units Method Reference Comment
Deltar18. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase
Deltar24.kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase
Quantity Value Units Method Reference Comment
Deltar95.8J/mol*KPHPMSHiraoka and Mori, 1989gas phase
Deltar130.J/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase

(Formyl cation bullet 5Carbon monoxide) + Carbon monoxide = (Formyl cation bullet 6Carbon monoxide)

By formula: (CHO+ bullet 5CO) + CO = (CHO+ bullet 6CO)

Quantity Value Units Method Reference Comment
Deltar10. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar79.5J/mol*KPHPMSHiraoka and Mori, 1989gas phase

(Formyl cation bullet 6Carbon monoxide) + Carbon monoxide = (Formyl cation bullet 7Carbon monoxide)

By formula: (CHO+ bullet 6CO) + CO = (CHO+ bullet 7CO)

Quantity Value Units Method Reference Comment
Deltar9. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar88.3J/mol*KPHPMSHiraoka and Mori, 1989gas phase

(Formyl cation bullet 7Carbon monoxide) + Carbon monoxide = (Formyl cation bullet 8Carbon monoxide)

By formula: (CHO+ bullet 7CO) + CO = (CHO+ bullet 8CO)

Quantity Value Units Method Reference Comment
Deltar9. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar92.0J/mol*KPHPMSHiraoka and Mori, 1989gas phase

(Formyl cation bullet 8Carbon monoxide) + Carbon monoxide = (Formyl cation bullet 9Carbon monoxide)

By formula: (CHO+ bullet 8CO) + CO = (CHO+ bullet 9CO)

Quantity Value Units Method Reference Comment
Deltar9. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar94.6J/mol*KPHPMSHiraoka and Mori, 1989gas phase

(Formyl cation bullet 9Carbon monoxide) + Carbon monoxide = (Formyl cation bullet 10Carbon monoxide)

By formula: (CHO+ bullet 9CO) + CO = (CHO+ bullet 10CO)

Quantity Value Units Method Reference Comment
Deltar8. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar93.3J/mol*KPHPMSHiraoka and Mori, 1989gas phase

(Formyl cation bullet 10Carbon monoxide) + Carbon monoxide = (Formyl cation bullet 11Carbon monoxide)

By formula: (CHO+ bullet 10CO) + CO = (CHO+ bullet 11CO)

Quantity Value Units Method Reference Comment
Deltar8. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar96.2J/mol*KPHPMSHiraoka and Mori, 1989gas phase

(Formyl cation bullet 11Carbon monoxide) + Carbon monoxide = (Formyl cation bullet 12Carbon monoxide)

By formula: (CHO+ bullet 11CO) + CO = (CHO+ bullet 12CO)

Quantity Value Units Method Reference Comment
Deltar8. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar97.1J/mol*KPHPMSHiraoka and Mori, 1989gas phase

(Formyl cation bullet 12Carbon monoxide) + Carbon monoxide = (Formyl cation bullet 13Carbon monoxide)

By formula: (CHO+ bullet 12CO) + CO = (CHO+ bullet 13CO)

Quantity Value Units Method Reference Comment
Deltar8. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar97.1J/mol*KPHPMSHiraoka and Mori, 1989gas phase

(Formyl cation bullet 13Carbon monoxide) + Carbon monoxide = (Formyl cation bullet 14Carbon monoxide)

By formula: (CHO+ bullet 13CO) + CO = (CHO+ bullet 14CO)

Quantity Value Units Method Reference Comment
Deltar7. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar96.7J/mol*KPHPMSHiraoka and Mori, 1989gas phase

(Formyl cation bullet 14Carbon monoxide) + Carbon monoxide = (Formyl cation bullet 15Carbon monoxide)

By formula: (CHO+ bullet 14CO) + CO = (CHO+ bullet 15CO)

Quantity Value Units Method Reference Comment
Deltar7.36kJ/molPHPMSHiraoka and Mori, 1989gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar96.J/mol*KN/AHiraoka and Mori, 1989gas phase; Entropy change calculated or estimated

Formyl cation + Carbon dioxide = (Formyl cation bullet Carbon dioxide)

By formula: CHO+ + CO2 = (CHO+ bullet CO2)

Quantity Value Units Method Reference Comment
Deltar52.7kJ/molPHPMSHiraoka, Shoda, et al., 1986gas phase
Quantity Value Units Method Reference Comment
Deltar89.5J/mol*KPHPMSHiraoka, Shoda, et al., 1986gas phase

(Formyl cation bullet Carbon dioxide) + Carbon dioxide = (Formyl cation bullet 2Carbon dioxide)

By formula: (CHO+ bullet CO2) + CO2 = (CHO+ bullet 2CO2)

Quantity Value Units Method Reference Comment
Deltar30.kJ/molPHPMSHiraoka, Shoda, et al., 1986gas phase
Quantity Value Units Method Reference Comment
Deltar82.4J/mol*KPHPMSHiraoka, Shoda, et al., 1986gas phase

(Formyl cation bullet 2Carbon dioxide) + Carbon dioxide = (Formyl cation bullet 3Carbon dioxide)

By formula: (CHO+ bullet 2CO2) + CO2 = (CHO+ bullet 3CO2)

Quantity Value Units Method Reference Comment
Deltar29.kJ/molPHPMSHiraoka, Shoda, et al., 1986gas phase
Quantity Value Units Method Reference Comment
Deltar95.0J/mol*KPHPMSHiraoka, Shoda, et al., 1986gas phase

(Formyl cation bullet 3Carbon dioxide) + Carbon dioxide = (Formyl cation bullet 4Carbon dioxide)

By formula: (CHO+ bullet 3CO2) + CO2 = (CHO+ bullet 4CO2)

Quantity Value Units Method Reference Comment
Deltar35.kJ/molPHPMSHiraoka, Shoda, et al., 1986gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KN/AHiraoka, Shoda, et al., 1986gas phase; Entropy change calculated or estimated

Formyl cation + Hydrogen = (Formyl cation bullet Hydrogen)

By formula: CHO+ + H2 = (CHO+ bullet H2)

Quantity Value Units Method Reference Comment
Deltar16.kJ/molPHPMSHiraoka and Kebarle, 1975gas phase
Quantity Value Units Method Reference Comment
Deltar85.8J/mol*KPHPMSHiraoka and Kebarle, 1975gas phase

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Jennings, Headley, et al., 1982
Jennings, K.R.; Headley, J.V.; Mason, R.S., The Temperature Dependence of Ion - Molecule Association Reactions, Int. J. Mass. Spectrom. Ion Phys, 1982, 45, 315. [all data]

Hiraoka, Saluja, et al., 1979
Hiraoka, K.; Saluja, P.P.S.; Kebarle, P., Stabilities of Complexes (N2)nH+, (CO)nH+ and (O2)nH+ for n = 1 to 7 Based on Gas Phase Ion Equilibrium Measurements, Can. J. Chem., 1979, 57, 16, 2159, https://doi.org/10.1139/v79-346 . [all data]

Meot-Ner (Mautner) and Field, 1974
Meot-Ner (Mautner), M.; Field, F.H., Kinetics and Thermodynamics of the Association of CO+ with CO and of N2+ with N2 between 120 and 650 K, J. Chem. Phys., 1974, 61, 9, 3742, https://doi.org/10.1063/1.1682560 . [all data]

Hiraoka and Mori, 1989
Hiraoka, K.; Mori, T., Gas Phase Stabilities of the Cluster Ions H+(CO)2(CO)n, H+(N2)2(N2)n and H+(O2)2(O2)n with n = 1 - 14, Chem. Phys., 1989, 137, 1-3, 345, https://doi.org/10.1016/0301-0104(89)87119-8 . [all data]

Hiraoka, Shoda, et al., 1986
Hiraoka, K.; Shoda, T.; Morise, K.; Yamabe, S.; Kawai, E.; Hirao, K., Stability and structure of cluster ions in the gas phase: Carbon dioxide with Cl-, H3O+, HCO2+ and HCO+, J. Chem. Phys., 1986, 84, 2091. [all data]

Hiraoka and Kebarle, 1975
Hiraoka, K.; Kebarle, P., Stability and Structure of H3CO+ Formed from COH+ + H2 at Low Temperature, J. Chem. Phys., 1975, 63, 4, 1688, https://doi.org/10.1063/1.431499 . [all data]


Notes

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