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Formyl cation


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Formyl cation + Carbon monoxide = (Formyl cation bullet Carbon monoxide)

By formula: CHO+ + CO = (CHO+ bullet CO)

Quantity Value Units Method Reference Comment
Deltar10.8kcal/molPHPMSJennings, Headley, et al., 1982gas phase
Deltar12.8kcal/molPHPMSHiraoka, Saluja, et al., 1979gas phase
Deltar11.7kcal/molPHPMSMeot-Ner (Mautner) and Field, 1974gas phase
Quantity Value Units Method Reference Comment
Deltar22.5cal/mol*KPHPMSJennings, Headley, et al., 1982gas phase
Deltar24.cal/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase
Deltar20.9cal/mol*KPHPMSMeot-Ner (Mautner) and Field, 1974gas phase

(Formyl cation bullet Carbon monoxide) + Carbon monoxide = (Formyl cation bullet 2Carbon monoxide)

By formula: (CHO+ bullet CO) + CO = (CHO+ bullet 2CO)

Quantity Value Units Method Reference Comment
Deltar4.9 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase
Deltar6.6kcal/molPHPMSHiraoka, Saluja, et al., 1979gas phase
Quantity Value Units Method Reference Comment
Deltar15.0cal/mol*KPHPMSHiraoka and Mori, 1989gas phase
Deltar24.cal/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase

(Formyl cation bullet 2Carbon monoxide) + Carbon monoxide = (Formyl cation bullet 3Carbon monoxide)

By formula: (CHO+ bullet 2CO) + CO = (CHO+ bullet 3CO)

Quantity Value Units Method Reference Comment
Deltar4.7 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase
Deltar6.3kcal/molPHPMSHiraoka, Saluja, et al., 1979gas phase
Quantity Value Units Method Reference Comment
Deltar15.8cal/mol*KPHPMSHiraoka and Mori, 1989gas phase
Deltar26.cal/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase

(Formyl cation bullet 3Carbon monoxide) + Carbon monoxide = (Formyl cation bullet 4Carbon monoxide)

By formula: (CHO+ bullet 3CO) + CO = (CHO+ bullet 4CO)

Quantity Value Units Method Reference Comment
Deltar4.5 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase
Deltar6.2kcal/molPHPMSHiraoka, Saluja, et al., 1979gas phase
Quantity Value Units Method Reference Comment
Deltar18.2cal/mol*KPHPMSHiraoka and Mori, 1989gas phase
Deltar29.cal/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase

(Formyl cation bullet 4Carbon monoxide) + Carbon monoxide = (Formyl cation bullet 5Carbon monoxide)

By formula: (CHO+ bullet 4CO) + CO = (CHO+ bullet 5CO)

Quantity Value Units Method Reference Comment
Deltar4.2 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase
Deltar5.8kcal/molPHPMSHiraoka, Saluja, et al., 1979gas phase
Quantity Value Units Method Reference Comment
Deltar22.9cal/mol*KPHPMSHiraoka and Mori, 1989gas phase
Deltar32.cal/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase

(Formyl cation bullet 5Carbon monoxide) + Carbon monoxide = (Formyl cation bullet 6Carbon monoxide)

By formula: (CHO+ bullet 5CO) + CO = (CHO+ bullet 6CO)

Quantity Value Units Method Reference Comment
Deltar2.4 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar19.0cal/mol*KPHPMSHiraoka and Mori, 1989gas phase

(Formyl cation bullet 6Carbon monoxide) + Carbon monoxide = (Formyl cation bullet 7Carbon monoxide)

By formula: (CHO+ bullet 6CO) + CO = (CHO+ bullet 7CO)

Quantity Value Units Method Reference Comment
Deltar2.3 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar21.1cal/mol*KPHPMSHiraoka and Mori, 1989gas phase

(Formyl cation bullet 7Carbon monoxide) + Carbon monoxide = (Formyl cation bullet 8Carbon monoxide)

By formula: (CHO+ bullet 7CO) + CO = (CHO+ bullet 8CO)

Quantity Value Units Method Reference Comment
Deltar2.2 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar22.0cal/mol*KPHPMSHiraoka and Mori, 1989gas phase

(Formyl cation bullet 8Carbon monoxide) + Carbon monoxide = (Formyl cation bullet 9Carbon monoxide)

By formula: (CHO+ bullet 8CO) + CO = (CHO+ bullet 9CO)

Quantity Value Units Method Reference Comment
Deltar2.1 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar22.6cal/mol*KPHPMSHiraoka and Mori, 1989gas phase

(Formyl cation bullet 9Carbon monoxide) + Carbon monoxide = (Formyl cation bullet 10Carbon monoxide)

By formula: (CHO+ bullet 9CO) + CO = (CHO+ bullet 10CO)

Quantity Value Units Method Reference Comment
Deltar2.0 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar22.3cal/mol*KPHPMSHiraoka and Mori, 1989gas phase

(Formyl cation bullet 10Carbon monoxide) + Carbon monoxide = (Formyl cation bullet 11Carbon monoxide)

By formula: (CHO+ bullet 10CO) + CO = (CHO+ bullet 11CO)

Quantity Value Units Method Reference Comment
Deltar2.0 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar23.0cal/mol*KPHPMSHiraoka and Mori, 1989gas phase

(Formyl cation bullet 11Carbon monoxide) + Carbon monoxide = (Formyl cation bullet 12Carbon monoxide)

By formula: (CHO+ bullet 11CO) + CO = (CHO+ bullet 12CO)

Quantity Value Units Method Reference Comment
Deltar1.9 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar23.2cal/mol*KPHPMSHiraoka and Mori, 1989gas phase

(Formyl cation bullet 12Carbon monoxide) + Carbon monoxide = (Formyl cation bullet 13Carbon monoxide)

By formula: (CHO+ bullet 12CO) + CO = (CHO+ bullet 13CO)

Quantity Value Units Method Reference Comment
Deltar1.8 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar23.2cal/mol*KPHPMSHiraoka and Mori, 1989gas phase

(Formyl cation bullet 13Carbon monoxide) + Carbon monoxide = (Formyl cation bullet 14Carbon monoxide)

By formula: (CHO+ bullet 13CO) + CO = (CHO+ bullet 14CO)

Quantity Value Units Method Reference Comment
Deltar1.8 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar23.1cal/mol*KPHPMSHiraoka and Mori, 1989gas phase

(Formyl cation bullet 14Carbon monoxide) + Carbon monoxide = (Formyl cation bullet 15Carbon monoxide)

By formula: (CHO+ bullet 14CO) + CO = (CHO+ bullet 15CO)

Quantity Value Units Method Reference Comment
Deltar1.76kcal/molPHPMSHiraoka and Mori, 1989gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/AHiraoka and Mori, 1989gas phase; Entropy change calculated or estimated

Formyl cation + Carbon dioxide = (Formyl cation bullet Carbon dioxide)

By formula: CHO+ + CO2 = (CHO+ bullet CO2)

Quantity Value Units Method Reference Comment
Deltar12.6kcal/molPHPMSHiraoka, Shoda, et al., 1986gas phase
Quantity Value Units Method Reference Comment
Deltar21.4cal/mol*KPHPMSHiraoka, Shoda, et al., 1986gas phase

(Formyl cation bullet Carbon dioxide) + Carbon dioxide = (Formyl cation bullet 2Carbon dioxide)

By formula: (CHO+ bullet CO2) + CO2 = (CHO+ bullet 2CO2)

Quantity Value Units Method Reference Comment
Deltar7.2kcal/molPHPMSHiraoka, Shoda, et al., 1986gas phase
Quantity Value Units Method Reference Comment
Deltar19.7cal/mol*KPHPMSHiraoka, Shoda, et al., 1986gas phase

(Formyl cation bullet 2Carbon dioxide) + Carbon dioxide = (Formyl cation bullet 3Carbon dioxide)

By formula: (CHO+ bullet 2CO2) + CO2 = (CHO+ bullet 3CO2)

Quantity Value Units Method Reference Comment
Deltar6.9kcal/molPHPMSHiraoka, Shoda, et al., 1986gas phase
Quantity Value Units Method Reference Comment
Deltar22.7cal/mol*KPHPMSHiraoka, Shoda, et al., 1986gas phase

(Formyl cation bullet 3Carbon dioxide) + Carbon dioxide = (Formyl cation bullet 4Carbon dioxide)

By formula: (CHO+ bullet 3CO2) + CO2 = (CHO+ bullet 4CO2)

Quantity Value Units Method Reference Comment
Deltar8.4kcal/molPHPMSHiraoka, Shoda, et al., 1986gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar24.cal/mol*KN/AHiraoka, Shoda, et al., 1986gas phase; Entropy change calculated or estimated

Formyl cation + Hydrogen = (Formyl cation bullet Hydrogen)

By formula: CHO+ + H2 = (CHO+ bullet H2)

Quantity Value Units Method Reference Comment
Deltar3.9kcal/molPHPMSHiraoka and Kebarle, 1975gas phase
Quantity Value Units Method Reference Comment
Deltar20.5cal/mol*KPHPMSHiraoka and Kebarle, 1975gas phase

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Jennings, Headley, et al., 1982
Jennings, K.R.; Headley, J.V.; Mason, R.S., The Temperature Dependence of Ion - Molecule Association Reactions, Int. J. Mass. Spectrom. Ion Phys, 1982, 45, 315. [all data]

Hiraoka, Saluja, et al., 1979
Hiraoka, K.; Saluja, P.P.S.; Kebarle, P., Stabilities of Complexes (N2)nH+, (CO)nH+ and (O2)nH+ for n = 1 to 7 Based on Gas Phase Ion Equilibrium Measurements, Can. J. Chem., 1979, 57, 16, 2159, https://doi.org/10.1139/v79-346 . [all data]

Meot-Ner (Mautner) and Field, 1974
Meot-Ner (Mautner), M.; Field, F.H., Kinetics and Thermodynamics of the Association of CO+ with CO and of N2+ with N2 between 120 and 650 K, J. Chem. Phys., 1974, 61, 9, 3742, https://doi.org/10.1063/1.1682560 . [all data]

Hiraoka and Mori, 1989
Hiraoka, K.; Mori, T., Gas Phase Stabilities of the Cluster Ions H+(CO)2(CO)n, H+(N2)2(N2)n and H+(O2)2(O2)n with n = 1 - 14, Chem. Phys., 1989, 137, 1-3, 345, https://doi.org/10.1016/0301-0104(89)87119-8 . [all data]

Hiraoka, Shoda, et al., 1986
Hiraoka, K.; Shoda, T.; Morise, K.; Yamabe, S.; Kawai, E.; Hirao, K., Stability and structure of cluster ions in the gas phase: Carbon dioxide with Cl-, H3O+, HCO2+ and HCO+, J. Chem. Phys., 1986, 84, 2091. [all data]

Hiraoka and Kebarle, 1975
Hiraoka, K.; Kebarle, P., Stability and Structure of H3CO+ Formed from COH+ + H2 at Low Temperature, J. Chem. Phys., 1975, 63, 4, 1688, https://doi.org/10.1063/1.431499 . [all data]


Notes

Go To: Top, Ion clustering data, References